Pragyan P. Dash , P. Mohanty , S. Behera , R. Behura , Bibhuti B. Palai , Bhaskar Nath , Suban K. Sahoo , Bigyan R. Jali
{"title":"用于水快速检测的芘基荧光化学传感器及其应用。","authors":"Pragyan P. Dash , P. Mohanty , S. Behera , R. Behura , Bibhuti B. Palai , Bhaskar Nath , Suban K. Sahoo , Bigyan R. Jali","doi":"10.1016/j.ymeth.2023.10.006","DOIUrl":null,"url":null,"abstract":"<div><p>This manuscript introduces a pyrene-based Schiff base <strong>L</strong> by reacting pyrenecarboxaldehyde with 2-aminothiazole in equimolar ratio. The ligand <strong>L</strong> was characterized by various spectral data and single crystal. The water sensing ability of <strong>L</strong><span> was examined in different organic solvents. The weakly emissive </span><strong>L</strong> in DMSO showed a fluorescence enhancement upon the addition of water. The water-induced fluorescence enhancement of <strong>L</strong><span> was occurred due to the combined effect of aggregation-induced emission (AIE) phenomenon and suppression of photo-induced electron transfer (PET) process. Using </span><strong>L</strong>, the water in DMSO can be detected down to 0.50 wt% with a quantification limit of 1.52 wt%. The analytical novelty of the developed sensor <strong>L</strong> was validated by detecting moisture in a variety of raw food products.</p></div>","PeriodicalId":390,"journal":{"name":"Methods","volume":"219 ","pages":"Pages 127-138"},"PeriodicalIF":4.2000,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pyrene-based fluorescent chemosensor for rapid detection of water and its applications\",\"authors\":\"Pragyan P. Dash , P. Mohanty , S. Behera , R. Behura , Bibhuti B. Palai , Bhaskar Nath , Suban K. Sahoo , Bigyan R. Jali\",\"doi\":\"10.1016/j.ymeth.2023.10.006\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This manuscript introduces a pyrene-based Schiff base <strong>L</strong> by reacting pyrenecarboxaldehyde with 2-aminothiazole in equimolar ratio. The ligand <strong>L</strong> was characterized by various spectral data and single crystal. The water sensing ability of <strong>L</strong><span> was examined in different organic solvents. The weakly emissive </span><strong>L</strong> in DMSO showed a fluorescence enhancement upon the addition of water. The water-induced fluorescence enhancement of <strong>L</strong><span> was occurred due to the combined effect of aggregation-induced emission (AIE) phenomenon and suppression of photo-induced electron transfer (PET) process. Using </span><strong>L</strong>, the water in DMSO can be detected down to 0.50 wt% with a quantification limit of 1.52 wt%. The analytical novelty of the developed sensor <strong>L</strong> was validated by detecting moisture in a variety of raw food products.</p></div>\",\"PeriodicalId\":390,\"journal\":{\"name\":\"Methods\",\"volume\":\"219 \",\"pages\":\"Pages 127-138\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2023-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Methods\",\"FirstCategoryId\":\"99\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1046202323001706\",\"RegionNum\":3,\"RegionCategory\":\"生物学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"BIOCHEMICAL RESEARCH METHODS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Methods","FirstCategoryId":"99","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1046202323001706","RegionNum":3,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
Pyrene-based fluorescent chemosensor for rapid detection of water and its applications
This manuscript introduces a pyrene-based Schiff base L by reacting pyrenecarboxaldehyde with 2-aminothiazole in equimolar ratio. The ligand L was characterized by various spectral data and single crystal. The water sensing ability of L was examined in different organic solvents. The weakly emissive L in DMSO showed a fluorescence enhancement upon the addition of water. The water-induced fluorescence enhancement of L was occurred due to the combined effect of aggregation-induced emission (AIE) phenomenon and suppression of photo-induced electron transfer (PET) process. Using L, the water in DMSO can be detected down to 0.50 wt% with a quantification limit of 1.52 wt%. The analytical novelty of the developed sensor L was validated by detecting moisture in a variety of raw food products.
期刊介绍：
Methods focuses on rapidly developing techniques in the experimental biological and medical sciences.
Each topical issue, organized by a guest editor who is an expert in the area covered, consists solely of invited quality articles by specialist authors, many of them reviews. Issues are devoted to specific technical approaches with emphasis on clear detailed descriptions of protocols that allow them to be reproduced easily. The background information provided enables researchers to understand the principles underlying the methods; other helpful sections include comparisons of alternative methods giving the advantages and disadvantages of particular methods, guidance on avoiding potential pitfalls, and suggestions for troubleshooting.
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