{"title":"SrTiO3钙钛矿在Na2SO4+50wt.%V2O5和Na2SO4+10wt.%NaCl环境中900°C的热腐蚀","authors":"M. Prasad, K. S. Rao, M. Reddy, G. Sreedhar","doi":"10.1155/2018/4763085","DOIUrl":null,"url":null,"abstract":"This study examines the phase stability of perovskite SrTiO3 in Na2SO4 + 50 wt.% V2O5 and Na2SO4 + 10 wt.% NaCl environments at 900°C. Hot corrosion results show the formation of Sr2VO4, SrV2O6, and SrTiV5O11 phases in Na2SO4 + 50 wt.% V2O5 environment and Sr3Ti2O7, Na4TiO4, and TiO2 phases in Na2SO4 + 10 wt.% NaCl environment. Morphological observations revealed the austerity of hot corrosion attack on SrTiO3. The Sr2+ ions leached out from SrTiO3 and reacted with corrosive environments. These observations clearly indicate the destabilization of SrTiO3 in both environments.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2018-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/4763085","citationCount":"1","resultStr":"{\"title\":\"Hot Corrosion of SrTiO3 Perovskite in Na2SO4 + 50 wt.% V2O5 and Na2SO4 + 10 wt.% NaCl Environments at 900°C\",\"authors\":\"M. Prasad, K. S. Rao, M. Reddy, G. Sreedhar\",\"doi\":\"10.1155/2018/4763085\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This study examines the phase stability of perovskite SrTiO3 in Na2SO4 + 50 wt.% V2O5 and Na2SO4 + 10 wt.% NaCl environments at 900°C. Hot corrosion results show the formation of Sr2VO4, SrV2O6, and SrTiV5O11 phases in Na2SO4 + 50 wt.% V2O5 environment and Sr3Ti2O7, Na4TiO4, and TiO2 phases in Na2SO4 + 10 wt.% NaCl environment. Morphological observations revealed the austerity of hot corrosion attack on SrTiO3. The Sr2+ ions leached out from SrTiO3 and reacted with corrosive environments. These observations clearly indicate the destabilization of SrTiO3 in both environments.\",\"PeriodicalId\":13893,\"journal\":{\"name\":\"International Journal of Corrosion\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2018-05-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1155/2018/4763085\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Corrosion\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2018/4763085\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Corrosion","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2018/4763085","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Hot Corrosion of SrTiO3 Perovskite in Na2SO4 + 50 wt.% V2O5 and Na2SO4 + 10 wt.% NaCl Environments at 900°C
This study examines the phase stability of perovskite SrTiO3 in Na2SO4 + 50 wt.% V2O5 and Na2SO4 + 10 wt.% NaCl environments at 900°C. Hot corrosion results show the formation of Sr2VO4, SrV2O6, and SrTiV5O11 phases in Na2SO4 + 50 wt.% V2O5 environment and Sr3Ti2O7, Na4TiO4, and TiO2 phases in Na2SO4 + 10 wt.% NaCl environment. Morphological observations revealed the austerity of hot corrosion attack on SrTiO3. The Sr2+ ions leached out from SrTiO3 and reacted with corrosive environments. These observations clearly indicate the destabilization of SrTiO3 in both environments.
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