基于低聚环氧氯丙烷和哌嗪的离子交换流体材料

K. E. Varlan, Svetlana A. Plotichkina, Aleksandra L. Kuzmenko
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引用次数: 0

摘要

以低聚环氧氯丙烷与哌嗪缩合为原料,经化学改性,合成了具有离子交换性能的薄膜材料。采用与聚合物具有不同热力学亲和关系的化合物作为改性剂。研究表明,通过选择组合的顺序,可以克服各组分相容性不足的问题。结合的结果可以通过原料、中间产物和基于它们的预聚物的希尔德布兰德参数值来预测。通过选择甲苯二异氰酸酯、环氧大豆油和四乙氧基硅烷等化学改性剂的组合来调整合成材料的性能。
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Іонообмінні плівкові матеріали на основі олігоепіхлоргідринового епоксиду і піперазину
The film materials with ion-exchanged properties on the basis of the polymer, obtained by condensation of oligoepichlorohydrined epoxide and piperazine with the subsequent chemical modification have been synthesized. Compounds which have different thermodynamic affinity with the polymer and each other have been used as modifiers. It has been shown that the possibility of overcoming the lack of compatibility of the components by selection of the order of their combination. The result of the combination can be predicted by the Hildebrand parameter values of the ingredients, intermediate products and prepolymers based on them. The properties of synthesized materials can be adjusted by selection of combinations of chemical modifiers: toluilenediisocyanate, epoxyed soybean oil and tetraethoxysilane.
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