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Dyeing of Mixed Cotton and Polyester Fabrics with New Dyes—Complexes of Collagen with Transition Metal Ions 用新型染料--胶原蛋白与过渡金属离子的络合物--染色棉和涤纶混合织物
IF 0.6 4区 工程技术 Q4 MATERIALS SCIENCE, TEXTILES Pub Date : 2024-07-23 DOI: 10.1177/24723444241257541
A. Rafikov, M. Zubaydullaeva, D. Sadikova, F. Abdurakhimova
Uniform, stable, one-step dyeing of textile fabrics made from a mixture of natural and synthetic fibers using traditional methods remains problematic to this day. As an alternative to traditional methods, a one-step method for dyeing mixed cotton and polyester fabrics with a new natural dye—a complex of collagen and [Formula: see text] and [Formula: see text] ions—was proposed for the first time. Dyeing of pre-prepared cotton, polyester, and cotton–polyester fabrics is carried out by dipping in an aqueous dye solution, squeezing, drying, and heat setting. The influence of the mass ratio of dye components, fixation temperature, and pH of the solution on the degree of dye fixation was determined. A degree of sorption of dyes (14–25%) from the solution onto the surface of fabrics was established, which after heat fixation decreases slightly (1–3%). During washing processes, the copper complex is almost completely washed out from polyester and blended fabrics and remains in small quantities (2.4–3.8%) on the surface of cotton fabrics. After water washing, the degree of fixation of the collagen–chrome complex in fabrics is as follows: in cotton—8–10%, in polyester—10–12%, and in cotton–polyester—8–9%. The color coordinates of cotton and cotton–polyester fabrics hardly change before and after washing, but for polyester fabric, the changes are significant. The mechanism of interaction of the complex dye with the fibers was studied using the Fourier transform infrared method, and the morphology and distribution of the dye on the surface of the samples using the SEM-EDS method. The dye binds to cellulose through ionic and coordination bonds, and to polyester through joint melting. Therefore, unlike pure polyester fabric, cotton and cotton–polyester fabrics demonstrated high color fastness to washing and light fastness. The use of production waste, the exclusion of synthetic dyes and harmful chemicals, and single-stage dyeing of the material reduce the environmental burden.
使用传统方法对天然纤维和合成纤维混合制成的纺织品进行均匀、稳定的一步法染色,至今仍是一个难题。作为传统方法的替代方法,我们首次提出了一种用新型天然染料--胶原蛋白和[式:见正文]及[式:见正文]离子的复合物--对混合棉和涤纶织物进行一步法染色的方法。通过在染料水溶液中浸渍、挤压、干燥和热定型,对预先准备好的棉织物、涤纶织物和棉涤纶织物进行染色。测定了染料成分的质量比、固着温度和溶液的 pH 值对染料固着程度的影响。结果表明,染料从溶液中吸附到织物表面的程度(14%-25%)在加热固色后略有下降(1%-3%)。在水洗过程中,铜络合物几乎完全从涤纶和混纺织物中洗掉,少量(2.4-3.8%)残留在棉织物表面。水洗后,织物中胶原-铬复合物的固定程度如下:棉-8-10%,涤纶-10-12%,棉-涤纶-8-9%。棉织物和棉涤织物的色坐标在洗涤前后几乎没有变化,但涤纶织物的色坐标变化很大。利用傅立叶变换红外方法研究了复合染料与纤维的相互作用机理,利用扫描电镜-电子显微镜方法研究了染料在样品表面的形态和分布。染料通过离子键和配位键与纤维素结合,通过共同熔化与聚酯结合。因此,与纯涤纶织物不同,棉布和棉-涤纶织物具有很高的耐洗色牢度和耐光牢度。生产废料的利用、合成染料和有害化学物质的排除以及材料的单段染色都减轻了环境负担。
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引用次数: 0
Process Optimization for Coating of Acanthus Ilicifolius Extract on Silk Sutures 在蚕丝缝合线上涂覆刺桐提取物的工艺优化
IF 0.6 4区 工程技术 Q4 MATERIALS SCIENCE, TEXTILES Pub Date : 2024-07-23 DOI: 10.1177/24723444241257540
Natarajan Sivanesan, S. Ariharasudhan, Ramesh Babu V, Sakthivel Santhanam
This study investigates the optimization of process parameters for coating silk sutures with Acanthus ilicifolius leaf extract. The increasing awareness of surgical site infections is a critical concern associated with the use of sutures in medical procedure undertaking. Our study aimed to assess the impact of three crucial coating factors, namely extract content, temperature, and duration, on the mechanical and antibacterial characteristics of silk sutures braided together. Through Box–Behnken design, in conjunction with the response surface approach, we conducted a thorough analysis to refine the model. The result showed that extract concentration directly influences both antimicrobial activity and elongation, while temperature and time primarily affect tensile strength and bending stiffness. To achieve the maximum tensile strength, minimum breaking elongation, minimum bending stiffness, and lower friction, all while maintaining the important antimicrobial efficacy of the sutures, this study emphasizes the use of response surface methodology in optimizing coating parameters for A. ilicifolius leaf extract on silk sutures. The response models are developed on the complex relationships between these parameters and the properties of the sutures.
