{"title":"双(乙氧基乙酸酯)双铜(II)的单晶电子和电子自旋共振谱","authors":"R. J. Fereday, B. Hathaway","doi":"10.1039/J19710002758","DOIUrl":null,"url":null,"abstract":"The polarised single-crystal electronic and e.s.r. spectra of bis(ethoxyacetato)bisaquocopper(II) have been measured. The correlation of the single-crystal g-values and the crystallographic data suggest a dx2–y2 ground-state for the CuO4O′2 chromophore. The polarised single-crystal electronic spectra are interpreted in the effective symmetry of D2h and yield the tentative partial one-electron orbital sequence dx2–y2 > dz2 > dyz > dxz.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Single-crystal electronic and electron spin resonance spectra of bis(ethoxyacetato)bisaquocopper(II)\",\"authors\":\"R. J. Fereday, B. Hathaway\",\"doi\":\"10.1039/J19710002758\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The polarised single-crystal electronic and e.s.r. spectra of bis(ethoxyacetato)bisaquocopper(II) have been measured. The correlation of the single-crystal g-values and the crystallographic data suggest a dx2–y2 ground-state for the CuO4O′2 chromophore. The polarised single-crystal electronic spectra are interpreted in the effective symmetry of D2h and yield the tentative partial one-electron orbital sequence dx2–y2 > dz2 > dyz > dxz.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710002758\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710002758","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Single-crystal electronic and electron spin resonance spectra of bis(ethoxyacetato)bisaquocopper(II)
The polarised single-crystal electronic and e.s.r. spectra of bis(ethoxyacetato)bisaquocopper(II) have been measured. The correlation of the single-crystal g-values and the crystallographic data suggest a dx2–y2 ground-state for the CuO4O′2 chromophore. The polarised single-crystal electronic spectra are interpreted in the effective symmetry of D2h and yield the tentative partial one-electron orbital sequence dx2–y2 > dz2 > dyz > dxz.
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