{"title":"浓度和激发波长对 CuInS2 QD 荧光行为的影响","authors":"Priya Chandra, K.S. Ojha","doi":"10.1016/j.solidstatesciences.2025.107886","DOIUrl":null,"url":null,"abstract":"<div><div>Copper indium sulfide (CuInS<sub>2</sub>) ternary quantum dots (QDs) offer tunable optical properties for displays, efficient solar cells, and advanced biomedical imaging. In this work, CuInS<sub>2</sub> QDs are prepared via a one-pot solvothermal route. The XRD has been performed for structural information, revealing the chalcopyrite structure of CuInS<sub>2</sub> with an average crystalline size of 8 nm, consistent with particle size calculated by the HRTEM image. The functional group analysis confirms the formation of CuInS<sub>2</sub> QDs. A blue shift in the energy gap of the prepared QDs has been found compared to the bulk. A narrow emission peak lying at 610 nm has been observed, showing Stoke's shift of 130 nm. The fluorescence behaviour of synthesized QDs with excitation wavelength and concentration has been investigated.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"163 ","pages":"Article 107886"},"PeriodicalIF":3.4000,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Impact of concentration and excitation wavelength on fluorescence behaviour of CuInS2 QDs\",\"authors\":\"Priya Chandra, K.S. Ojha\",\"doi\":\"10.1016/j.solidstatesciences.2025.107886\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Copper indium sulfide (CuInS<sub>2</sub>) ternary quantum dots (QDs) offer tunable optical properties for displays, efficient solar cells, and advanced biomedical imaging. In this work, CuInS<sub>2</sub> QDs are prepared via a one-pot solvothermal route. The XRD has been performed for structural information, revealing the chalcopyrite structure of CuInS<sub>2</sub> with an average crystalline size of 8 nm, consistent with particle size calculated by the HRTEM image. The functional group analysis confirms the formation of CuInS<sub>2</sub> QDs. A blue shift in the energy gap of the prepared QDs has been found compared to the bulk. A narrow emission peak lying at 610 nm has been observed, showing Stoke's shift of 130 nm. The fluorescence behaviour of synthesized QDs with excitation wavelength and concentration has been investigated.</div></div>\",\"PeriodicalId\":432,\"journal\":{\"name\":\"Solid State Sciences\",\"volume\":\"163 \",\"pages\":\"Article 107886\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2025-03-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solid State Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1293255825000640\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Sciences","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1293255825000640","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Impact of concentration and excitation wavelength on fluorescence behaviour of CuInS2 QDs
Copper indium sulfide (CuInS2) ternary quantum dots (QDs) offer tunable optical properties for displays, efficient solar cells, and advanced biomedical imaging. In this work, CuInS2 QDs are prepared via a one-pot solvothermal route. The XRD has been performed for structural information, revealing the chalcopyrite structure of CuInS2 with an average crystalline size of 8 nm, consistent with particle size calculated by the HRTEM image. The functional group analysis confirms the formation of CuInS2 QDs. A blue shift in the energy gap of the prepared QDs has been found compared to the bulk. A narrow emission peak lying at 610 nm has been observed, showing Stoke's shift of 130 nm. The fluorescence behaviour of synthesized QDs with excitation wavelength and concentration has been investigated.
期刊介绍:
Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments.
Key topics for stand-alone papers and special issues:
-Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials
-Physical properties, emphasizing but not limited to the electrical, magnetical and optical features
-Materials related to information technology and energy and environmental sciences.
The journal publishes feature articles from experts in the field upon invitation.
Solid State Sciences - your gateway to energy-related materials.