本研究探讨了用刺桐叶提取物涂覆丝线缝合线的工艺参数优化问题。手术部位感染的意识日益增强,这是与医疗程序中使用缝合线相关的一个重要问题。我们的研究旨在评估三个关键涂层因素(即提取物含量、温度和持续时间)对编织在一起的丝线缝合线的机械和抗菌特性的影响。通过盒-贝肯设计,结合响应面法,我们进行了深入分析,以完善模型。结果表明,提取物浓度直接影响抗菌活性和伸长率,而温度和时间则主要影响拉伸强度和弯曲刚度。为了实现最大的拉伸强度、最小的断裂伸长率、最小的弯曲刚度和较低的摩擦力,同时保持缝合线的重要抗菌功效,本研究强调使用响应面方法优化蚕豆叶提取物在蚕丝缝合线上的涂层参数。响应模型是根据这些参数与缝合线特性之间的复杂关系建立的。
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引用次数: 0
Producing Multifunctional Chitosan/Viscose Fabric by β-Thujaplicin and Harmaline Finishing 通过β-竹节苷脂和无害整理生产多功能壳聚糖/粘胶织物
IF 0.7 4区 工程技术 Q4 Materials Science Pub Date : 2024-06-07 DOI: 10.1177/24723444241257545
Maryam Jahanpanah, Abolfazl Davodiroknabadi, Mohammadreza Sayedmir, Mohammadali Shirgholami, Mohammad Shahvaziyan
This article introduces the fabrication of multifunctional viscose fabric with chitosan, β-thujaplicin, and harmaline. The scanning electron microscope of the produced sample shows excellent distribution of used materials on surface of viscose fabric. After 10, 20, and 30 washing cycles the bactericidal properties and durability were investigated, and the results indicate that the durability of bactericidal action against Shigella and Bacillus cereus was very good. Moreover, abrasion resistance after 500, 700, and 900 cycles rubbing tests was studied, and the results were analyzed in detail. On the contrary, the ultraviolet blocking properties and durability after 10, 20, and 30 washing cycles were investigated. The outcome indicates that the treated fabrics have excellent ultraviolet blocking even after 30 washing cycles. Consequently, the produced multifunctional fabric has excellent physical and chemical properties, such as increased tensile strength and abrasion resistance, antibacterial activity, and ultraviolet blocking.
