溶剂萃取矾铜最佳萃取剂的试验

IF 0.8 Q4 METALLURGY & METALLURGICAL ENGINEERING Kompleksnoe Ispolzovanie Mineralnogo Syra Pub Date : 2022-09-06 DOI:10.31643/2023/6445.06
T. Chepushtanova, M. Yessirkegenov, K. Mamyrbayeva, Y. Merkibayev, A. Nikolosky
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引用次数: 0

摘要

对于从浸出液中溶剂萃取铜,(PLS)目前市场上有各种各样的现代萃取剂,其选择是使用SX-EW(溶剂萃取和电积)技术生产铜的一个非常重要的问题。本工作的目的是确定用SX-EW处理铝矾矿生产液的最佳铜萃取剂。研究采用浸出Almaly矿床铜矿石的生产溶液进行,其组成为:1)Cu - 0.262, Fe-17.97, SiO2-0.36。模型溶液中铜的萃取结果表明,5% Acorga 5640萃取剂对铜的萃取率最高(94%),而其他萃取剂对铜的萃取率均不高(10% Lix984 ~ 93%);Acorga 5640 - 91%;10% Acorga 5910和10% Acorga 5747 -各85%。结果表明,采用5% Acorga 5640、10% Lix984和10% Acorga 5640萃取剂时,有机相铜的萃取率最高,达到90.2以上;10% Acorga 5910萃取剂时,铜的萃取率最低,达到88.2%。选择Acorga 5640为最佳萃取剂,萃取率为5%。
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English Testing of the optimum extragent for solvent-extraction of Almaly deposit copper
For the solvent extraction of copper from pregnant leach solutions, (PLS) a wide range of modern extractants is currently offered on the market, and its choice is a very important issue in the production of copper using the SX-EW (Solvent Extraction and Electrowinning) technology. The purpose of this work was to determine the optimal copper extractant for processing productive solutions of the Almaly deposit using the SX-EW. The studies were carried out with a productive solution obtained by leaching copper ores from the Almaly deposit of composition, g/dm3: 1) Cu– 0.262, Fe–17.97, SiO2–0.36. The results of copper extraction from model solutions showed that the maximum extraction of copper (94%) is observed when using the extractant 5% Acorga 5640, while the other extractants did not provide a high degree of extraction of 10% Lix984 - 93%; 10% Acorga 5640 - 91%; 10% Acorga 5910 and 10% Acorga 5747 - 85% each. According to the results of the retraction process, a high degree of copper extraction from the organic phase (90.2 and more) was ensured when using extractants of 5% Acorga 5640, 10% Lix984, and 10% Acorga 5640, the minimum - at 10% Acorga 5910 (88.2%). For the extraction of copper from the productive solution of the Almaly deposit 5% Acorga 5640 was chosen as the optimal extractant.
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