HCl浓度改性剂对氧化石墨烯/还原氧化石墨烯(GO/rGO)从鸡泡炭中剥离的影响

E. Hastuti, Feny Fefiyanti, M. Muthmainnah
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引用次数: 0

摘要

鸡肉消费量的增加可能会对鸡毛的浪费产生影响。已经做出了一些努力来处理鸡毛垃圾,这些垃圾很难分解并且会污染环境。鸡毛是一种具有高角蛋白含量的生物质,有潜力用作碳材料。在本研究中,将鸡毛用于化学剥落方法,以生产还原氧化石墨烯(rGO)材料。鸡毛分两个阶段加热,温度分别为250和400℃。用不同浓度的HCl(0、0.5、1、1.5和2M)进行剥离程序。X射线衍射光谱显示,样品具有rGO型碳相,晶体尺寸随着HCl浓度的增加而减小。FTIR光谱揭示了被鉴定为GO/rGO的官能团C-O、C=C和C-OH的存在。HCl剥离过程降低了样品的电导率和电容,在最水样品(GO-0 M)中获得的最高值约为10-5S/M和10-7F/m2。
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Pengaruh Konsentrasi HCl Pada Proses Exfoliasi Graphene Oxide/Reduce Graphene Oxide (GO/rGO) Dari Karbon Bulu Ayam

An increase in the consumption of chicken meat may have an impact on the waste of chicken feathers. Several efforts have been made to treat chicken feather waste, which is difficult to decompose and can pollute the environment. Chicken feathers are biomass with a high keratin content that has the potential to be used as a carbon material. In this study, chicken feathers were used in the chemical exfoliation method to produce reduced Graphene Oxide (rGO) material. Chicken feathers are heated in two stages, at temperatures of 250 and 400 ℃ in the air. The exfoliation procedure was carried out with varying concentrations of HCl (0, 0.5, 1, 1.5, and 2 M). The X-ray diffraction spectra revealed that the sample had a rGO type carbon phase, with the crystal size decreasing as the HCl concentration increased. The presence of functional groups C-O, C=C, and C-OH identified as GO/rGO was revealed by FTIR spectra. The HCl exfoliation process reduced the sample's conductivity and capacitance, with the highest values obtained in aquadest sample (GO-0 M), about 10-5 S/m and 10-7 F/m2.

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