本文介绍了用壳聚糖、β-巯基嘌呤和禾草灵制备多功能粘胶织物的方法。样品的扫描电子显微镜显示,所用材料在粘胶织物表面的分布非常均匀。经过 10 次、20 次和 30 次洗涤后,对杀菌性能和耐久性进行了研究,结果表明对志贺氏杆菌和蜡样芽孢杆菌的杀菌作用耐久性非常好。此外,还研究了 500、700 和 900 次摩擦试验后的耐磨性,并对结果进行了详细分析。相反,还研究了经过 10、20 和 30 次洗涤后的紫外线阻隔性能和耐久性。结果表明,经过处理的织物即使在 30 次洗涤后仍具有良好的紫外线阻隔性。因此,生产出的多功能织物具有优异的物理和化学特性,如抗拉强度和耐磨性、抗菌活性和紫外线阻隔性。
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引用次数: 0
An Investigation of Fastness and Potential Antibacterial Features on Cotton Fabric Colored with Novel Azo Compounds 新型偶氮化合物染色棉织物的牢度和潜在抗菌特性研究
IF 0.7 4区 工程技术 Q4 Materials Science Pub Date : 2024-05-03 DOI: 10.1177/24723444241246306
Pinar SARAL ÖZDEMİR, Günay Kaya Kantar, A. Özgüney, S. Şaşmaz
Novel azo compounds were synthesized by diazotization of aniline and of 3-aminopyridine in the presence of NaNO2 and HCl, followed by coupling with 2-methylresorcinol in alkaline media. The structures were characterized using FT-IR, 1H NMR, and 13C NMR analysis. The main purpose of the present study is to investigate coloration applications, and antibacterial and fastness properties of the new azo structures in textile industry. Exhaust dyeing processes were applied on cotton fabric. Color strength ( K/ S values), L, a*, and b* values were measured. The color fastness values (to rubbing, light, perspiration, washing) of azo compounds on cotton fabric were presented according to ISO standards for comparison. Antibacterial activity assessment of the colored fabrics was performed according to AATCC 147-2016 test method against two types of bacteria: Staphylococcus aureus and Klebsiella pneumoniae. The fabric dyed with 2-methyl-4-[pyridin-3-yldiazenyl]benzene-1,3-diol demonstrated acceptable antibacterial activity against S. aureus.
在 NaNO2 和 HCl 的存在下,通过重氮化苯胺和 3- 氨基吡啶,然后在碱性介质中与 2-甲基间苯二酚偶联,合成了新型偶氮化合物。利用傅立叶变换红外光谱、1H NMR 和 13C NMR 分析对这些化合物的结构进行了表征。本研究的主要目的是调查新偶氮结构在纺织工业中的着色应用以及抗菌和牢度特性。棉织物采用了排气染色工艺。测量了色强度(K/S 值)、L、a* 和 b* 值。偶氮化合物在棉织物上的色牢度值(耐摩擦、耐光、耐汗渍、耐洗涤)根据 ISO 标准进行了比较。根据 AATCC 147-2016 测试方法,对有色织物的抗菌活性进行了评估:金黄色葡萄球菌和肺炎克雷伯菌。使用 2-甲基-4-[吡啶-3-基二苯乙烯基]苯-1,3-二醇染色的织物对金黄色葡萄球菌具有可接受的抗菌活性。
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引用次数: 0
The Impact of Miss Stitch on the Dimensional Properties and Stability of Double Weft Knitted Fabrics after Dry and Washing Relaxations 纰针对双纬针织物干洗松弛后的尺寸特性和稳定性的影响
IF 0.7 4区 工程技术 Q4 Materials Science Pub Date : 2024-04-04 DOI: 10.1177/24723444241237314
Nadiia P Bukhonka
This study investigated the effect of the rib set-out repeat and single miss stitches on the structural properties and dimensional stability of double weft knitted fabrics compared with half Milano rib. Nine variations of double weft knitted fabrics were produced, each with a different number of inactive needles at the width repeat Rb. The fabrics were tested after 10 days of dry relaxation and five washings. The fabric’s structural repeat at the height Rh consisted of a combination of two courses, rib and plain (variant 1), and rib set-out and single with miss (float) stitch, with stitch repeats varying at the width Rb (for variants 2–10). The miss stitch was made on the technical back of the knitted fabrics, and the number of inactive needles during the production of the single and double stitches ranged from 1 to 3. The fabrics were manufactured using a 10-gauge flat bed-knitting machine from blended wool/PAN (60% wool, 40% PAN) 25×2tex×2 yarn. The results demonstrated that the width repeat of miss knit stitches Rb (different numbers of knit and miss loop stitches) plays a crucial role in determining the dimensional stability and structural properties of double knitted fabrics. The number of washing cycles did not significantly impact the structural properties (around ±5%). The research results demonstrated shrinkage in the length and width directions, specifically after the first two washing cycles. The rib set-out repeat and single miss stitches affect dimensional changes in both directions: an increase in the number of inactive needles increases shrinkage in the length and decreases shrinkage in the width direction. Overall, this study highlights the importance of the number and placement of miss stitches during the design process of double weft knitted fabrics, particularly when aiming to achieve specific structural and dimensional properties.
