说明催化与手工分子模型集:催化氧化一氧化碳在铂表面

IF 2.2 Q2 EDUCATION, SCIENTIFIC DISCIPLINES Chemistry Teacher International : best practices in chemistry education Pub Date : 2021-08-02 DOI:10.1515/cti-2021-0010
R. Horikoshi, Syota Nakajima, S. Hosokawa, Y. Kobayashi, H. Kageyama
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引用次数: 2

摘要

催化转化器(汽车催化剂)及其催化的化学反应出现在一般和入门化学教科书中。虽然催化转化器中发生的化学反应的详细机制已经通过最近的表面化学和计算化学研究的发展清楚地揭示出来,但在教科书中对催化的描述和说明仍然是模糊的。在本文中,我们描述了一个课外讲座,其中使用手工教具来说明一氧化碳在铂表面催化氧化的基本原理,这是催化转化器中发生的重要反应。该教具结合了容易获得的材料,可以说明催化氧化过程中分子在铂表面的位置和运动。讲座受到非化学专业学生和高中生的好评。尽管这个话题很困难,但观众的理解程度还是比较高的。
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Illustrating catalysis with a handmade molecular model set: catalytic oxidation of carbon monoxide over a platinum surface
Abstract Catalytic converters (automotive catalysts) and the chemical reactions they catalyze appear in general and introductory chemistry textbooks. Although the detailed mechanisms of the chemical reactions that occur in catalytic converters have been clearly revealed via recent developments in surface and computational chemistry research, the description and illustration of the catalysis are still ambiguous in textbooks. In this paper, we describe an extracurricular lecture whereby a handmade teaching aid was employed to illustrate the basic principle of the catalytic oxidation of carbon monoxide over platinum surface, which is an essential reaction occurring in catalytic converters. The teaching aid, constructed combining easily available materials, can illustrate the positions and motions of the molecules on the platinum surface during catalytic oxidation. The lecture was favorably received by non-chemistry majors and high school students. Despite the difficulty of the topic, the audience displayed a relatively high level of understanding.
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