用特征基团和交联反应动力学评价延迟固化免烫增感织物的贮存稳定性

IF 0.6 4区 工程技术 Q4 MATERIALS SCIENCE, TEXTILES AATCC Journal of Research Pub Date : 2023-05-29 DOI:10.1177/24723444231175210
Jiangfei Lou, Hongmei Cai, Yueling Sun, J. Yuan, Jin Xu, Aixue Dong, Zheng-biao Gu, X. Fan
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引用次数: 0

摘要

在延迟固化和非铁整理中,低温干燥后的敏化织物在高温固化前应具有良好的表面平整度,这意味着整理剂在储存过程中没有与纤维素纤维发生反应;因此,一种合适的无铁整理剂对于实现上述目的是必不可少的。同时,目前还没有成熟有效的敏化织物储存稳定性评价方法。本文测定了不同贮存条件下敏化织物的特征基团含量。高温储存(40–60°C)可将储存时间从30天缩短至6天。建立了高温贮存条件下的反应动力学方程;然后用该方程预测敏化织物在低温长期贮存过程中的交联度,也可以评价敏化织物的贮存稳定性。反应度的预测值与测量值之间的相对误差为2.5%,表明了所建立方法的准确性和有效性。本文为敏化织物的稳定性评价以及延迟固化和非熨烫整理剂、整理工艺和储存条件的选择提供了依据。
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Evaluation of Storage Stability for Delayed-Curing Non-Iron Finishing Sensitized Fabrics via Characteristic Group and Cross-linking Reaction Kinetics
In delayed-curing and non-iron finishing, the sensitized fabric after low-temperature drying should have good surface planeness before curing at high temperatures, which implies that the finishing agent has not reacted with the cellulose fibers during storage; therefore, a suitable non-iron finishing agent is essential for achieving the above objectives. Meanwhile, there are currently no mature and efficient evaluation methods for the storage stability of sensitized fabrics. In this article, the content of characteristic groups of the sensitized fabrics with different storage conditions was measured. The storage time can be shortened from 30 to 6 days with high-temperature storage (40–60°C). The reaction kinetics equation was established under high-temperature storage; then using this equation to predict the cross-linking degree of sensitized fabrics during long-term storage at low temperature, the storage stability of sensitized fabrics can also be evaluated. The relative error of 2.5% between the predicted value and the measured value of the reaction degree showed the accuracy and effectiveness of the established method. This article provided a basis for the stability evaluation of the sensitized fabric and the selection of the finishing agent, finishing process, and storage conditions for the delayed-curing and non-ironing finishing process.
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来源期刊
AATCC Journal of Research
AATCC Journal of Research MATERIALS SCIENCE, TEXTILES-
CiteScore
1.30
自引率
0.00%
发文量
34
期刊介绍: AATCC Journal of Research. This textile research journal has a broad scope: from advanced materials, fibers, and textile and polymer chemistry, to color science, apparel design, and sustainability. Now indexed by Science Citation Index Extended (SCIE) and discoverable in the Clarivate Analytics Web of Science Core Collection! The Journal’s impact factor is available in Journal Citation Reports.
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