{"title":"光活性分子对圆偏振光微分拉曼散射的对称规则","authors":"L. Barron","doi":"10.1039/J19710002899","DOIUrl":null,"url":null,"abstract":"The various theories of optical activity are applied to the differential Raman scattering of circularly polarized light by optically active molecules. In particular, the ‘one electron’ theory provides simple symmetry rules which enable the dissymmetric environments of functional groups with well-defined ‘fingerprints’ in the Raman spectrum to be probed, and this could yield more detailed conformational and structural information than the o.r.d. and c.d. bands of dissymmetrically perturbed chromophores.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"338","resultStr":"{\"title\":\"Symmetry rules for the differential Raman scattering of circularly polarized light by optically active molecules\",\"authors\":\"L. Barron\",\"doi\":\"10.1039/J19710002899\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The various theories of optical activity are applied to the differential Raman scattering of circularly polarized light by optically active molecules. In particular, the ‘one electron’ theory provides simple symmetry rules which enable the dissymmetric environments of functional groups with well-defined ‘fingerprints’ in the Raman spectrum to be probed, and this could yield more detailed conformational and structural information than the o.r.d. and c.d. bands of dissymmetrically perturbed chromophores.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"338\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710002899\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710002899","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Symmetry rules for the differential Raman scattering of circularly polarized light by optically active molecules
The various theories of optical activity are applied to the differential Raman scattering of circularly polarized light by optically active molecules. In particular, the ‘one electron’ theory provides simple symmetry rules which enable the dissymmetric environments of functional groups with well-defined ‘fingerprints’ in the Raman spectrum to be probed, and this could yield more detailed conformational and structural information than the o.r.d. and c.d. bands of dissymmetrically perturbed chromophores.