Sari Wahyuni , Muhammad Riswan , Nanang Adrianto , Mahardika Yoga Dharmawan , Rivaldo Marsel Tumbelaka , Rona Cuana , Nurul Imani Istiqomah , Adhistinka Jiananda , Shania Garcia , Edi Suharyadi
{"title":"绿色合成Fe3O4/Ag复合纳米颗粒的局域表面等离子体共振特性与Ag浓度和电场的关系","authors":"Sari Wahyuni , Muhammad Riswan , Nanang Adrianto , Mahardika Yoga Dharmawan , Rivaldo Marsel Tumbelaka , Rona Cuana , Nurul Imani Istiqomah , Adhistinka Jiananda , Shania Garcia , Edi Suharyadi","doi":"10.1016/j.photonics.2023.101191","DOIUrl":null,"url":null,"abstract":"<div><p>The use of green-synthesized Fe<sub>3</sub>O<sub>4</sub><span>/Ag composites nanoparticles<span> (NPs) on the surface plasmon<span><span> resonance (SPR) system induced by the electric field generates the effect of electrooptic-localized surface plasmon resonance (EO-LSPR). EO-LSPR is the promising method to increase dispersibility, generate plasmons, bind to biomolecular targets, modify the </span>refractive index, and increase the SPR signal. Green synthesis of Fe</span></span></span><sub>3</sub>O<sub>4</sub>/Ag NPs has several advantages, including being environmentally friendly, cost-effective, and sustainable. This research successfully investigated the EO-LSPR properties of green-synthesized Fe<sub>3</sub>O<sub>4</sub>/Ag NPs with various Ag concentrations. Green synthesis of Fe<sub>3</sub>O<sub>4</sub>/Ag composites NPs was prepared utilizing <em>Moringa oleifera</em><span> by an aqueous solution method. The EO-LSPR phenomenon was investigated by applying various voltages in the Kretschmann configuration with a layer arrangement of a prism/Au thin film/NPs/air with a wavelength of 632.8 nm. Transmission electron microscope results show that the average size of Fe</span><sub>3</sub>O<sub>4</sub>/Ag particles is around 16.72 ± 7.30 nm. The scanning electron microscopy-energy dispersive x-ray results showed that Ag was distributed on the surface of Fe<sub>3</sub>O<sub>4</sub><span><span>. The addition of Ag concentration decreased the saturation magnetization while the </span>coercivity field increased. The SPR angle of the prism/Au thin film/air layer structures is 44.66°. After depositing with Fe</span><sub>3</sub>O<sub>4</sub>/Ag with an Ag concentration of 60 millimolar, the LSPR angle shifted by 0.98°. Under an electric field, the LSPR angle shifted to 1.00°, 1.17°, and 1.22° of 2 volts, 4 volts, and 6 volts, respectively. The results show that applying the electric field induces the LSPR angle of Fe<sub>3</sub>O<sub>4</sub>/Ag NPs to shift to a larger angle. Applying an electric field causes a change in the material's refractive index. The greater the applied electric field, the more significant the LSPR angle shifts. The significant shifts in the LSPR angle due to the application of an electric field indicate that the EO-LSPR system using green-synthesized Fe<sub>3</sub>O<sub>4</sub><span>/Ag composites NPs could be a promising alternative to increase the performance of SPR biosensors in the future.</span></p></div>","PeriodicalId":49699,"journal":{"name":"Photonics and Nanostructures-Fundamentals and Applications","volume":null,"pages":null},"PeriodicalIF":2.5000,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Localized surface plasmon resonance properties dependence of green-synthesized Fe3O4/Ag composite nanoparticles on Ag concentration and an electric field for biosensor application\",\"authors\":\"Sari Wahyuni , Muhammad Riswan , Nanang Adrianto , Mahardika Yoga Dharmawan , Rivaldo Marsel Tumbelaka , Rona Cuana , Nurul Imani Istiqomah , Adhistinka Jiananda , Shania Garcia , Edi Suharyadi\",\"doi\":\"10.1016/j.photonics.2023.101191\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The use of green-synthesized Fe<sub>3</sub>O<sub>4</sub><span>/Ag composites nanoparticles<span> (NPs) on the surface plasmon<span><span> resonance (SPR) system induced by the electric field generates the effect of electrooptic-localized surface plasmon resonance (EO-LSPR). EO-LSPR is the promising method to increase dispersibility, generate plasmons, bind to biomolecular targets, modify the </span>refractive index, and increase the SPR signal. Green synthesis of Fe</span></span></span><sub>3</sub>O<sub>4</sub>/Ag NPs has several advantages, including being environmentally friendly, cost-effective, and sustainable. This research successfully investigated the EO-LSPR properties of green-synthesized Fe<sub>3</sub>O<sub>4</sub>/Ag NPs with various Ag concentrations. Green synthesis of Fe<sub>3</sub>O<sub>4</sub>/Ag composites NPs was prepared utilizing <em>Moringa oleifera</em><span> by an aqueous solution method. The EO-LSPR phenomenon was investigated by applying various voltages in the Kretschmann configuration with a layer arrangement of a prism/Au thin film/NPs/air with a