Jian-Yu Zheng, Shuichi Noguchi, Kenjo Miyauchi, Masahiro Hamada, K. Kinbara, K. Saigo
{"title":"链连接的富勒烯供体二对体[60]","authors":"Jian-Yu Zheng, Shuichi Noguchi, Kenjo Miyauchi, Masahiro Hamada, K. Kinbara, K. Saigo","doi":"10.1081/FST-100107149","DOIUrl":null,"url":null,"abstract":"A series of [60]fullerene bis-adducts having a π-electron-rich aromatic ring as a donor in a face-to-face arrangement were synthesized by the bis-cyclopropanation of [60]fullerene with tether-linked bis-malonates. One of the bis-adducts showed a photoinduced intramolecular electron transfer which caused the dramatic quenching of its fluorescence in a polar solvent.","PeriodicalId":12470,"journal":{"name":"Fullerene Science and Technology","volume":"342 1","pages":"467 - 475"},"PeriodicalIF":0.0000,"publicationDate":"2001-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"TETHER-LINKED [60]FULLERENE-DONOR DYADS\",\"authors\":\"Jian-Yu Zheng, Shuichi Noguchi, Kenjo Miyauchi, Masahiro Hamada, K. Kinbara, K. Saigo\",\"doi\":\"10.1081/FST-100107149\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A series of [60]fullerene bis-adducts having a π-electron-rich aromatic ring as a donor in a face-to-face arrangement were synthesized by the bis-cyclopropanation of [60]fullerene with tether-linked bis-malonates. One of the bis-adducts showed a photoinduced intramolecular electron transfer which caused the dramatic quenching of its fluorescence in a polar solvent.\",\"PeriodicalId\":12470,\"journal\":{\"name\":\"Fullerene Science and Technology\",\"volume\":\"342 1\",\"pages\":\"467 - 475\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-08-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fullerene Science and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/FST-100107149\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fullerene Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/FST-100107149","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A series of [60]fullerene bis-adducts having a π-electron-rich aromatic ring as a donor in a face-to-face arrangement were synthesized by the bis-cyclopropanation of [60]fullerene with tether-linked bis-malonates. One of the bis-adducts showed a photoinduced intramolecular electron transfer which caused the dramatic quenching of its fluorescence in a polar solvent.