Ni-Nb-Sb系大块金属玻璃的结晶行为

Junxia Lu, Jiliang Zhang, C. Shek
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引用次数: 0

摘要

研究了(Ni8Nb5)99.5Sb0.5大块金属玻璃在合成空气中700℃的结晶过程。结晶形成柱状NiNb2O6和氧化物Nb2O5和NiO。表面呈现致密连续的结构。从横截面上可以看出,氧化垢深度约为40µm。上尺度为致密结构,而随深度的增加,呈松散的层状结构。内部可见致密的过渡层。
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Crystallization behavior of Ni-Nb-Sb system bulk metallic glass
The crystallization of (Ni8Nb5)99.5Sb0.5 bulk metallic glass at the temperature of 700°C in the synthetic air was investigated. Crystallization occurred to form the columbite NiNb2O6 and oxides Nb2O5 and NiO. The surface presented the compact and continuous structure. The cross section shows that the oxide scale is about 40 µm depth. The upper scale forms the compact structure, however, loose one with the lamellar structure was observed with the depth. In the internal, a compact transition layer was also seen.
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