{"title":"巯基乙酸乙酯作抑制剂分离黄铜矿和钼矿的浮选行为及机理研究","authors":"Xiaofeng Yang, Xukun Zhao, Yao-yao Liu","doi":"10.37190/ppmp/162824","DOIUrl":null,"url":null,"abstract":"The effect of ethyl thioglycolate organic small molecule inhibitors on chalcopyrite molybdenite flotation behaviour is investigated via single mineral micro-flotation tests, zeta potential tests, and X-ray photoelectron spectroscopy (XPS) analysis. Results of the flotation test indicate that ethyl thioglycolate organic small-molecule inhibitors can effectively separate Cu and Mo and selectively inhibit chalcopyrite under weak alkaline conditions. Infrared spectroscopy and XPS analysis show that hydrophilic functional groups C=O and -COOH in the ethyl thioglycolate organic small molecules can chemically adsorb onto the chalcopyrite surface. Moreover, ethyl thioglycolate has no obvious effect on zeta potential of molybdenite. Therefore, ethyl thioglycolate can effectively separate chalcopyrite and molybdenite.","PeriodicalId":49137,"journal":{"name":"Physicochemical Problems of Mineral Processing","volume":" ","pages":""},"PeriodicalIF":1.3000,"publicationDate":"2023-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on flotation behavior and mechanism of separating chalcopyrite and Molybdenite with ethyl mercaptoglycolate as inhibitor\",\"authors\":\"Xiaofeng Yang, Xukun Zhao, Yao-yao Liu\",\"doi\":\"10.37190/ppmp/162824\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The effect of ethyl thioglycolate organic small molecule inhibitors on chalcopyrite molybdenite flotation behaviour is investigated via single mineral micro-flotation tests, zeta potential tests, and X-ray photoelectron spectroscopy (XPS) analysis. Results of the flotation test indicate that ethyl thioglycolate organic small-molecule inhibitors can effectively separate Cu and Mo and selectively inhibit chalcopyrite under weak alkaline conditions. Infrared spectroscopy and XPS analysis show that hydrophilic functional groups C=O and -COOH in the ethyl thioglycolate organic small molecules can chemically adsorb onto the chalcopyrite surface. Moreover, ethyl thioglycolate has no obvious effect on zeta potential of molybdenite. Therefore, ethyl thioglycolate can effectively separate chalcopyrite and molybdenite.\",\"PeriodicalId\":49137,\"journal\":{\"name\":\"Physicochemical Problems of Mineral Processing\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2023-03-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physicochemical Problems of Mineral Processing\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.37190/ppmp/162824\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physicochemical Problems of Mineral Processing","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.37190/ppmp/162824","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Study on flotation behavior and mechanism of separating chalcopyrite and Molybdenite with ethyl mercaptoglycolate as inhibitor
The effect of ethyl thioglycolate organic small molecule inhibitors on chalcopyrite molybdenite flotation behaviour is investigated via single mineral micro-flotation tests, zeta potential tests, and X-ray photoelectron spectroscopy (XPS) analysis. Results of the flotation test indicate that ethyl thioglycolate organic small-molecule inhibitors can effectively separate Cu and Mo and selectively inhibit chalcopyrite under weak alkaline conditions. Infrared spectroscopy and XPS analysis show that hydrophilic functional groups C=O and -COOH in the ethyl thioglycolate organic small molecules can chemically adsorb onto the chalcopyrite surface. Moreover, ethyl thioglycolate has no obvious effect on zeta potential of molybdenite. Therefore, ethyl thioglycolate can effectively separate chalcopyrite and molybdenite.
期刊介绍:
Physicochemical Problems of Mineral Processing is an international, open access journal which covers theoretical approaches and their practical applications in all aspects of mineral processing and extractive metallurgy.
Criteria for publication in the Physicochemical Problems of Mineral Processing journal are novelty, quality and current interest. Manuscripts which only make routine use of minor extensions to well established methodologies are not appropriate for the journal.
Topics of interest
Analytical techniques and applied mineralogy
Computer applications
Comminution, classification and sorting
Froth flotation
Solid-liquid separation
Gravity concentration
Magnetic and electric separation
Hydro and biohydrometallurgy
Extractive metallurgy
Recycling and mineral wastes
Environmental aspects of mineral processing
and other mineral processing related subjects.