bi2moo6 /GO纳米片光降解直接紫51染料的研究

Q4 Agricultural and Biological Sciences Proceedings of the Pakistan Academy of Sciences: Part B Pub Date : 2023-02-15 DOI:10.53560/ppasb(60-1)796
H. Bhatti, Sumaira Younis, S. Bajwa, Jie Xu, Saba Jamil
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引用次数: 0

摘要

水污染是维持环境可持续性的一个具有挑战性的问题。工业废水被认为是水污染的主要来源,影响地表水和地下水的水质。本研究介绍了半导体钼酸铋/氧化石墨烯(Bi2MoO6/GO)复合纳米材料作为太阳能光驱动催化剂,用于光降解直接紫(DV) 51染料和工业废水。利用扫描电镜(SEM)、zeta电位、x射线衍射分析和傅里叶变换红外光谱(FTIR)对Bi2MoO6 /GO复合材料进行了表征。实验结果表明,片状Bi2MoO6 /GO复合材料在80分钟内对DV染料的降解活性为99.00%。在pH为7时,Bi2MoO6 /GO纳米片对DV染料的降解率为98.70%,在100mg的催化剂剂量下,降解率在60分钟内分别达到99.99%。稳定性/可重用性研究表明,通过优化实验参数,在80分钟内,染料在第1天至第7天的降解率为99.82% ~ 93.84%。根据实验结果的动力学研究,拟一阶模型与所得数据拟合最佳,决定系数R2=0.954。此外,在对工业废水的光降解研究中,化学需氧量(COD)降低了69.23%。结果表明,Bi2MoO6 /GO纳米片具有良好的光催化潜力和稳定性,可降解有机水污染物。这些材料可以有效地用于光降解有机水污染物,提高环境安全性。
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Photodegradation of Direct Violet 51 Dye using Bi2 MoO6 /GO Nanoflakes as Promising Solar Light-driven Photocatalys
Water contamination is a challenging issue for the maintenance of environmental sustainability. Industrial effluents are considered major sources of water pollution which affect the quality of surface as well as ground water. In the present research work, semiconducting Bismuth Molybdate/Graphene Oxide (Bi2MoO6/GO) composite nanomaterial has been introduced as the solar light-driven catalyst for photodegradation of Direct Violet (DV) 51 dye and industrial wastewater. Scanning electron microscope (SEM), zeta potential, X-ray diffraction analysis and Fourier transform infrared spectroscopy (FTIR) were used to characterize the Bi2MoO6 /GO composite material. Experimental findings revealed that flake-like Bi2MoO6 /GO composite exhibits 99.00 % degradation activity against DV dye within 80 minutes. Bi2MoO6 /GO nanoflakes degrade DV dye up to 98.70 % at pH 7 and 99.99 % with a 100 mg catalyst dose within 60 minutes, respectively. The stability/reusability study presented 99.82 % - 93.84 % dye degradation from the 1st to 7th day within 80 minutes while optimizing experimental parameters. According to kinetic studies of experimental outcomes, the pseudo-first-order model was best fitted to the obtained data with a coefficient of determination R2=0.954. Moreover, a 69.23 % reduction was observed in chemical oxygen demand (COD) during the photodegradation study of industrial wastewater. Results indicate that Bi2MoO6 /GO nanoflakes have good photocatalytic potential and stability to degrade organic water pollutants under sunlight. Such materials can be used effectively for the photodegradation of organic water pollutants to enhance environmental safety.
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Proceedings of the Pakistan Academy of Sciences: Part B
Proceedings of the Pakistan Academy of Sciences: Part B Agricultural and Biological Sciences-Agricultural and Biological Sciences (all)
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