实验和理论确定比热,相变温度和焓的铁- c - cr - ni允许

S. Sorokina, B. Smetana, Ľ. Drozdová, M. Kawuloková, S. Zlá
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引用次数: 0

摘要

材料的热力学和热物理性质的知识在许多工业应用中起着重要作用。本文主要研究了三种基于Fe-C-Cr-Ni的模型合金。所研究的合金含碳量为0.33 - 0.36 wt%,铬为1.08 - 4.70 wt%,镍为1.04 - 4.96 wt%。在低温区和高温区研究了不同合金成分的热物理和热力学性能,如比热、相变温度和焓。实验数据使用以下设备获得:Setaram Sensys Evo和Setaram MHTC Line 96带3D DSC传感器。比热采用连续法计算。所有的测量都是在氦大气中进行的。利用SW thermal - calc计算了相同的性能,并与实验数据进行了比较和讨论。
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EXPERIMENTAL AND THEORETICAL DETERMINATION OF SPECIFIC HEATS, PHASE TRANSFORMATIONS TEMPERATURES AND ENTHALPY OF Fe-C-Cr-Ni ALLOWS
Knowledge of thermodynamical and thermophysical properties of materials plays an important role for many industrial applications. The paper is dedicated to the study of three model alloys based on Fe-C-Cr-Ni. The studied alloys contained carbon in a range of 0.33 – 0.36 wt%, chromium 1.08 – 4.70 wt% and nickel 1.04 – 4.96 wt%. Thermophysical and thermodynamical properties depending on the composition of alloys such as specific heats, phase transformations temperatures and enthalpy were studied in low and high temperature areas. Experimental data were obtained using following devices: Setaram Sensys Evo and Setaram MHTC Line 96 with 3D DSC sensors. Specific heats were obtained using the continuous method. All measurements were performed in a helium atmosphere. The same properties were calculated using SW Thermo-Calc, then were compared and discussed with experimental data.
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