wavelength of 632.8 nm. Transmission electron microscope results show that the average size of Fe</span><sub>3</sub>O<sub>4</sub>/Ag particles is around 16.72 ± 7.30 nm. The scanning electron microscopy-energy dispersive x-ray results showed that Ag was distributed on the surface of Fe<sub>3</sub>O<sub>4</sub><span><span>. The addition of Ag concentration decreased the saturation magnetization while the </span>coercivity field increased. The SPR angle of the prism/Au thin film/air layer structures is 44.66°. After depositing with Fe</span><sub>3</sub>O<sub>4</sub>/Ag with an Ag concentration of 60 millimolar, the LSPR angle shifted by 0.98°. Under an electric field, the LSPR angle shifted to 1.00°, 1.17°, and 1.22° of 2 volts, 4 volts, and 6 volts, respectively. The results show that applying the electric field induces the LSPR angle of Fe<sub>3</sub>O<sub>4</sub>/Ag NPs to shift to a larger angle. Applying an electric field causes a change in the material's refractive index. The greater the applied electric field, the more significant the LSPR angle shifts. The significant shifts in the LSPR angle due to the application of an electric field indicate that the EO-LSPR system using green-synthesized Fe<sub>3</sub>O<sub>4</sub><span>/Ag composites NPs could be a promising alternative to increase the performance of SPR biosensors in the future.</span></p></div>\",\"PeriodicalId\":49699,\"journal\":{\"name\":\"Photonics and Nanostructures-Fundamentals and Applications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2023-10-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Photonics and Nanostructures-Fundamentals and Applications\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1569441023000858\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Photonics and Nanostructures-Fundamentals and Applications","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1569441023000858","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Localized surface plasmon resonance properties dependence of green-synthesized Fe3O4/Ag composite nanoparticles on Ag concentration and an electric field for biosensor application
The use of green-synthesized Fe3O4/Ag composites nanoparticles (NPs) on the surface plasmon resonance (SPR) system induced by the electric field generates the effect of electrooptic-localized surface plasmon resonance (EO-LSPR). EO-LSPR is the promising method to increase dispersibility, generate plasmons, bind to biomolecular targets, modify the refractive index, and increase the SPR signal. Green synthesis of Fe3O4/Ag NPs has several advantages, including being environmentally friendly, cost-effective, and sustainable. This research successfully investigated the EO-LSPR properties of green-synthesized Fe3O4/Ag NPs with various Ag concentrations. Green synthesis of Fe3O4/Ag composites NPs was prepared utilizing Moringa oleifera by an aqueous solution method. The EO-LSPR phenomenon was investigated by applying various voltages in the Kretschmann configuration with a layer arrangement of a prism/Au thin film/NPs/air with a wavelength of 632.8 nm. Transmission electron microscope results show that the average size of Fe3O4/Ag particles is around 16.72 ± 7.30 nm. The scanning electron microscopy-energy dispersive x-ray results showed that Ag was distributed on the surface of Fe3O4. The addition of Ag concentration decreased the saturation magnetization while the coercivity field increased. The SPR angle of the prism/Au thin film/air layer structures is 44.66°. After depositing with Fe3O4/Ag with an Ag concentration of 60 millimolar, the LSPR angle shifted by 0.98°. Under an electric field, the LSPR angle shifted to 1.00°, 1.17°, and 1.22° of 2 volts, 4 volts, and 6 volts, respectively. The results show that applying the electric field induces the LSPR angle of Fe3O4/Ag NPs to shift to a larger angle. Applying an electric field causes a change in the material's refractive index. The greater the applied electric field, the more significant the LSPR angle shifts. The significant shifts in the LSPR angle due to the application of an electric field indicate that the EO-LSPR system using green-synthesized Fe3O4/Ag composites NPs could be a promising alternative to increase the performance of SPR biosensors in the future.
期刊介绍:
This journal establishes a dedicated channel for physicists, material scientists, chemists, engineers and computer scientists who are interested in photonics and nanostructures, and especially in research related to photonic crystals, photonic band gaps and metamaterials. The Journal sheds light on the latest developments in this growing field of science that will see the emergence of faster telecommunications and ultimately computers that use light instead of electrons to connect components.