Ibrahim Hotan Alsohaimi , Abdulelah Nashmi Alrashidi , Hassan M.A. Hassan , Qiao Chen
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引用次数: 1
摘要
利用非溶剂诱导相分离(NIPS)方法,制备了由聚醚砜(PES)和微晶纤维素(MCC)制成的新型混合基质超滤膜(MMM),用于修复水介质中的溴酸盐(BrO3−)。还考察了MCC对接触角、孔隙率、水通量和BrO3−吸附性能的影响。高达5wt%的MCC的添加导致接触角从纯PES的60.1°显著下降到43.1°,表明膜亲水性增加。此外,在1、3和5 wt%浓度下,MCC的掺入导致水通量分别提高到169、178和180 L m−2 h−1,表明膜渗透性得到改善。MCC集成的PES膜表现出增强的防污性能,如含5%MCC的膜实现的高通量回收率(99%)所证明的。此外,所有MCC整合的PES膜在去除溴酸根离子(BrO3−)方面都表现出优异的性能,1%、3%和5%的MCC的截留率分别为60.8%、80.2%和92%,远高于原始PES膜。
Highly efficient ultrafiltration membrane performance of PES@microcrystalline cellulose extracted from waste fruits for the removal of BrO3− from drinking water samples
New mixed-matrix ultrafiltration membranes (MMMs) made of polyethersulfone (PES) and microcrystalline cellulose (MCC) were created utilizing a nonsolvent induced phase separation (NIPS) approach for the remediation of bromate (BrO3−) from aqueous medium. The influence of MCC integrated on the contact angle, porosity, water flux, and BrO3− adsorption performance was also examined. The addition of MCC, up to 5 wt%, resulted in a significant decline in the contact angle from 60.1° of neat PES to 43.1°, indicating an increase in membrane hydrophilicity. Moreover, MCC incorporation at 1, 3, and 5 wt% concentrations led to an enhancement in the water flux to 169, 178, and 180 L m−2 h−1, respectively, indicating the improved membrane permeability. MCC-integrated PES membranes exhibited enhanced antifouling properties, as demonstrated by the achieved high flux recovery ratio (99%) of the 5% MCC-containing membrane. Furthermore, all MCC-integrated PES membranes exhibited superior performance in the removal of bromate ions (BrO3−), with rejection rates of 60.8%, 80.2%, and 92% for 1%, 3%, and 5% MCC, respectively, which was much greater than that of the virgin PES membrane.
期刊介绍:
Colloid and Interface Science Communications provides a forum for the highest visibility and rapid publication of short initial reports on new fundamental concepts, research findings, and topical applications at the forefront of the increasingly interdisciplinary area of colloid and interface science.