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TUDY OF THE INFLUENCE OF THE ACCUMULATED DOSE OF DAMAGE IN THE NEAR-SURFACE LAYER ON RESISTANCE TO EXTERNAL INFLUENCES ASSOCIATED WITH CORROSION PROCESSES DURING HIGH-TEMPERATURE ANNEALING 研究近表层损伤累积剂量对高温退火过程中抵抗与腐蚀过程相关的外部影响的影响
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/14-20
A. Kozlovskiy
Abstract. Investigating the challenges associated with the structural and strength degradation of ceramic fuel cells, which hold significant potential for hydrogen production through electrolysis methods, is a current focus ofresearch. Understanding the degradation processes and their occurrence rate is crucial in the assessment of the efficacy of these ceramics for applications in alternative energy production, specifically in the realm of hydrogen energy. The aim of this study is to ascertain the impact of doping ceramics with aluminum nitride NiAl2O4, irradiated with protons with a dose of approximately 50 dpa, on resistance to high-temperature degradation, and associated corrosive processes of oxidation and swelling, as well as migration processes of implanted hydrogen. Three types of ceramics were selected as objects for study: NiAl2O4ceramics, NiAl2O4ceramics stabilized with 0.05 M AlN, NiAl2O4ceramics stabilized with 0.15 M AlN, that are distinguished by the formation of impurity phases in Al7O3N8, with an orthorhombic type of crystal lattice. As a result of high-temperature tests, it was observed that NiAl2O4ceramics, when stabilized, exhibit reduced susceptibility to destructive alterations in strength characteristics, primarily attributed to the deformation distortion of the crystal structure caused by its swelling. These processes are associated with an augmentation in the thermal expansion of the crystal structure, manifested in the deformation swelling of the crystal lattice volume.
摘要陶瓷燃料电池具有通过电解方法制氢的巨大潜力,研究与陶瓷燃料电池的结构和强度降解相关的挑战是当前的研究重点。了解降解过程及其发生率对于评估这些陶瓷在替代能源生产(特别是氢能领域)中的应用效果至关重要。本研究的目的是确定在陶瓷中掺入氮化铝 NiAl2O4,并用剂量约为 50 dpa 的质子进行辐照,对耐高温降解、相关的氧化和膨胀腐蚀过程以及植入氢迁移过程的影响。我们选择了三种陶瓷作为研究对象:分别是 NiAl2O4 陶瓷、用 0.05 M AlN 稳定的 NiAl2O4 陶瓷和用 0.15 M AlN 稳定的 NiAl2O4 陶瓷,它们的特点是在 Al7O3N8 中形成杂质相,晶格类型为正交菱形。高温测试结果表明,NiAl2O4 陶瓷经稳定化处理后,强度特性发生破坏性变化的几率降低,这主要归因于膨胀引起的晶体结构变形。这些过程与晶体结构的热膨胀有关,表现为晶格体积的变形膨胀。
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引用次数: 0
SIMULATION OF MULTIPOINT CONTACT UNDER THERMOELECTRIC TESTING 热电测试下的多点接触模拟
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/93-103
Soldatov A.A
The article presents the results of modeling a multipoint contact in the thermoelectric method of testing. Sources of thermoelectromotive force (thermoEMF) have shown different influences, according to their type, on the load characteristics of the equivalent source obtained by parallel connection of several thermocouples as shown in the explanatory figures. The presented model is implemented in the NI LabVIEW package, which is freely available. The model was verified on three types of thermocouples (copper-constantan, copper-nichrome, and chromel-alumel), which have been connected in parallel in different quantities. The calculated load characteristics of the equivalent sources differ from the experimental ones by no more than 6%. The results of modeling the load characteristics of the equivalent thermoEMF sources obtained by parallel connection of different quantities of two types of thermocouples are presented. It is shown that in order to obtain reliable data, it is necessary to provide an equivalent source load of at least 1 kOhm.
