[合成羟基磷灰石吸收氟化物]。

I Yévenes, U Sánchez, M E Medina
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引用次数: 0

摘要

研究了氟化钠、氟化铵、氟化锡和单氟磷酸钠对合成氢磷灰石的吸附作用对pH (pH 4.7、5.5和6.1)的影响。在两个模型中;在第一个模型中,用人工唾液洗脱氢磷灰石柱中的氟化物;在第二个模型中,氟化物与缓冲的氢磷灰石一起孵育到上述ph值。氟的测定采用特定离子活性电极电位法。洗脱结果表明,在所研究的pH值下,氟化钠和氟化锡的洗脱水平不同。另一方面,氟化铵没有表现出差异。实验结果表明,氟化铵的吸附效果最好,氟化钠稍弱,单氟磷酸钠的吸附效果最差。同时,随着pH值的升高,三种氟化物的吸附量均呈下降趋势。两种模型的比较表明,对于所研究的pH值,孵育比洗脱具有更高的吸附值。
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[Absorption of fluorides by synthetic hydroxyapatites].

We studied the adsorption of sodium fluoride, ammonium fluoride, tin fluoride and sodium monofluorophosphate to synthetic hydroxiapatite in function of the pH (pH 4.7, 5.5 and 6.1). In two models; in a first model was eluted the fluorides of the hydroxiapatite column with artificial saliva; in the second model were incubated the fluoride with bufferized hydroxiapatite to the above pH. The fluoride determination was done by potentiometric method with a specific ion activity electrode. The results in the elution indicated that the sodium and tin fluorides give elution levels different at the pH studied. By other hand ammonium fluoride did not present differences. The results with incubation demonstrated that ammonium fluoride gives the greater adsorption, the sodium fluoride is slightly lower, and the sodium monofluorophosphate the lowest. Also, was observed that the adsorption decrease with the increase of the pH for the three fluorides. The comparison of both models showed that the incubation presented higher values of adsorption than the elution for the pH studied.

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