{"title":"脉冲电位电沉积法制备还原性氧化石墨烯/锌纳米复合镀层及其耐蚀性","authors":"S. Asl, A. Afshar, Y. Yaghoubinezhad","doi":"10.1155/2018/3028693","DOIUrl":null,"url":null,"abstract":"Pulse-potential coelectrodeposition of reduced graphene oxide/zinc (rGO-Zn) nanocomposite coating is directly controlled upon a steel substrate from a one-pot aqueous mixture containing [GO−/Zn2+]δ+ nanoclusters. GO nanosheets are synthesized by modified Hummer’s approach while Zn cations are produced in the solution and deposited on GO nanosheets using anodic dissolution technique. Eventually, nanoclusters are reduced to rGO-Zn film through an electrochemical process. Chemical composition, surface morphology, and corrosion resistance of the thin film are characterized. Results show that the corrosion resistance of rGO-Zn coating is approximately 10 times more than the bare steel.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2018-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/3028693","citationCount":"19","resultStr":"{\"title\":\"An Electrochemical Synthesis of Reduced Graphene Oxide/Zinc Nanocomposite Coating through Pulse-Potential Electrodeposition Technique and the Consequent Corrosion Resistance\",\"authors\":\"S. Asl, A. Afshar, Y. Yaghoubinezhad\",\"doi\":\"10.1155/2018/3028693\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Pulse-potential coelectrodeposition of reduced graphene oxide/zinc (rGO-Zn) nanocomposite coating is directly controlled upon a steel substrate from a one-pot aqueous mixture containing [GO−/Zn2+]δ+ nanoclusters. GO nanosheets are synthesized by modified Hummer’s approach while Zn cations are produced in the solution and deposited on GO nanosheets using anodic dissolution technique. Eventually, nanoclusters are reduced to rGO-Zn film through an electrochemical process. Chemical composition, surface morphology, and corrosion resistance of the thin film are characterized. Results show that the corrosion resistance of rGO-Zn coating is approximately 10 times more than the bare steel.\",\"PeriodicalId\":13893,\"journal\":{\"name\":\"International Journal of Corrosion\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2018-04-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1155/2018/3028693\",\"citationCount\":\"19\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Corrosion\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2018/3028693\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Corrosion","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2018/3028693","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
An Electrochemical Synthesis of Reduced Graphene Oxide/Zinc Nanocomposite Coating through Pulse-Potential Electrodeposition Technique and the Consequent Corrosion Resistance
Pulse-potential coelectrodeposition of reduced graphene oxide/zinc (rGO-Zn) nanocomposite coating is directly controlled upon a steel substrate from a one-pot aqueous mixture containing [GO−/Zn2+]δ+ nanoclusters. GO nanosheets are synthesized by modified Hummer’s approach while Zn cations are produced in the solution and deposited on GO nanosheets using anodic dissolution technique. Eventually, nanoclusters are reduced to rGO-Zn film through an electrochemical process. Chemical composition, surface morphology, and corrosion resistance of the thin film are characterized. Results show that the corrosion resistance of rGO-Zn coating is approximately 10 times more than the bare steel.