缠绕式过滤壳:高腐蚀性溶液合理净化工艺的关键

J. Radulovic, Radovan Karkalić
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引用次数: 2

摘要

本文介绍了一种基于双酚a聚酯树脂的纤维缠绕过滤壳用于高腐蚀性污染溶液净化的实际可行方法。介绍了长丝缠绕技术和聚酯及高分子复合材料的基本术语。给出了纯(无增强)双酚A聚酯树脂试样和以上述树脂和玻璃纤维为基础的复合材料试样的生产模式。将整齐的树脂样品分别暴露在次氯酸钙水溶液、氢氧化钠水溶液、硫酸水溶液、柠檬酸水溶液和液体洗涤剂的单一影响下360小时,并在所有上述水溶液的累计影响下总时间为1440小时。样品的质量变化、硬度和抗冲击性能测试表明,纯双酚A聚酯树脂的质量没有受到负面影响。长丝缠绕复合增强玻璃纤维/双酚A聚酯树脂基环和圆柱体暴露于次氯酸钙水溶液中1128小时。对复合材料增强环的质量变化、拉伸断裂力和拉伸强度以及复合材料增强缸的水力破裂压力进行了测试,结果表明,复合材料增强环具有较高的抗净化性能。结果表明,采用双酚A型聚酯树脂和玻璃纤维为原料,采用长丝缠绕技术可制备用于高腐蚀性污染溶液净化的过滤壳。
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Filament wound filter housing: Key for rational purification process of highly corrosive solutions
Practical and realistic approach for a successful use of filament wound filter housing based on bisphenol A polyester resin for purification of highly corrosive contaminated solutions is presented in this paper. Filament winding technology and basic terms about polyester and polymeric composite materials are described. Data about modes of producing neat (no reinforced) bisphenol A polyester resin specimens and composite material specimen, based on mentioned resin and glass fiber, are presented. Neat resin specimens were exposed to the single influence of aqueous solution of calcium hypochlorite, of sodium hydroxide, of sulphuric acid, of citric acid and liquid detergent for a period of 360 hours each, separately, and to the cumulative influence of all mentioned aqueous solutions for in overall period of 1440 hours. Tested properties of these specimens (mass change, hardness and impact resistance) showed that there is no negative influence on neat bisphenol A polyester resin quality. Filament wound composite reinforced glass fiber/bisphenol A polyester resin-based rings and cylinders were exposed to the influence of calcium hypochlorite aqueous solution for 1128 hours. Results of testing mass change, tensile breaking force and tensile strength of composite reinforced rings and hydraulic burst pressure of composite reinforced cylinders indicated that these specimens have high resistance to mentioned purification agent. It is concluded that the filter housing for purification of highly corrosive contaminated solutions can be produced by filament winding technology using bisphenol A polyester resin and glass fiber.
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