文章介绍了热电测试法中多点接触建模的结果。热电动势(thermoEMF)源的类型不同,对通过并联多个热电偶获得的等效源的负载特性的影响也不同,如注释图所示。所介绍的模型是在免费提供的 NI LabVIEW 软件包中实现的。该模型在三种类型的热电偶(铜-康铜、铜-铬和铬-铝)上进行了验证,这些热电偶以不同数量并联。计算得出的等效源负载特性与实验结果相差不超过 6%。本文介绍了通过并联不同数量的两种热电偶而获得的等效热电偶源的负载特性建模结果。结果表明,为了获得可靠的数据,必须提供至少 1 千欧的等效源负载。
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引用次数: 0
MECHANISM OF FORMATION OF INTERNAL AND SURFACE DEFECTS IN CASTING AND THEIR TRANSFORMATION INTO SURFACE DEFECTS OF SHEET 铸件内部和表面缺陷的形成机理及其向板材表面缺陷的转化
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/28-37
I.K. I.K. Ibraev
This study aimed to elucidate the formation mechanisms of micro-macrostructural heterogeneities in the ingot's cortical zone and their transformation into surface defects during heating, plastic deformation, and rolling processes. The methodology and results of studying the macro-and microstructural and chemical heterogeneities of ingots and finished rolled sheets are presented. A comparative method of structural-concentration analysis of metal at theend-to-end metallurgical processing stage of ingot -slab -rolled sheets was developed. The technique utilizes metallographic methods to study the structure and perform qualitative analysis of non-metallic inclusions. The research findings indicate that the quality of the rolled sheet surface is predominantly determined by the physical heterogeneity of the ingot's crust zone, while the internal defects in thin rolled sheets are largely influenced by the contamination of the metal with non-metallic inclusions. A novel mechanism is proposed for the transformation of defects in the casting cortical zone into surface and internal defects in rolled sheets. This study contributes to a deeper understanding of the formation and transformation of defects during metal processing, enabling the development of strategies for improving the quality of rolled sheets. Additionally, the study highlights the importance of controlling the physical heterogeneity of the ingot's crust zone and minimizing non-metallic inclusion contamination to achieve high-quality rolled sheets.
这项研究旨在阐明在加热、塑性变形和轧制过程中,钢锭皮层区微观宏观结构异质性的形成机制及其向表面缺陷的转化。本文介绍了研究钢锭和成品轧制板宏观和微观结构及化学异质性的方法和结果。在钢锭-板坯-轧制板材的端到端冶金加工阶段,开发了一种金属结构浓度分析比较方法。该技术利用金相方法研究结构,并对非金属夹杂物进行定性分析。研究结果表明,轧制薄板表面的质量主要由铸锭结壳区的物理异质性决定,而轧制薄板的内部缺陷则主要受金属中非金属夹杂物污染的影响。研究提出了铸造皮层区缺陷转化为轧制薄板表面和内部缺陷的新机制。这项研究有助于加深对金属加工过程中缺陷形成和转化的理解,从而制定出提高轧制板材质量的策略。此外,该研究还强调了控制铸锭皮壳区的物理异质性和尽量减少非金属夹杂物污染对获得高质量轧制板材的重要性。
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引用次数: 0
Numerical modeling of the process of extrusion of high-viscosity pastes 高粘度浆料挤压过程的数值模拟
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/114-123
R. Gadirov
This paper provides a theoretical consideration of the process of paste extrusion using a piston dispenser. The paste is considered as a highly viscous suspension of terpineol and silver particle powder. As a result of numerical modeling, the distribution of silver particles in a steady paste flow was obtained. The excess pressure in the piston depending on its speed and the effective width of the track depending on the piston speed were obtained. Modeling showed that the viscosity of the paste has the greatest influence on the extrusion process. Application of the obtained dependencies will allow you to control the paste extrusion process.
本文从理论上探讨了使用活塞式分配器挤出膏体的过程。糊状物被视为松油醇和银颗粒粉末的高粘度悬浮液。通过数值建模,得到了银颗粒在稳定的膏体流动中的分布情况。此外,还得出了活塞中的过剩压力取决于活塞的速度,以及轨道的有效宽度取决于活塞的速度。建模结果表明,浆料的粘度对挤出过程的影响最大。应用所获得的依赖关系可以控制浆料挤出过程。
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引用次数: 0
IMPROVING THE QUALITY OF EKIBASTUZ COAL USING THE DRY ENRICHMENT METHOD 利用干法浓缩提高埃基巴斯图兹煤的质量
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/67-73
K. Shaimerdenova
This paper discusses the possibility of improving the ekibastuz coal quality through the use of "dry enrichment" technology. The experiments and calculations carried out made it possible to determine the optimal scheme for enrichment of samples of thermal coals from the Ekibastuzsky open-pit mineof "Angrensor-Energo" LLP. Testing of technical characteristics, such as moisture content, ash content, volatile matter yield and calculation of energy characteristics of enriched samples of thermal coal was carried out in 3 stages in a coal chemistry laboratory. As a result, it was found that the energy content of the enriched fuel samples increased to 28.5% of the original. This significantly improved consumer properties by obtaining the maximum yield of high quality coal concentrate. Consequently, the developed scheme of enrichment allows to significantly reduce the consumption of electricity, reduce emissions into the atmosphere, reduce the harmful impact on the environment, and expand the markets for coal.
