S. I. Moseenkov, A. V. Zavorin, A. N. Serkova, B. A. Kolesov, V. L. Kuznetsov
{"title":"激光处理对多壁碳纳米管改性聚合物复合材料表面电阻的影响","authors":"S. I. Moseenkov, A. V. Zavorin, A. N. Serkova, B. A. Kolesov, V. L. Kuznetsov","doi":"10.1134/S0022476625010172","DOIUrl":null,"url":null,"abstract":"<p>Changes in the surface resistance of polyethylene based composite films modified by multi-walled carbon nanotubes (MWCNTs) as a result of laser treatment are studied. Composites containing uniformly distributed nanotubes throughout their volume are prepared by mechanical melt mixing. The composite surfaces are treated by a 1064 nm fiber laser while varying the pulse duration within the 3-120 ns range and the source power within the 0.6-21 W range, so that the surface energy density during processing is 0.1-18.3 J/cm<sup>2</sup>. The influence of laser treatment parameters on the surface structure of composites is studied by scanning electron microscopy and Raman spectroscopy, and the surface resistance is determined using a four-electrode circuit. It is established that the surface resistance of the MWCNT-modified polymer composites can be either decreased by 30-50 times or increased by up to 140 times by tuning the laser treatment parameters.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"66 1","pages":"188 - 200"},"PeriodicalIF":1.2000,"publicationDate":"2025-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Laser Treatment on the Surface Resistance of Polymer Composites Modified by Multi-Walled Carbon Nanotubes\",\"authors\":\"S. I. Moseenkov, A. V. Zavorin, A. N. Serkova, B. A. Kolesov, V. L. Kuznetsov\",\"doi\":\"10.1134/S0022476625010172\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Changes in the surface resistance of polyethylene based composite films modified by multi-walled carbon nanotubes (MWCNTs) as a result of laser treatment are studied. Composites containing uniformly distributed nanotubes throughout their volume are prepared by mechanical melt mixing. The composite surfaces are treated by a 1064 nm fiber laser while varying the pulse duration within the 3-120 ns range and the source power within the 0.6-21 W range, so that the surface energy density during processing is 0.1-18.3 J/cm<sup>2</sup>. The influence of laser treatment parameters on the surface structure of composites is studied by scanning electron microscopy and Raman spectroscopy, and the surface resistance is determined using a four-electrode circuit. It is established that the surface resistance of the MWCNT-modified polymer composites can be either decreased by 30-50 times or increased by up to 140 times by tuning the laser treatment parameters.</p>\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"66 1\",\"pages\":\"188 - 200\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2025-02-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476625010172\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476625010172","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Effect of Laser Treatment on the Surface Resistance of Polymer Composites Modified by Multi-Walled Carbon Nanotubes
Changes in the surface resistance of polyethylene based composite films modified by multi-walled carbon nanotubes (MWCNTs) as a result of laser treatment are studied. Composites containing uniformly distributed nanotubes throughout their volume are prepared by mechanical melt mixing. The composite surfaces are treated by a 1064 nm fiber laser while varying the pulse duration within the 3-120 ns range and the source power within the 0.6-21 W range, so that the surface energy density during processing is 0.1-18.3 J/cm2. The influence of laser treatment parameters on the surface structure of composites is studied by scanning electron microscopy and Raman spectroscopy, and the surface resistance is determined using a four-electrode circuit. It is established that the surface resistance of the MWCNT-modified polymer composites can be either decreased by 30-50 times or increased by up to 140 times by tuning the laser treatment parameters.
期刊介绍:
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.