{"title":"比较不同预处理工艺得到的木质素的理化特性和解聚行为","authors":"Qian Qian, Zhongyang Luo, Haoran Sun, Qi Wei, Jingkang Shi, Simin Li","doi":"10.1016/j.fuproc.2023.107921","DOIUrl":null,"url":null,"abstract":"<div><p><span><span><span><span>Lignin valorization is an important part of increasing the economic viability of sustainable biorefineries. Various methods have been proposed for lignin </span>depolymerization<span>. However, the relationship between lignin structure and its depolymerization behavior hasn't been extensively investigated. This research aims to clarify how the structure and composition of lignins derived from different </span></span>pretreatment<span> processes affect the downstream catalytic conversion. Herein, optimal organosolv lignin yield above 50% in three different solvent systems were obtained. Meanwhile, three types of hydrolyzed lignin were used as reference lignins. Various lignins were comprehensively characterized by </span></span>elemental analysis<span><span>, FT-IR, TGA-DSC and Py-GC/MS techniques. Compared with hydrolyzed lignin, organosolv lignin has higher purity, wider functional group distribution, more uniform structure, as well as a lower G/S ratio. Moreover, lignin depolymerization was carried out with a non-noble </span>metal catalyst Ni/Al</span></span><sub>2</sub>O<sub>3</sub> and without the addition of H<sub>2</sub><span>. The results showed that transetherification<span> and alkylation<span> reaction were enhanced significantly for organosolv lignin. Total depolymerized aromatics yield from organosolv lignin was 4 to 11 times higher than that of hydrolyzed lignin-rich residues. Notably, Methanol-extracted lignin obtained an optimal yield of 29.7 wt% of monomeric aromatics. Methanol can effectively protect benzylic carbocations formed during organosolv pretreatment, thus minimizing the formation of C</span></span></span><img>C bonds.</p></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":null,"pages":null},"PeriodicalIF":7.2000,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Comparing physicochemical characteristics and depolymerization behaviors of lignins derived from different pretreatment processes\",\"authors\":\"Qian Qian, Zhongyang Luo, Haoran Sun, Qi Wei, Jingkang Shi, Simin Li\",\"doi\":\"10.1016/j.fuproc.2023.107921\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span><span><span><span>Lignin valorization is an important part of increasing the economic viability of sustainable biorefineries. Various methods have been proposed for lignin </span>depolymerization<span>. However, the relationship between lignin structure and its depolymerization behavior hasn't been extensively investigated. This research aims to clarify how the structure and composition of lignins derived from different </span></span>pretreatment<span> processes affect the downstream catalytic conversion. Herein, optimal organosolv lignin yield above 50% in three different solvent systems were obtained. Meanwhile, three types of hydrolyzed lignin were used as reference lignins. Various lignins were comprehensively characterized by </span></span>elemental analysis<span><span>, FT-IR, TGA-DSC and Py-GC/MS techniques. Compared with hydrolyzed lignin, organosolv lignin has higher purity, wider functional group distribution, more uniform structure, as well as a lower G/S ratio. Moreover, lignin depolymerization was carried out with a non-noble </span>metal catalyst Ni/Al</span></span><sub>2</sub>O<sub>3</sub> and without the addition of H<sub>2</sub><span>. The results showed that transetherification<span> and alkylation<span> reaction were enhanced significantly for organosolv lignin. Total depolymerized aromatics yield from organosolv lignin was 4 to 11 times higher than that of hydrolyzed lignin-rich residues. Notably, Methanol-extracted lignin obtained an optimal yield of 29.7 wt% of monomeric aromatics. Methanol can effectively protect benzylic carbocations formed during organosolv pretreatment, thus minimizing the formation of C</span></span></span><img>C bonds.</p></div>\",\"PeriodicalId\":326,\"journal\":{\"name\":\"Fuel Processing Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":7.2000,\"publicationDate\":\"2023-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fuel Processing Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0378382023002692\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fuel Processing Technology","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0378382023002692","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Comparing physicochemical characteristics and depolymerization behaviors of lignins derived from different pretreatment processes
Lignin valorization is an important part of increasing the economic viability of sustainable biorefineries. Various methods have been proposed for lignin depolymerization. However, the relationship between lignin structure and its depolymerization behavior hasn't been extensively investigated. This research aims to clarify how the structure and composition of lignins derived from different pretreatment processes affect the downstream catalytic conversion. Herein, optimal organosolv lignin yield above 50% in three different solvent systems were obtained. Meanwhile, three types of hydrolyzed lignin were used as reference lignins. Various lignins were comprehensively characterized by elemental analysis, FT-IR, TGA-DSC and Py-GC/MS techniques. Compared with hydrolyzed lignin, organosolv lignin has higher purity, wider functional group distribution, more uniform structure, as well as a lower G/S ratio. Moreover, lignin depolymerization was carried out with a non-noble metal catalyst Ni/Al2O3 and without the addition of H2. The results showed that transetherification and alkylation reaction were enhanced significantly for organosolv lignin. Total depolymerized aromatics yield from organosolv lignin was 4 to 11 times higher than that of hydrolyzed lignin-rich residues. Notably, Methanol-extracted lignin obtained an optimal yield of 29.7 wt% of monomeric aromatics. Methanol can effectively protect benzylic carbocations formed during organosolv pretreatment, thus minimizing the formation of CC bonds.
期刊介绍:
Fuel Processing Technology (FPT) deals with the scientific and technological aspects of converting fossil and renewable resources to clean fuels, value-added chemicals, fuel-related advanced carbon materials and by-products. In addition to the traditional non-nuclear fossil fuels, biomass and wastes, papers on the integration of renewables such as solar and wind energy and energy storage into the fuel processing processes, as well as papers on the production and conversion of non-carbon-containing fuels such as hydrogen and ammonia, are also welcome. While chemical conversion is emphasized, papers on advanced physical conversion processes are also considered for publication in FPT. Papers on the fundamental aspects of fuel structure and properties will also be considered.