本文讨论了通过使用 "干法富集 "技术提高埃基巴斯图兹煤炭质量的可能性。通过实验和计算,确定了 "Angrensor-Energo "有限责任公司埃基巴斯图兹露天矿热能煤样品浓缩的最佳方案。在煤炭化学实验室分三个阶段对热能煤浓缩样本的水分含量、灰分含量、挥发物产量等技术特性进行了测试,并计算了能量特性。结果发现,富集燃料样品的能量含量提高到原来的 28.5%。这极大地改善了煤炭的消费特性,获得了最高产量的优质精煤。因此,所开发的浓缩方案可以大大降低电力消耗,减少大气排放,降低对环境的有害影响,并扩大煤炭市场。
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引用次数: 0
INFLUENCE OF PLASMON EFFECT ON THE SENSITIZATION OF TITANIUM DIOXIDE BY DYE MOLECULES 等离子体效应对染料分子敏化二氧化钛的影响
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/49-56
Auzhanova A.A, Ibrayev N.Kh, E. Seliverstova
The influence of the plasmon effect of metal nanoparticles on electron transfer from Eosin and Rhodamine B dyes to TiO2was studied. Spectral-kineticmeasurementsshowedthat, compared to SiO2, not only the intensity but also the fluorescence lifetime of both dyes decreases on the TiO2surface, which indicates the charge transfer from the dye to the semiconductor. In the presence of core@shell (Ag@TiO2) plasmon nanostructures, an intensification of the fluorescence of both dyes is observed, as well as a decrease in the duration of the dyes emission. The optimal concentration for which the maximum plasmon effect was recorded is 3 wt% of Ag@TiO2. The plasmon effect also leads to an increase in the efficiency of sensitization of the semiconductor by molecules of the dyes under study, which is expressed as an increase in the photovoltaic and charge-transport characteristics of the semiconductor films. The results obtained on theplasmoneffect on the charge transfer process in the dye/semiconductor system can be used in the development of devices for photovoltaics, photocatalytic, and optoelectronic elements.
研究了金属纳米粒子的等离子效应对曙红和罗丹明 B 染料向二氧化钛的电子转移的影响。光谱动力学测量结果表明,与二氧化硅相比,两种染料在二氧化钛表面的荧光强度和荧光寿命都有所下降,这表明电荷从染料转移到了半导体。在核@壳(Ag@TiO2)等离子体纳米结构的存在下,两种染料的荧光都会增强,同时染料发射的持续时间也会缩短。记录到最大等离子效应的最佳浓度为 3 wt% 的 Ag@TiO2。等离子效应还能提高所研究的染料分子对半导体的敏化效率,这表现为半导体薄膜的光电和电荷传输特性的提高。关于染料/半导体系统中电荷转移过程的质子效应的研究结果可用于光伏、光催化和光电元件设备的开发。
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引用次数: 0
Методика измерения диэлектрических коэффициентов полярных жидкостей в диапазоне микроволн 微波范围内极性液体介电系数的测量方法
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/138-144
С А Азизов
В статье предложна методика измерения диэлектрических коэффициентов полярных жидкостей для исследования объектов с большими потерями. Известные резонансные методы определения диэлектрических коэффициентов являются наиболее точными при изучении диэлектриков с малыми потерями. Применение этих методов для исследования объектов с большими потерями ограничено тем, что при внесении образца добротность резонансной системы падает настолько сильно, что ее изучение и измерения существующими методами становится невозможным. В диапазоне частот от 50 КГц до 200 МГц наибольшее распространение получил метод измерения при помощи куметра. Данный прибор допускает определение значений добротности больше 50 – 30. Между тем, в области дисперсии электромагнитных волн, значения тангенса угла потерь tgδ = (ε" / ε') зачастую превышают единицу. В этом случае применение известных методов измерения диэлектрических коэффициентов для исследования объектов с большими потерями неизбежно связано со столь большой погрешностью, что получаемые результаты не могут быть использованы для количественной интерпретации. Из – за простоты и удобства измерений при помощи куметра вопрос о расширении области измерения в сторону малых и больших потерь является приемлемым для исследований полярных жидкостей.
