{"title":"新型铜前驱体热分解法制备的CuO/Cu2O纳米复合材料的制备、结构表征、光学性能和抗菌活性","authors":"A. D. Khalaji, M. Jarošová, P. Machek","doi":"10.22038/NMJ.2020.07.0007","DOIUrl":null,"url":null,"abstract":"Objective(s): In this study, a new copper precursor was prepared from the combination of Cu(CH3COO)2∙H2O (1 g in 5 ml of methanol) and benzoic acid (1 g in 5 ml of methanol) at room temperature. Following that, the copper precursor was calcined at the temperature of 500oC and 600oC for 1.5 hours to form CuO/Cu2O nanocomposites with the code numbers of CuO-1 and CuO-2, respectively. Materials and Methods: The prepared CuO/Cu2O nanocomposites were characterized by Fourier Transform infrared (FT-IR), UV-Vis, and photoluminescence (PL) spectroscopy, X-ray powder diffraction (XRD), and transmission electron microscopy (TEM). Results: The results of the FT-IR and XRD techniques confirmed the formation of the CuO/Cu2O nanocomposites. In the UV-Vis of CuO/Cu2O nanocomposites, two peaks were observed at approximately 216 and 277 nanometers, which were assigned to the direct transition of electrons and surface plasmon resonance. In addition, the TEM images indicated that the CuO/Cu2O nanocomposites had diverse shapes with high agglomeration. The antibacterial results also showed that the inhibitory effects of the prepared CuO/Cu2O nanocomposites (CuO-1 and CuO-2) were more significant against the two gram negative strains compared to the two gram positive strains.","PeriodicalId":18933,"journal":{"name":"Nanomedicine Journal","volume":"7 1","pages":"231-236"},"PeriodicalIF":1.4000,"publicationDate":"2020-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"The Preparation, structural characterization, optical properties, and antibacterial activity of the CuO/Cu2O nanocomposites prepared by the facile thermal decomposition of a new copper precursor\",\"authors\":\"A. D. Khalaji, M. Jarošová, P. Machek\",\"doi\":\"10.22038/NMJ.2020.07.0007\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Objective(s): In this study, a new copper precursor was prepared from the combination of Cu(CH3COO)2∙H2O (1 g in 5 ml of methanol) and benzoic acid (1 g in 5 ml of methanol) at room temperature. Following that, the copper precursor was calcined at the temperature of 500oC and 600oC for 1.5 hours to form CuO/Cu2O nanocomposites with the code numbers of CuO-1 and CuO-2, respectively. Materials and Methods: The prepared CuO/Cu2O nanocomposites were characterized by Fourier Transform infrared (FT-IR), UV-Vis, and photoluminescence (PL) spectroscopy, X-ray powder diffraction (XRD), and transmission electron microscopy (TEM). Results: The results of the FT-IR and XRD techniques confirmed the formation of the CuO/Cu2O nanocomposites. In the UV-Vis of CuO/Cu2O nanocomposites, two peaks were observed at approximately 216 and 277 nanometers, which were assigned to the direct transition of electrons and surface plasmon resonance. In addition, the TEM images indicated that the CuO/Cu2O nanocomposites had diverse shapes with high agglomeration. The antibacterial results also showed that the inhibitory effects of the prepared CuO/Cu2O nanocomposites (CuO-1 and CuO-2) were more significant against the two gram negative strains compared to the two gram positive strains.\",\"PeriodicalId\":18933,\"journal\":{\"name\":\"Nanomedicine Journal\",\"volume\":\"7 1\",\"pages\":\"231-236\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2020-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanomedicine Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22038/NMJ.2020.07.0007\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"NANOSCIENCE & NANOTECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanomedicine Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22038/NMJ.2020.07.0007","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"NANOSCIENCE & NANOTECHNOLOGY","Score":null,"Total":0}
引用次数: 3
摘要
目的:在本研究中,由Cu(CH3COO)2∙H2O(1 g在5 ml甲醇中)和苯甲酸(1 g In 5 ml甲醇)在室温下制备了一种新的铜前体。随后,将铜前体在500℃和600℃的温度下煅烧1.5小时,以形成代号分别为CuO-1和CuO-2的CuO/Cu2O纳米复合材料。材料与方法:采用傅立叶变换红外光谱、紫外-可见光谱、光致发光光谱、X射线粉末衍射和透射电子显微镜对制备的CuO/Cu2O纳米复合材料进行了表征。结果:FT-IR和XRD技术证实了CuO/Cu2O纳米复合材料的形成。在CuO/Cu2O纳米复合材料的UV-Vis中,在大约216和277纳米处观察到两个峰,这两个峰被认为是电子的直接跃迁和表面等离子体共振。此外,TEM图像表明,CuO/Cu2O纳米复合材料具有不同的形状,具有较高的团聚度。抗菌结果还表明,与两克阳性菌株相比,所制备的CuO/Cu2O纳米复合材料(CuO-1和CuO-2)对两克阴性菌株的抑制作用更显著。
The Preparation, structural characterization, optical properties, and antibacterial activity of the CuO/Cu2O nanocomposites prepared by the facile thermal decomposition of a new copper precursor
Objective(s): In this study, a new copper precursor was prepared from the combination of Cu(CH3COO)2∙H2O (1 g in 5 ml of methanol) and benzoic acid (1 g in 5 ml of methanol) at room temperature. Following that, the copper precursor was calcined at the temperature of 500oC and 600oC for 1.5 hours to form CuO/Cu2O nanocomposites with the code numbers of CuO-1 and CuO-2, respectively. Materials and Methods: The prepared CuO/Cu2O nanocomposites were characterized by Fourier Transform infrared (FT-IR), UV-Vis, and photoluminescence (PL) spectroscopy, X-ray powder diffraction (XRD), and transmission electron microscopy (TEM). Results: The results of the FT-IR and XRD techniques confirmed the formation of the CuO/Cu2O nanocomposites. In the UV-Vis of CuO/Cu2O nanocomposites, two peaks were observed at approximately 216 and 277 nanometers, which were assigned to the direct transition of electrons and surface plasmon resonance. In addition, the TEM images indicated that the CuO/Cu2O nanocomposites had diverse shapes with high agglomeration. The antibacterial results also showed that the inhibitory effects of the prepared CuO/Cu2O nanocomposites (CuO-1 and CuO-2) were more significant against the two gram negative strains compared to the two gram positive strains.