与半米兰罗纹相比,本研究调查了罗纹设置重复次数和单失误针迹对双纬针织物结构特性和尺寸稳定性的影响。研究人员生产了九种不同的双纬针织物,每种织物在幅宽重复Rb上都有不同数量的非活动针。织物在经过 10 天的干松和五次水洗后进行了测试。织物在高度 Rh 上的结构重复由罗纹和平纹(变体 1)以及罗纹套色和单针错针(浮针)两道组合而成,在宽度 Rb 上的针迹重复次数各不相同(变体 2-10)。织物是用 10 号横机从羊毛/PAN 混纺(60% 羊毛,40% PAN)25×2tex×2 纱线织成的。结果表明,漏针宽度重复数 Rb(编织针数和漏圈针数不同)在决定双面针织物的尺寸稳定性和结构特性方面起着至关重要的作用。水洗次数对结构特性的影响不大(约为 ±5%)。研究结果表明,织物在长度和宽度方向上都出现了缩水,尤其是在头两次水洗之后。罗纹设置重复和单针失针会影响两个方向的尺寸变化:非活动针数的增加会增加长度方向的收缩率,减少宽度方向的收缩率。总之,这项研究强调了在双纬针织物的设计过程中,失针数量和位置的重要性,尤其是在旨在实现特定的结构和尺寸特性时。
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引用次数: 0
Sustaining Natural Dye Plants with Post-Consumer Textile Waste 利用消费后纺织废料维持天然染料厂的发展
IF 0.7 4区 工程技术 Q4 Materials Science Pub Date : 2024-02-18 DOI: 10.1177/24723444241230120
Helen X. Trejo, Nidia K Trejo, Tasha L. Lewis
Aligned with the circular economy framework, this study aims to address pertinent research gaps regarding material and chemical properties of clothing and suitability for closed-loop applications. Primary research questions include: (1) what are the material and chemical properties of post-consumer textile waste from a sustainable fashion take-back program; (2) which natural post-consumer textile waste is most suitable to support the growth of natural dye plants in a hydroponics system; and (3) can the use of post-consumer textile waste in a hydroponics system be scaled to support a circular fashion supply chain? This study focuses on wool, cotton, linen, silk, rayon, and Tencel® lyocell as substrates to nurture the growth of purple basil, a natural dye plant. Vertical hydroponics is a farming method that uses nutrient water to grow plants in place of soil throughout the year. The system can be indoors, making resourceful use of limited space available and the water is recirculated. Standard hydroponic substrates, like peat moss and rockwool, have good porosity for oxygen transport and suitable moisture holding capacity for nutrient delivery. In this study, we compared the performance of the standard hydroponic substrates with various textiles. The impact on water quality, color release, moisture wicking, stability against degradation, and survival rate of the plants was used to evaluate suitability in the application. Wool, silk, and Tencel lyocell demonstrated good durability in the hydroponic system, like peat moss and rockwool, during the first growth cycle. During the second growth cycle, protein fibers—wool and silk—supported plant survival at a greater capacity than Tencel lyocell. Future research can confirm that wool and silk can support the growth of natural dye plants with a larger sample size. This research aligns with several circular economy objectives and provides a model for future research to support circular fashion supply chains.
根据循环经济框架,本研究旨在解决服装材料和化学特性以及闭环应用适用性方面的相关研究缺口。主要研究问题包括(1) 来自可持续时装回收计划的消费后纺织品废弃物的材料和化学特性是什么;(2) 哪些天然消费后纺织品废弃物最适合在水培系统中支持天然染料植物的生长;以及 (3) 在水培系统中使用消费后纺织品废弃物能否扩大规模,以支持循环时装供应链?本研究以羊毛、棉花、亚麻、丝绸、人造丝和 Tencel® lyocell 为基质,培育天然染色植物紫苏的生长。垂直水培法是一种全年使用营养水代替土壤种植植物的耕作方法。该系统可以在室内进行,充分利用有限的空间,而且水是循环流动的。标准的水培基质(如泥炭藓和岩棉)具有良好的孔隙度,有利于氧气的输送,并具有适当的保湿能力,有利于养分的输送。在这项研究中,我们比较了标准水培基质和各种纺织品的性能。通过对水质、颜色释放、吸湿性、降解稳定性和植物存活率的影响来评估其在应用中的适用性。在第一个生长周期,羊毛、丝绸和天丝纤维在水培系统中表现出良好的耐久性,就像泥炭藓和岩棉一样。在第二个生长周期中,蛋白质纤维-羊毛和蚕丝-支持植物存活的能力高于天丝纤维。未来的研究可以用更大的样本量来证实羊毛和蚕丝可以支持天然染料植物的生长。这项研究符合多个循环经济目标,为未来支持循环时尚供应链的研究提供了一个模型。
