{"title":"Energy-Saving Processes for Increasing the Molecular Weight via a Falling Film Reactor in Large-Scale Production of PET Fiber","authors":"Shichang Chen, Ran Xu, Junhua Cao, Wenxing Chen","doi":"10.1021/acs.iecr.4c04775","DOIUrl":null,"url":null,"abstract":"The industrial production of poly(ethylene terephthalate) (PET) melt in these decades has relied on a high-energy-consuming horizontal stirring reactor, especially for industrial-grade PET where the process involves interrupting the melt reaction and a lengthy solid-state polycondensation procedure. A falling film melt polycondensation reactor model was established and used to simulate the production process of industrial-grade PET, and the process was verified in production. On this basis, two new process designs were implemented to produce both clothing-grade and industrial-grade PET. Due to the efficient mass transfer of the falling film reactor, properties such as the molecular weight and terminal carboxyl content of products were improved, along with an increase in production efficiency. The clothing-grade PET production with a falling film reactor reduced electricity consumption by 10–20%. When dual falling film reactors in series replaced the solid-state polycondensation process, the energy and water consumption dropped to surprisingly low levels owing to the elimination of several production stages.","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"16 1","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial & Engineering Chemistry Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1021/acs.iecr.4c04775","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
摘要
近几十年来,聚对苯二甲酸乙二醇酯(PET)熔体的工业化生产一直依赖于高能耗的水平搅拌反应器,尤其是工业级 PET 的生产过程涉及中断熔体反应和漫长的固态缩聚过程。我们建立了降膜熔融缩聚反应器模型,用于模拟工业级 PET 的生产过程,并在生产中对该过程进行了验证。在此基础上,实施了两种新的工艺设计,以生产服装级和工业级 PET。由于降膜反应器的传质效率高,产品的分子量和末端羧基含量等性能得到了改善,生产效率也得到了提高。使用降膜反应器生产服装级 PET 的耗电量降低了 10-20%。当双降膜反应器串联取代固态缩聚工艺时,由于省去了几个生产阶段,能耗和水耗降到了惊人的低水平。
Energy-Saving Processes for Increasing the Molecular Weight via a Falling Film Reactor in Large-Scale Production of PET Fiber
The industrial production of poly(ethylene terephthalate) (PET) melt in these decades has relied on a high-energy-consuming horizontal stirring reactor, especially for industrial-grade PET where the process involves interrupting the melt reaction and a lengthy solid-state polycondensation procedure. A falling film melt polycondensation reactor model was established and used to simulate the production process of industrial-grade PET, and the process was verified in production. On this basis, two new process designs were implemented to produce both clothing-grade and industrial-grade PET. Due to the efficient mass transfer of the falling film reactor, properties such as the molecular weight and terminal carboxyl content of products were improved, along with an increase in production efficiency. The clothing-grade PET production with a falling film reactor reduced electricity consumption by 10–20%. When dual falling film reactors in series replaced the solid-state polycondensation process, the energy and water consumption dropped to surprisingly low levels owing to the elimination of several production stages.
期刊介绍:
ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.