介孔磁性氧化铁-硅酸铝吸附剂对水中铬的吸附:吸附等温线和动力学研究

Mumtaz Khan , Islamud Din , Fazli Aziz , Imdad Ullah Qureshi , Muhammad Zahid , Ghulam Mustafa , Aroosa Sher , Said Hakim
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引用次数: 0

摘要

含重金属工业废水排放导致的水质恶化是环境问题的突出问题之一。采用沉积沉淀法合成了介孔磁性氧化铁-硅酸铝(Fe3O4-Al2SiO5)吸附剂,并考察了其对铬(VI)的吸附效果。研究表明,制备的介孔吸附剂具有较大的比表面积(476.0 m2g-1)和介孔结构,增强了吸附物的吸附性能。结果表明,在中性pH下,吸附量最大(99.9%),吸附数据最符合Langmuir等温线和拟二级动力学模型。研究进一步表明,介孔吸附剂可以重复使用,并且共存的竞争离子的影响很小。研究表明,经进一步改性和活化后,所制备的介孔吸附材料可用于工业水净化。
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Chromium adsorption from water using mesoporous magnetic iron oxide-aluminum silicate adsorbent: An investigation of adsorption isotherms and kinetics

One of the prominent issues of the environment is water quality deterioration due to release of industrial wastewater containing heavy metals. This research work focused on the synthesis of mesoporous magnetic iron oxide-aluminum silicate (Fe3O4-Al2SiO5) adsorbent via deposition-precipitation method and to assess its efficiency for chromium (VI) adsorption. The study demonstrated that the prepared mesoporous adsorbent exhibit large surface area (476.0 m2g-1) and mesoporous structure, which enhances the adsorbate adsorption. From the results it was noticed that maximum removal (99.9%) was occurring at neutral pH and the adsorption data was find in best fitting to both Langmuir isotherm as well as with pseudo-second-order kinetic models. The study further concluded that the mesoporous adsorbent can be reused following several cycles and that very slight effect of coexisting competitive ions was noticed. The study recommends that after further modification and activation, the desired mesoporous adsorbent material could be utilized for water purification at industrial level.

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来源期刊
Current Research in Green and Sustainable Chemistry
Current Research in Green and Sustainable Chemistry Materials Science-Materials Chemistry
CiteScore
11.20
自引率
0.00%
发文量
116
审稿时长
78 days
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