Co3O4混杂电催化剂;产氢,析氧-还原和二氧化碳还原反应的材料描述和机理方面。

IF 7 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chemical record Pub Date : 2024-12-04 DOI:10.1002/tcr.202400166
Aneela Tahira, Mohsen Padervand, Elmuez Dawi, Umair Aftab, Shahnaz Ghasemi, Brigitte Vigolo, Matteo Tonezzer, Samina Bidmeshkipour, Masoud Baghernejad, Abdelkader Labidi, Eric Lichtfouse, Chuanyi Wang, Alberto Vomiero, Zafar Hussain Ibupoto
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引用次数: 0

摘要

控制全球变暖对人类社会的不利影响需要减少二氧化碳排放和开发清洁能源。化石燃料的过度使用会破坏环境,并引发对可持续性的担忧。钴氧化物作为一种资源丰富的元素,作为一种价格低廉、环境友好的电催化剂而备受关注。Co3O4由于Co的反尖晶石结构而具有高度稳定性,但碱性溶液容易分散Co3O4。金属氧化物、泡沫镍、聚合物框架和碳纳米管已成功地与Co3O4结构结合,以提高其电催化性能。迄今为止,还没有全面的研究系统地研究了氧化钴杂化物的物理化学电子方面与其催化特性之间的关系。本文主要综述了材料的设计、制造、形态、结构特性和电活性,并考虑了实际应用的关键因素。还论证了这些建设的经济影响及其对大规模利用的预期贡献。此外,本研究还讨论了关键电化学参数对co3o4基混合动力车可持续能源生产的协同效应。最后,根据新出现的因素,对实际应用提出了有益的结论性建议。未来该领域旨在发展可持续和清洁能源生产技术的研究可以有效地受益于本报告的发现。
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Co3O4 Hybrid Electrocatalysts; Materials Description and Mechanistic Aspects Toward Hydrogen Production, Oxygen Evolution-Reduction, and CO2 Reduction Reactions.

Controlling the adverse effects of global warming on human communities requires reducing carbon dioxide emissions and developing clean energy resources. Fossil fuel overuse damages the environment and raises sustainability concerns. As a resource-rich element, cobalt oxide hybrids have attracted considerable attention as low-priced and eco-friendly electrocatalysts. Alkaline solutions disperse Co3O4 easily despite its highly stable nature, which arises from the reverse spinel structures of Co. Metal oxides, nickel foam, polymeric frameworks, and carbon nanotubes have been successfully served to combine with the Co3O4 constructions for improving the electrocatalytic performance. To date, no comprehensive study has systematically investigated the relation between the cobalt oxide hybrid's physicochemical-electronic aspects and its catalytic features. This review mainly focuses on material design, fabrication, morphology, structural characteristics, and electroactivity, considering the critical factors towards practical applications. The economic impacts of the constructions and their expected contribution to large-scale utilizations are also demonstrated. Moreover, this research discusses the synergistic effects of crucial electrochemical parameters on sustainable energy production over the Co3O4-based hybrids. Finally, some beneficial conclusive suggestions are made based on emerging factors for real-world application. Future research in the field aiming at developing sustainable and clean energy production technologies can effectively benefit from the findings of this report.

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来源期刊
Chemical record
Chemical record 化学-化学综合
CiteScore
11.00
自引率
3.00%
发文量
188
审稿时长
>12 weeks
期刊介绍: The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.
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