本文提出了一种测量极性液体介电系数的方法,用于研究高损耗物体。在研究小损耗电介质时,已知的介电系数共振测定方法是最精确的。但这些方法在研究高损耗物体时的应用受到了限制,因为当引入样品时,共振系统的好坏会大大降低,以至于无法用现有方法对其进行研究和测量。在 50 kHz 至 200 MHz 的频率范围内,最广泛使用的测量方法是累积计。这种仪器可以测定大于 50 - 30 的拟合优度值。同时,在电磁波色散领域,损耗角正切 tgδ = (ε" / ε')的值往往超过 1。在这种情况下,应用已知的介电系数测量方法来研究具有较大损耗的物体,不可避免地会产生较大误差,以至于所获得的结果无法用于定量解释。由于使用积算器进行测量简单方便,因此在极性液体的研究中,将测量范围扩大到小损耗和大损耗的问题是可以接受的。
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引用次数: 0
REASON OF PITTING CORROSION OF MARTENSITIC STEELIN SEA WATER 马氏体钢在海水中发生点蚀的原因
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/38-48
M.I. Baikenov
Abstract. The assumption that corrosion of products from X17 martensitic stainless steel in seawater occurs due to incomplete oxidation of chromium atoms in cells on the surface of the products is made in the presented work. Incomplete oxidation of chromium atoms occurs in the cells of X17 steel. This is due to the fact that oxygen molecules at temperatures up to 350 °C not having enough energy for chemical interaction with trivalent chromium atoms entering the cubic body-centeredcells of martensitic stainless steel. There is a significant decrease in the corrosion rate after placing X17 stainless steel products in 5% iodine solution in ethanol after pre-treatment of the product surface with active forms of oxygen. The treatment was carried out during 12 hours with chemically active forms of oxygen (ozone and singlet oxygen) at a temperature of 350 °С. Most of the chromium atoms on the surface of X17 steel samples were completely oxidized as a result of 12 hours exposure to highly active forms of oxygen. The density of the oxide passivation layer on the surface of the products increased significantly as a result of the formation of new bonds CHROMIUM -OXYGEN -CHROMIUM. This resulted in increased corrosion resistance. The rate of interaction with an alcohol solution containing halogen ions was reduced by 71% for the samples with the oxide passivation layer compared to samples of untreated X17 steel.
摘要本文假定 X17 马氏体不锈钢产品在海水中的腐蚀是由于产品表面晶胞中铬原子的不完全氧化造成的。铬原子的不完全氧化发生在 X17 钢的晶胞中。这是由于氧分子在高达 350 °C 的温度下没有足够的能量与进入马氏体不锈钢立方体中心电池的三价铬原子发生化学作用。在用活性氧预处理产品表面后,将 X17 不锈钢产品放入 5%的碘乙醇溶液中,其腐蚀率明显降低。用化学活性氧(臭氧和单线态氧)在 350 °С 的温度下进行了 12 小时的处理。在高活性氧环境中暴露 12 小时后,X17 钢样品表面的大部分铬原子完全氧化。由于形成了新的铬-氧-铬键,产品表面氧化物钝化层的密度显著增加。从而提高了耐腐蚀性。与未经处理的 X17 钢样品相比,带有氧化物钝化层的样品与含有卤素离子的酒精溶液的相互作用率降低了 71%。
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引用次数: 0
EFFECT OF TWO-PHASE FLOW ON THE FUEL GRAIN IGNITION AND ITS DEPARTURE FROM THE CARTRIDGE CASE 两相流对燃料颗粒点火及其偏离弹壳的影响
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/84-92
L. L. Minkov
False heat targets play an important role in the safety of aircraft and helicopters. The main task is to ensure stable ignition of the fuel grain before leaving the cartridge case. In order to optimize this process, it is important to study the influence of various parameters, such as the size of the gap between the cartridge case and the cylindrical surface of fuel grain, as well as the size of the particles coming from the initiator and fuel grain. This article offers a physical and mathematical model of the ignition and departure process of the grain, and studies the influence of the specified parameters on the ignition time. The ignition times of the grain end surface for different particle sizes equals r = 1 μm and r = 25 μm have been estimated, the gap between the cartridge case and the cylindrical surface of grain ranged from 0.5 mm to 2 mm. The output velocities of the grain from the cartridge case are obtained for particles equal to 1 μm and 25 μmand different gap between the cartridge case and the cylindrical surface of fuel grain.
