Anna Skwierawska , Dominika Nowacka , Katarzyna Kozłowska-Tylingo
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Removal of nonsteroidal anti-inflammatory drugs and analgesics from wastewater by adsorption on cross-linked β-cyclodextrin
We present a method using the material in the form of cross-linked β-cyclodextrin (CD) showing high efficiency in the simultaneous removal of hazardous pollutants from sewage, such as diclofenac (DIC), ibuprofen (IBU), ketoprofen (KETO), naproxen (NAPR), salicylic acid (SALI) and tramadol (TRAM). The material is stable and particularly easy to regenerate. The sorbent probably remembers the shape of the contaminants, which increases its sorption capacity after the second use. The kinetics of the KETO adsorption process from one-, two- and three-component solutions are well described by the pseudo-second-order model. The maximum polymer capacity was 162.60 mg g−1. The interactions of KETO with CD were investigated, indicating that the main sorption mechanism is based on supramolecular interaction and uptake by a polymer network. The material is not sensitive to low pH and high salinity, so it can be used for the treatment of DIC, IBU, and KETO post-production wastewaters.
期刊介绍:
Water Resources and Industry moves research to innovation by focusing on the role industry plays in the exploitation, management and treatment of water resources. Different industries use radically different water resources in their production processes, while they produce, treat and dispose a wide variety of wastewater qualities. Depending on the geographical location of the facilities, the impact on the local resources will vary, pre-empting the applicability of one single approach. The aims and scope of the journal include: -Industrial water footprint assessment - an evaluation of tools and methodologies -What constitutes good corporate governance and policy and how to evaluate water-related risk -What constitutes good stakeholder collaboration and engagement -New technologies enabling companies to better manage water resources -Integration of water and energy and of water treatment and production processes in industry