Qian Chai, Lei E, Yajing Li, Yuedan Zhang, Dan Zhao, Yuxin Lv, Yaoyu Zhao
{"title":"具有自清洁特性的水下超疏水 TiO2/多孔金属基质,用于实现高性能油水分离","authors":"Qian Chai, Lei E, Yajing Li, Yuedan Zhang, Dan Zhao, Yuxin Lv, Yaoyu Zhao","doi":"10.1007/s00339-024-08094-2","DOIUrl":null,"url":null,"abstract":"<div><p>Porous metal materials with special surface wettability are widely used in oily wastewater treatment. To realize efficient oil/water separation of porous metal material, layered spherical TiO<sub>2</sub> and “woodchip” NiO micro-nano structures were constructed on the surface of nickel foam (NF) matrix by hydrothermal method, which endowed the porous metal material with superhydrophilic and underwater superoleophobic (SHI/USOB) characteristics. Moreover, the separation efficiency of various oil/water mixtures remained above 98%, and the water flux exceeded 2.66 × 10<sup>5</sup> L m<sup>−2</sup> h<sup>−1</sup>. Meanwhile, the uniformly supported TiO<sub>2</sub> nanoparticles showed excellent self-cleaning performance, and the oil droplets remaining on the sample surface could be effectively degraded under ultraviolet irradiation for 8 h. TiO<sub>2</sub>/NF has a lot of potential because of its three-dimensional micro-nano porous structure, self-cleaning capabilities and environmental friendliness.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 12","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Underwater superoleophobic TiO2/porous metal matrix with self-cleaning properties for high performance oil/water separation\",\"authors\":\"Qian Chai, Lei E, Yajing Li, Yuedan Zhang, Dan Zhao, Yuxin Lv, Yaoyu Zhao\",\"doi\":\"10.1007/s00339-024-08094-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Porous metal materials with special surface wettability are widely used in oily wastewater treatment. To realize efficient oil/water separation of porous metal material, layered spherical TiO<sub>2</sub> and “woodchip” NiO micro-nano structures were constructed on the surface of nickel foam (NF) matrix by hydrothermal method, which endowed the porous metal material with superhydrophilic and underwater superoleophobic (SHI/USOB) characteristics. Moreover, the separation efficiency of various oil/water mixtures remained above 98%, and the water flux exceeded 2.66 × 10<sup>5</sup> L m<sup>−2</sup> h<sup>−1</sup>. Meanwhile, the uniformly supported TiO<sub>2</sub> nanoparticles showed excellent self-cleaning performance, and the oil droplets remaining on the sample surface could be effectively degraded under ultraviolet irradiation for 8 h. TiO<sub>2</sub>/NF has a lot of potential because of its three-dimensional micro-nano porous structure, self-cleaning capabilities and environmental friendliness.</p></div>\",\"PeriodicalId\":473,\"journal\":{\"name\":\"Applied Physics A\",\"volume\":\"130 12\",\"pages\":\"\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-11-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Physics A\",\"FirstCategoryId\":\"4\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00339-024-08094-2\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Physics A","FirstCategoryId":"4","ListUrlMain":"https://link.springer.com/article/10.1007/s00339-024-08094-2","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Underwater superoleophobic TiO2/porous metal matrix with self-cleaning properties for high performance oil/water separation
Porous metal materials with special surface wettability are widely used in oily wastewater treatment. To realize efficient oil/water separation of porous metal material, layered spherical TiO2 and “woodchip” NiO micro-nano structures were constructed on the surface of nickel foam (NF) matrix by hydrothermal method, which endowed the porous metal material with superhydrophilic and underwater superoleophobic (SHI/USOB) characteristics. Moreover, the separation efficiency of various oil/water mixtures remained above 98%, and the water flux exceeded 2.66 × 105 L m−2 h−1. Meanwhile, the uniformly supported TiO2 nanoparticles showed excellent self-cleaning performance, and the oil droplets remaining on the sample surface could be effectively degraded under ultraviolet irradiation for 8 h. TiO2/NF has a lot of potential because of its three-dimensional micro-nano porous structure, self-cleaning capabilities and environmental friendliness.
期刊介绍:
Applied Physics A publishes experimental and theoretical investigations in applied physics as regular articles, rapid communications, and invited papers. The distinguished 30-member Board of Editors reflects the interdisciplinary approach of the journal and ensures the highest quality of peer review.