{"title":"两种柔性双膦烷配体的银(I)配合物:金属大环、聚合链和金属基。","authors":"Paul Boar, Peter Lönnecke, Evamarie Hey-Hawkins","doi":"10.1002/zaac.202000001","DOIUrl":null,"url":null,"abstract":"<p><p>In a 2:2 reaction with silver(I) chloride or bromide, 1,5-bis(1-phospholano)pentane (<b>1a</b>) afforded frame-like macrocyclic structures, with intra- (<b>2</b>, Cl) or intermolecular (<b>3</b>, Br) halido bridges. In contrast, 1,7-bis(1-phospholano)heptane (<b>1b</b>) formed coordination polymers <b>4a</b> (Cl) and <b>4b</b> (Br) with bridging bis-phospholane and halido ligands. A unique paddle wheel-type metallacryptand structure <b>5</b> was obtained from <b>1a</b> and silver(I) bromide in a 2:3 reaction (M:L). All complexes were fully characterized by NMR, IR spectroscopy, mass spectrometry, and X-ray crystallography.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"646 13","pages":"915-922"},"PeriodicalIF":1.1000,"publicationDate":"2020-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/zaac.202000001","citationCount":"0","resultStr":"{\"title\":\"Silver(I) Complexes of Two Flexible Bis-phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands.\",\"authors\":\"Paul Boar, Peter Lönnecke, Evamarie Hey-Hawkins\",\"doi\":\"10.1002/zaac.202000001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In a 2:2 reaction with silver(I) chloride or bromide, 1,5-bis(1-phospholano)pentane (<b>1a</b>) afforded frame-like macrocyclic structures, with intra- (<b>2</b>, Cl) or intermolecular (<b>3</b>, Br) halido bridges. In contrast, 1,7-bis(1-phospholano)heptane (<b>1b</b>) formed coordination polymers <b>4a</b> (Cl) and <b>4b</b> (Br) with bridging bis-phospholane and halido ligands. A unique paddle wheel-type metallacryptand structure <b>5</b> was obtained from <b>1a</b> and silver(I) bromide in a 2:3 reaction (M:L). All complexes were fully characterized by NMR, IR spectroscopy, mass spectrometry, and X-ray crystallography.</p>\",\"PeriodicalId\":54398,\"journal\":{\"name\":\"Zeitschrift fur Anorganische und Allgemeine Chemie\",\"volume\":\"646 13\",\"pages\":\"915-922\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2020-07-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1002/zaac.202000001\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift fur Anorganische und Allgemeine Chemie\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/zaac.202000001\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2020/5/12 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift fur Anorganische und Allgemeine Chemie","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/zaac.202000001","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2020/5/12 0:00:00","PubModel":"Epub","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Silver(I) Complexes of Two Flexible Bis-phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands.
In a 2:2 reaction with silver(I) chloride or bromide, 1,5-bis(1-phospholano)pentane (1a) afforded frame-like macrocyclic structures, with intra- (2, Cl) or intermolecular (3, Br) halido bridges. In contrast, 1,7-bis(1-phospholano)heptane (1b) formed coordination polymers 4a (Cl) and 4b (Br) with bridging bis-phospholane and halido ligands. A unique paddle wheel-type metallacryptand structure 5 was obtained from 1a and silver(I) bromide in a 2:3 reaction (M:L). All complexes were fully characterized by NMR, IR spectroscopy, mass spectrometry, and X-ray crystallography.
期刊介绍：
ZAAC is an international scientific journal which publishes original papers on new relevant research results from all areas of inorganic chemistry, solid state chemistry, and co-ordination chemistry.
The contributions reflect the latest findings in these research areas and serve the development of new materials, such as super-hard materials, electrical superconductors, or intermetallic compounds. Up-to-date physical methods for the characterization of new chemical compounds and materials are also described.
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