假热目标对飞机和直升机的安全起着重要作用。其主要任务是确保燃料颗粒在离开弹壳前稳定点燃。为了优化这一过程,必须研究各种参数的影响,例如弹壳与燃料颗粒圆柱表面之间的间隙大小,以及来自引发剂和燃料颗粒的颗粒大小。本文提供了燃料颗粒点火和离火过程的物理和数学模型,并研究了指定参数对点火时间的影响。本文估算了不同粒径(r = 1 μm 和 r = 25 μm)颗粒端面的点火时间,弹壳与颗粒圆柱面之间的间隙为 0.5 毫米至 2 毫米。在颗粒大小分别为 1 μm 和 25 μm 以及弹壳与燃料颗粒圆柱表面之间的间隙不同的情况下,获得了颗粒从弹壳中输出的速度。
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引用次数: 0
EW METAL/SUPERCONDUCTOR-INSULATOR TRANSITIONS AND THEIR EFFECTS ON HIGH-TCSUPERCONDUCTIVITY INUNDERDOPED AND OPTIMALLY DOPED CUPRATES 新的金属/超导体-绝缘体跃迁及其对低掺杂和最佳掺杂铜氧化物高超导性的影响
Q3 Engineering Pub Date : 2024-03-29 DOI: 10.31489/2024no1/21-27
U. Kurbanov
Abstract.Anew approach to the metal/superconductor-insulator transition in doped cuprates by studying the polaron formation and localization of doped charge carriers (holes) in them and the possibility of transforming a metallic or superconducting system into an insulatorwas developed. Amore suitable criterion for such a phase transition by comparing the bandwidth (or Fermi energy) of large polarons with their binding energies in the cuprateswas derived. The possibility of the metal/superconductor-insulator transition and phase separation in doped cuprates resulting in the formation of competing metallic/superconducting and insulating phases in underdoped, optimally doped and even in overdoped high-Tccuprateswas predicted. Then the possible detrimental and beneficial effects of the different disorders (e.g. polaron formation and charge-density-wave transition) and the coexisting insulating and superconducting phases on the critical temperature 𝑇𝑐of the superconducting transition of underdoped and optimally doped cuprateswas examined. The actual superconducting transition temperature 𝑇𝑐in these materials using the theory of Bose-liquid superconductivity, and not theBardeen-Cooper-Schrieffer-like theory of Fermi-liquid superconductivity, which is incapable of predicting the relevant value of 𝑇𝑐in high-𝑇𝑐cuprateswas determined. We find thatthe suppressing of the polaronic and charge-density-waveeffects in optimally doped cuprates results in the enhancement of 𝑇𝑐, while some lattice defects (e.g., anion vacancies) in the cuprates may strongly affect, on 𝑇𝑐and enhance high-𝑇𝑐superconductivity in them.
摘要:通过研究掺杂铜氧化物中极子的形成和掺杂电荷载流子(空穴)的定位以及将金属或超导系统转变为绝缘体的可能性,提出了掺杂铜氧化物中金属/超导-绝缘体转变的新方法。通过比较大极子的带宽(或费米能)和它们在铜氧化物中的结合能,得出了更适合这种相变的标准。预测了掺杂铜氧化物中金属/超导体-绝缘体转变和相分离的可能性,这导致在掺杂不足、最佳掺杂甚至过量掺杂的高掺杂铜氧化物中形成相互竞争的金属/超导和绝缘相。然后,研究了不同失调(如极子形成和电荷密度波转变)以及绝缘相和超导相共存对掺杂不足和最佳掺杂铜氧化物超导转变临界温度𝑇𝑐可能产生的不利和有利影响。我们利用玻色-液体超导理论,而非类似于巴丁-库珀-施里弗的费米-液体超导理论,确定了这些材料中的实际超导转变温度𝑇𝑐,后者无法预测高𝑇𝑐铜酸盐中的𝑇𝑐相关值。我们发现,最佳掺杂铜氧化物中极子效应和电荷密度波效应的抑制会导致𝑇𝑐的增强,而铜氧化物中的一些晶格缺陷(如阴离子空位)可能会强烈影响𝑇𝑐并增强其高𝑇𝑐超导性。
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引用次数: 0
期刊
Eurasian Physical Technical Journal
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