氢氧化钠智能手机法测定甲基紫的动力学常数

Yifan Zeng, Xiao-feng Qin, Yue Wang, Z. Li
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引用次数: 0

摘要

化学反应速率是反应动力学的基本概念,通过化学动力学实验确定反应速率规律是大学化学实验课程的常见内容。但是这个实验也有很多缺点,试剂的消耗大就是其中之一。我们从绿色化学的概念出发,提出将色彩理论与化学知识相结合,节省实验所用的试剂,提高学生对实验的兴趣。在本文中,我们首先进行了一项调查,调查人们对经典动力学实验的主观评价以及用智能手机做虚拟化学实验的意愿。在理论上分析了该方法的可行性后,我们拍摄了甲基紫与氢氧化钠反应的短视频,并用比色法测定了动力学常数。该方法结合了互补色理论和Lamber-Beer定律,只需使用智能手机和常用软件即可进行动态实验。
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Determination of Kinetic Constant of Methyl Violet with Sodium Hydroxide Using Smart Phone
The chemical reaction rate is the basic concept of reaction kinetics, and chemical kinetic experiments to determine rate laws are common in college chemistry laboratory courses. However, there are many shortcomings in this experiment, with the large consumption of reagents as one of them. Starting from the concept of green chemistry, we propose to combine the color theory with chemical knowledge, so as to save the reagents used in the experiment and improve the students’ interest in the experiment. In this paper, we first conducted a survey to investigate the subjective evaluation on classical kinetics experiments and the willingness to do virtual chemical experiments with smart phones. After analyzing the feasibility of the method in theory, we shot a short video of the reaction of methyl violet with sodium hydroxide, and determination of the kinetic constant using colorimetric analysis. The method combines the complementary color theory and Lamber-Beer law, and a dynamic experiment can be carried out by using smart phone and commonly used software only.
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