内坩埚半径变化对硅连续生长过程中熔体热场和氧输运的影响

IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Silicon Pub Date : 2024-10-24 DOI:10.1007/s12633-024-03184-5
Jiacheng Li, Xuekang Lv, Rongrong Hu, Salamat Ali, Gengjin Li, Jing Qi, Deyan He
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引用次数: 0

摘要

连续法是生产单晶硅的一种低成本、高效率的方法。内坩埚是CCz法中极为重要的组成部分。本文模拟了直径为215.00 mm的晶体硅棒的生产过程,研究了在外坩埚尺寸保持不变的情况下,内坩埚半径对熔体热场和熔体-晶体(m-c)界面形状的影响。此外,还研究了坩埚内半径的变化对晶体内Von Mises应力和熔体中氧杂质分布的影响。结果表明:当外坩埚半径一定时,随着内坩埚半径的增大,加热所需功率略有增加;而随着内坩埚半径的增大,m-c界面的凹凸度和挠度、晶体内部的Von Mises应力以及晶体生长界面的氧杂质含量均呈下降趋势。因此,较大的内坩埚尺寸有利于用CCz生产硅晶体。研究结果可以提高硅晶体的生产效率和质量。
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Influence of Inner Crucible Radius Variation on the Thermal Field and Oxygen Transport in the Melt During the Growth of Silicon by Continuous Czochralski Method

The continuous Czochralski (CCz) method is a low-cost and high-efficiency method for the production of monocrystalline silicon. The inner crucible is an extremely important component in the CCz method. In this work, the crystal silicon rod production process with a diameter of 215.00 mm is simulated to study how the inner crucible radius influences the thermal field of the melt and the melt-crystal (m-c) interface shape with the outer crucible size remaining constant. Additionally, the effects of varying the inner crucible radius on the Von Mises stress within the crystal and the distribution of oxygen impurities in the melt are also examined. The results show that when the radius of the outer crucible is fixed, the required heater power increases slightly with the increase of the inner crucible radius. However, the convexity and deflection of the m-c interface, the Von Mises stress inside the crystal, and the oxygen impurities content at the crystal growth interface decrease with the increase of the inner crucible radius. Therefore, the larger inner crucible size is favorable for silicon crystal production using CCz. The results of this work can improve the production efficiency and quality of the silicon crystal.

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来源期刊
Silicon
Silicon CHEMISTRY, PHYSICAL-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
5.90
自引率
20.60%
发文量
685
审稿时长
>12 weeks
期刊介绍: The journal Silicon is intended to serve all those involved in studying the role of silicon as an enabling element in materials science. There are no restrictions on disciplinary boundaries provided the focus is on silicon-based materials or adds significantly to the understanding of such materials. Accordingly, such contributions are welcome in the areas of inorganic and organic chemistry, physics, biology, engineering, nanoscience, environmental science, electronics and optoelectronics, and modeling and theory. Relevant silicon-based materials include, but are not limited to, semiconductors, polymers, composites, ceramics, glasses, coatings, resins, composites, small molecules, and thin films.
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