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引用次数: 0
Progress in Stability Adjustment of Photonic Crystal Coatings on Fabrics or Fiber: A Review 织物或纤维上光子晶体涂层的稳定性调整进展:综述
IF 0.7 4区 工程技术 Q4 Materials Science Pub Date : 2024-01-27 DOI: 10.1177/24723444231220700
Qingwen Shi, Xuyi Wang, Yin Fu, Islam Md Sarazul, Jiuxiao Sun, Xue Li, Jingchuan Hu, Haiying Tan
Photonic crystals with bright colors have shown great potential application in bio-sensing, anti-counterfeiting, and smart wear. Different methods are used to construct photonic crystals on fabrics using different raw materials. However, building photonic crystals on fibers or fabrics with vibrant colors and good stability is still challenging. Various strategies have been used to increase the stability (e.g. wash, bend, friction stability, and so on) of the photonic crystal coatings on the fabrics or fibers. Therefore, this paper reviews great efforts to construct photonic crystal-coated materials, the methods to increase the stability of photonic crystal coatings on the fabrics, and their possible applications. The summarization of this review may lay the foundation for the construction of photonic crystals on fabrics with high color fastness and application in fabric coloring.
色彩鲜艳的光子晶体在生物传感、防伪和智能穿戴等领域有着巨大的应用潜力。使用不同的原材料在织物上构建光子晶体的方法各不相同。然而,在纤维或织物上构建色彩鲜艳、稳定性好的光子晶体仍具有挑战性。为了提高织物或纤维上光子晶体涂层的稳定性(如洗涤、弯曲、摩擦稳定性等),人们采用了各种策略。因此,本文回顾了在构建光子晶体涂层材料方面所做的巨大努力、提高织物上光子晶体涂层稳定性的方法及其可能的应用。本综述的总结可为在织物上构建具有高色牢度的光子晶体并将其应用于织物着色奠定基础。
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引用次数: 0
An Experimental Study on EMI Shielding and Antibacterial Activity of Woven Fabrics Including Silver Nanocomposite Yarns 含银纳米复合纱线的机织物电磁干扰屏蔽和抗菌活性实验研究
IF 0.7 4区 工程技术 Q4 Materials Science Pub Date : 2024-01-18 DOI: 10.1177/24723444231212953
İ. İlhan, I. Özkan, Özlem Uslukul
This study investigates electromagnetic interference shielding and antibacterial activity of industrial polyester/viscose woven fabrics, including silver (Ag) treated yarns, to obtain multifunctional fabric. For this purpose, thin film-coated, nanoparticle-doped, and chemically treated yarns were used as weft in three different densities. Nine fabric samples and the control sample were woven under industrial conditions. As a result, the surface conductivity of the thin film-coated samples is significantly higher than the others in all the measurement directions. Also, these samples exhibit the best electromagnetic shielding efficiency of up to 64 dB in the 3–43 GHz frequency range. In addition, electromagnetic shielding efficiency reaches 83 dB when the samples are measured in multiple layers. The chemically treated samples exhibited better antibacterial activity, up to 74%. It was determined that the nanoparticle’s treatment type, position and density, and the number of fabric layers influence the performance properties.
