{"title":"硫代酸铅的制备及其性能","authors":"R. Shaw, M. Woods","doi":"10.1039/J19710001569","DOIUrl":null,"url":null,"abstract":"The preparation of a representative series of lead thiolates, Pb(SR)2(R = Et, Bun, But, Ph, p-C6H4Me, o-C6H4Me, p-C6H4Cl), is reported. Thermal decomposition of these thiolates leads to the formation of lead sulphide and the organic sulphide, R2S. Reaction of the thiolates with sulphur (or selenium) gives lead sulphide (or selenide) and the organic disulphide, R2S2. An assessment of the stability of lead thiolates in common organic solvents is given.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"26","resultStr":"{\"title\":\"Preparation and some properties of lead thiolates\",\"authors\":\"R. Shaw, M. Woods\",\"doi\":\"10.1039/J19710001569\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The preparation of a representative series of lead thiolates, Pb(SR)2(R = Et, Bun, But, Ph, p-C6H4Me, o-C6H4Me, p-C6H4Cl), is reported. Thermal decomposition of these thiolates leads to the formation of lead sulphide and the organic sulphide, R2S. Reaction of the thiolates with sulphur (or selenium) gives lead sulphide (or selenide) and the organic disulphide, R2S2. An assessment of the stability of lead thiolates in common organic solvents is given.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"26\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710001569\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710001569","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 26
摘要
报道了具有代表性的硫代酸铅系列Pb(SR)2(R = Et, Bun, But, Ph, p-C6H4Me, o-C6H4Me, p-C6H4Cl)的制备。这些硫酸盐的热分解导致硫化铅和有机硫化物R2S的形成。硫酸盐与硫(或硒)反应生成硫化铅(或硒化物)和有机二硫化物R2S2。对硫代酸铅在常见有机溶剂中的稳定性进行了评价。
The preparation of a representative series of lead thiolates, Pb(SR)2(R = Et, Bun, But, Ph, p-C6H4Me, o-C6H4Me, p-C6H4Cl), is reported. Thermal decomposition of these thiolates leads to the formation of lead sulphide and the organic sulphide, R2S. Reaction of the thiolates with sulphur (or selenium) gives lead sulphide (or selenide) and the organic disulphide, R2S2. An assessment of the stability of lead thiolates in common organic solvents is given.
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