过乙酸处理是防止紫外线照射下木材变色的有效方法

Kyoung-Chan Park, Byeongho Kim, Hanna Park, Se-Yeong Park
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引用次数: 2

摘要

木材一直被用于各种日常应用,如室内或室外建筑材料和家用产品。然而,它会受到包括紫外线在内的环境因素的光降解和变色,从而缩短了它的使用寿命。木材表面的漂白或脱木素是稳定木材免受紫外线风化的合适解决方案,因为这些技术可以改变或去除木质素中的发色团,而发色团是木材变色的主要因素。为了根据使用寿命提高木材表面的颜色稳定性,采用过乙酸(PAA)和过氧化氢(HP)对日本落叶松和蒙古栎木材进行了表面脱木素处理。PAA处理后,L*从60-70显著增加到90-95。此外,木材表面颜色在紫外线照射后没有显著变化。木材PPA处理前后的色差(ΔE*)分别为山柰4.8–12.2和蒙古栎1.7–3.7。傅立叶变换红外光谱(FT-IR)中的木质素相关峰随着PAA处理时间的增加而消失。这些结果证实在PAA处理后木质素组分被部分或完全去除;色差(ΔE*)清楚地表明,由于木质素的去除,红色(a*)和黄色(b*)减少,亮度(L*)增加。基于这些结果,本研究表明,从木材表面部分去除木质素是解决光降解的基本方法。
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Peracetic Acid Treatment as an Effective Method to Protect Wood Discoloration by UV Light
Wood has always been used for various day-to-day applications such as interior or exterior construction materials, and household products. However, it can undergo photodegradation and discoloration by environmental factors including ultraviolet (UV) light, and thus has shortened its service life. Bleaching or delignification of wood surfaces is a suitable solution to stabilize wood against weathering by UV because these techniques can alter or remove the chromophores in lignin, which is a main factor of wood discoloration. To improve the color stability of wood surface according to the lifespan, surface delignification was conducted using peracetic acid (PAA) and hydrogen peroxide (HP) on the woods of Larix kaempferi and Quercus mongolica . After the PAA treatment, L* increased considerably from 60 – 70 to 90 – 95. Furthermore, wood surface color did not change significantly after UV exposure. The color differences ( Δ E *) between before and after PPA treatment of wood showed the 4.8 – 12.2 of L. kaempferi , and 1.7 – 3.7 of Q. mongolica , respectively. The lignin-related peaks in Fourier transform infrared spectroscopy (FT-IR) spectra disappeared with increased duration of PAA treatment. These results confirmed that the lignin component was partially or completely removed after the PAA treatment; the color differences ( Δ E* ) clearly showed that there was a reduction in redness ( a* ) and yellowness ( b* ), and an increase in lightness ( L* ) owing to the removal of lignin. Based on these results, this study demonstrated that the partial removal of lignin from wood surfaces is a fundamental method for resolving photo-degradation.
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来源期刊
Journal of the Korean wood science and technology
Journal of the Korean wood science and technology Materials Science-Materials Science (miscellaneous)
CiteScore
5.20
自引率
0.00%
发文量
32
期刊介绍: The Journal of the Korean Wood Science and Technology (JKWST) launched in 1973 as an official publication of the Korean Society of Wood Science and Technology has been served as a core of knowledges on wood science and technology. The Journal acts as a medium for the exchange of research in the area of science and technology related to wood, and publishes results on the biology, chemistry, physics and technology of wood and wood-based products. Research results about applied sciences of wood-based materials are also welcome. The Journal is published bimonthly, and printing six issues per year. Supplemental or special issues are published occasionally. The abbreviated and official title of the journal is ''J. Korean Wood Sci. Technol.''. All submitted manuscripts written in Korean or English are peer-reviewed by more than two reviewers. The title, abstract, acknowledgement, references, and captions of figures and tables should be provided in English for all submitted manuscripts.
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