甘薯衍生的碳纳米片包含NiCo2O4纳米复合材料作为超级电容器的电极材料

Muhammadin Hamid , Martha Rianna , Maria Derani Ester Vania , Iga Dwi Yanti , Fadhilah Aulia Annisa Manurung , Richi Afriandani , Amru Daulay
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摘要

由于由碳和过渡金属氧化物组成的复合电极有很大的潜力成为未来储能系统的最佳电极类型,因此采用低温溶液生长法从甘薯中制备碳框架,并将NiCo2O4纳米颗粒附着在其上。该方法操作简单,成本低廉,可用于大规模商业化生产。FTIR光谱在波数857 cm−1处有Ni-O、Co-O和弯曲官能团的峰带。XRD显示了水晶飞机(1 1 1),(2 2 0),(3 3 1),(2 2 2),(4 0 0)(4 2 2)(5 1(1)和(4 4 0)在2θ= 18.97°,31.97°,37.51°、38.10°、44.55°、55.51°、58.65°,64.92°,表示NiCo2O4。23.3°左右的典型宽峰可以连接到非晶碳的(0 0 2)晶格面。NiCo2O4/C样品的晶粒平均尺寸为21.5±0.5 nm。VSM表明NiCo2O4/C具有较强的磁性。从形成的CV曲线可以看出,NiCo2O4/C-2.8具有平衡的阴极和阳极曲线,且电流密度高于其他材料。结果表明,NiCo2O4/C-2.8具有较高的电子迁移能力。在NiCo2O4中加入碳混合物的变化数显示了比电容。结果表明,碳会阻碍NiCo2O4中电子的移动,导致性能下降。适量的碳可以提高电子传递能力。
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Sweet potato‑derived carbon nanosheets incorporate NiCo2O4 nanocomposite as electrode materials for supercapacitors

Since a composite electrode made of carbon and transition metal oxides has much potential to be the best electrode type for a future energy storage system, the low-temperature solution growth method was used to make a carbon framework from sweet potato with NiCo2O4 nanoparticles attached to it. This method is easy, cheap, and can be used for large-scale commercial production. FTIR spectra a peak band of Ni-O and Co-O and the bending functional group at wave number 857 cm−1. XRD shows the crystal planes (1 1 1), (2 2 0), (3 3 1), (2 2 2), (4 0 0), (4 2 2), (5 1 1), and (4 4 0) at 2θ = 18.97°, 31.97°, 37.51°, 38.10°, 44.55°, 55.51°, 58.65°, and 64.92°, which indicates the NiCo2O4. The typical broad peaks around 23.3° can be linked to (0 0 2) lattice planes of amorphous carbon. The average size of the grains in the NiCo2O4/C samples was found to be 21.5 ± 0.5 nm. VSM shows that NiCo2O4/C has strong magnet properties. Based on the CV curve formed, it can be seen that NiCo2O4/C-2.8 has a balanced cathodic and anodic curve and also a higher current density than the others. It shows that NiCo2O4/C-2.8 has a higher ability to move electrons. The addition of the number of variations in the carbon mixture in NiCo2O4 shows the specific capacitance. It shows that carbon can prevent the movement of electrons in NiCo2O4, causing a decrease in performance. The right amount of carbon can increase the electron transfer ability.

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来源期刊
Materials Science for Energy Technologies
Materials Science for Energy Technologies Materials Science-Materials Science (miscellaneous)
CiteScore
16.50
自引率
0.00%
发文量
41
审稿时长
39 days
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