{"title":"磷石膏转化碳酸钙和一水硫酸锂的优化","authors":"Y. Ennaciri, M. Bettach","doi":"10.1051/mattech/2021020","DOIUrl":null,"url":null,"abstract":"Phosphogypsum (PG) is an acidic by-product generated during the production of phosphoric acid. Usually this by-product is stockpiled or dumped into water bodies, which causes several environmental pollution problems. The aim of this work is to reduce this environmental risk by producing CaCO3 and Li2SO4.H2O from the conversion of PG by Li2CO3. To optimize the reaction conditions, four parameters have been investigated such as the initial concentration of the reagents, the reaction duration, the temperature and the gypsum purity. In addition, the nature of the resulting products was proved principally by X-ray diffraction technic. The obtained results show that the initial concentration of the reagents and the reaction duration are the most influential parameters, while the temperature has no significance effect on this reaction. Also, the acidity and the presence of impurities into PG induce its reactivity compared than commercial gypsum. The purity of the formed CaCO3 and Li2SO4.H2O at the optimum conversion of PG is 96.08 and 98.71% respectively.","PeriodicalId":43816,"journal":{"name":"Materiaux & Techniques","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Optimization of phosphogypsum conversion into calcium carbonate and lithium sulfate monohydrate\",\"authors\":\"Y. Ennaciri, M. Bettach\",\"doi\":\"10.1051/mattech/2021020\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Phosphogypsum (PG) is an acidic by-product generated during the production of phosphoric acid. Usually this by-product is stockpiled or dumped into water bodies, which causes several environmental pollution problems. The aim of this work is to reduce this environmental risk by producing CaCO3 and Li2SO4.H2O from the conversion of PG by Li2CO3. To optimize the reaction conditions, four parameters have been investigated such as the initial concentration of the reagents, the reaction duration, the temperature and the gypsum purity. In addition, the nature of the resulting products was proved principally by X-ray diffraction technic. The obtained results show that the initial concentration of the reagents and the reaction duration are the most influential parameters, while the temperature has no significance effect on this reaction. Also, the acidity and the presence of impurities into PG induce its reactivity compared than commercial gypsum. The purity of the formed CaCO3 and Li2SO4.H2O at the optimum conversion of PG is 96.08 and 98.71% respectively.\",\"PeriodicalId\":43816,\"journal\":{\"name\":\"Materiaux & Techniques\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materiaux & Techniques\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1051/mattech/2021020\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materiaux & Techniques","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1051/mattech/2021020","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Optimization of phosphogypsum conversion into calcium carbonate and lithium sulfate monohydrate
Phosphogypsum (PG) is an acidic by-product generated during the production of phosphoric acid. Usually this by-product is stockpiled or dumped into water bodies, which causes several environmental pollution problems. The aim of this work is to reduce this environmental risk by producing CaCO3 and Li2SO4.H2O from the conversion of PG by Li2CO3. To optimize the reaction conditions, four parameters have been investigated such as the initial concentration of the reagents, the reaction duration, the temperature and the gypsum purity. In addition, the nature of the resulting products was proved principally by X-ray diffraction technic. The obtained results show that the initial concentration of the reagents and the reaction duration are the most influential parameters, while the temperature has no significance effect on this reaction. Also, the acidity and the presence of impurities into PG induce its reactivity compared than commercial gypsum. The purity of the formed CaCO3 and Li2SO4.H2O at the optimum conversion of PG is 96.08 and 98.71% respectively.
期刊介绍：
Matériaux & Techniques informs you, through high-quality and peer-reviewed research papers on research and progress in the domain of materials: physical-chemical characterization, implementation, resistance of materials in their environment (properties of use, modelling)... The journal concerns all materials, metals and alloys, nanotechnology, plastics, elastomers, composite materials, glass or ceramics. This journal for materials scientists, chemists, physicists, ceramicists, engineers, metallurgists and students provides 6 issues per year plus a special issue. Each issue, in addition to scientific articles on specialized topics, also contains selected technical news (conference announcements, new products etc.).
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