基于ch3nh3sni3的环保太阳能电池性能模拟

Z. Omarova
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引用次数: 1

摘要

使用СH3NH3PbI3may等高性能材料的钙钛矿光伏技术的大规模部署在未来将面临严重的环境问题。基于镍的钙钛矿太阳能电池的实施可能是商业化的替代解决方案。本文介绍了一种使用СH3NH3SnI3as吸光层的无铅环保光伏电池的理论研究结果。利用SCAPS-1D程序对钙钛矿基光伏电池的特性进行了建模。分析了不同厚度的吸收层,并提出了一种优化的器件结构,在环境温度下具有高达28%的高功率转换效率。对СH3NH3SnI3absorbing层厚度的分析表明,在厚度为500 nm时,效率为27.41%,填充系数为85.92%,短路电流密度为32.60 mA/cm2,开路电压为0.98 V。所得的数值结果表明,СH3NH3SnI3absorbing层可能是标准材料的可行替代品,并可能形成高效环保钙钛矿太阳能电池技术的基础。
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PERFORMANCE SIMULATION OF ECO-FRIENDLY SOLAR CELLS BASED ONCH3NH3SnI3
Large-scale deployment of the perovskite photovoltaic technology using such high-performance materials as СH3NH3PbI3may face serious environmental issuesin the future. Implementation of perovskite solar cellbased on Sncouldbe an alternative solution for commercialisation. This paperpresents the results of a theoretical study of a lead-free, environmentally-friendlyphotovoltaic cellusing СH3NH3SnI3as a light-absorbing layer. The characteristics of a photovoltaic cell based on perovskite were modelled using the SCAPS-1D program. Various thicknesses of the absorbing layer were analysed,and an optimised device structure is proposed,demonstratinga high power conversionefficiencyof up to 28% at ambient temperature. The analysis of the thicknesses of the СH3NH3SnI3absorbing layer revealedthat at a thickness of 500 nm, performance is demonstrated with an efficiencyof 27.41 %, a fill factor of 85.92 %, a short circuit current density of 32.60 mA/cm2and an open-circuit voltage of 0.98 V. The obtained numerical results indicate that the СH3NH3SnI3absorbing layer may be a viable replacement forthe standard materials and may form the basis of a highly efficient technology of the environmentally-friendlyperovskite solar cells.
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