本研究调查了工业涤纶/粘胶机织物(包括银(Ag)处理纱线)的电磁干扰屏蔽和抗菌活性,以获得多功能织物。为此,研究人员使用了三种不同密度的薄膜涂层纱线、纳米粒子掺杂纱线和化学处理纱线作为纬纱。在工业条件下编织了九种织物样品和对照样品。结果发现,在所有测量方向上,薄膜涂层样品的表面电导率都明显高于其他样品。同时,在 3-43 GHz 频率范围内,这些样品的电磁屏蔽效率最高可达 64 dB。此外,在对样品进行多层测量时,电磁屏蔽效率可达 83 dB。经过化学处理的样品具有更好的抗菌活性,最高可达 74%。结果表明,纳米粒子的处理类型、位置和密度以及织物层数都会影响性能特性。
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引用次数: 0
Effect of Microwave Irradiation on Coloring and Mechanical Properties of Direct Dyed Fabric 微波辐照对直接染色织物着色和机械性能的影响
IF 0.7 4区 工程技术 Q4 Materials Science Pub Date : 2023-12-22 DOI: 10.1177/24723444231215446
Assad Farooq, Ifra Shahzadi, M. A. Ashraf, Farida Irshad, Nayab Khan
Microwaves have a very short wavelength which allows them to pass through the small spaces between molecules without being scattered. This allows the microwaves to penetrate the matter and heat it from the inside out, providing uniform heat, and makes microwave technology ideal for applications that require rapid and consistent heating. It has been hypothesized that microwaves may have a positive effect on the shade depth and color fastness of the fabric due to the increased temperature. This research is being done to test this hypothesis and to study the effects of microwaves on the shade depth and color fastness properties of the fabric. Microwave-irradiated fabric dyed before and after dyeing has a greater shade depth and better fastness properties than fabric dyed without irradiation.
微波的波长很短,可以穿过分子之间的微小空隙而不被散射。这使得微波可以穿透物质,从内向外加热,提供均匀的热量,使微波技术成为需要快速和持续加热的应用的理想选择。据推测,由于温度升高,微波可能会对织物的色深和色牢度产生积极影响。这项研究就是为了验证这一假设,并研究微波对织物色深和色牢度特性的影响。与未经辐照而染色的织物相比,在染色前后经过微波辐照的织物具有更大的色深和更好的牢度特性。
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引用次数: 0
Statistical Optimization of Process Variables for the Dyeing of Jute with Marigold Petals Using a Dual Mordant System 使用双媒染剂系统对万寿菊花瓣染色黄麻的工艺变量进行统计优化
IF 0.7 4区 工程技术 Q4 Materials Science Pub Date : 2023-12-21 DOI: 10.1177/24723444231201452
Ritwik Chakraborty, Ashis Kumar Samanta, P. S. Vankar
Natural dye was extracted from the petals of orange-colored marigold flowers in aqueous medium, and extraction process parameters were optimized based on the color yield (optical density) of an aqueous extract of marigold petals. The extracted natural colorant was used to dye jute fabric and characterized by ultraviolet–visible spectroscopy. Extracts from gallnut and natural alum (fitkiri) were applied as mordants onto the bleached jute fabric by padding method followed by drying in air. The fabrics were treated with the mordants separately before dyeing, and then, both mordants were applied in sequence. Jute was premordanted first with gallnut followed by alum. Jute fibers were mordanted prior to dyeing with either gallnut or alum or both mordants (gallnut followed by alum treatment). Premordanted jute fabric was dyed with the natural dye extracted from marigold petals, and process conditions were standardized. The dual-mordanting process was found more effective to produce better color yield than the single mordanting process. Standardization of the process conditions was also examined statistically by the Box–Behnken design method after choosing the significant variables by the Plackett–Burman design method. The standardized dyeing process conditions were found to be dyeing temperature: 90°C; material to liquor ratio: 1:40; dyeing time: 60 min; dye concentration: 30% o.w.f.; and pH: 11.
在水介质中从橙色万寿菊花瓣中提取天然染料,并根据万寿菊花瓣水提取物的得色率(光密度)对提取工艺参数进行了优化。提取的天然着色剂被用于黄麻织物的染色,并通过紫外可见光谱进行表征。用轧染法将五倍子提取物和天然明矾(fitkiri)作为媒染剂涂在漂白黄麻织物上,然后在空气中干燥。织物在染色前分别用媒染剂处理,然后依次使用两种媒染剂。先用五倍子对黄麻进行预媒介处理,然后再用明矾。黄麻纤维在染色前用五倍子或明矾或两种媒染剂(先五倍子后明矾)进行媒染。用从万寿菊花瓣中提取的天然染料对预搀和黄麻织物进行染色,并对工艺条件进行标准化。结果发现,双媒染法比单媒染法更有效,能产生更好的得色率。在用普拉克特-伯曼设计法选出显著变量后,还用方框-贝肯设计法对工艺条件的标准化进行了统计检验。标准化染色工艺条件为:染色温度:90°C;料液比:1:40;染色时间:60 分钟;染料浓度:30%(含水率):30% o.w.f.;pH 值:11。
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引用次数: 0
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AATCC Journal of Research
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