染料在沸石上的吸附性能及其对纺织废水的处理

Z. Hammood, Tasnim Fahim Chyad, Rasha Al-Saedi
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引用次数: 15

摘要

摘要纺织废水中染料的去除因其毒性大、不易被发现以及对水环境的不良影响而受到广泛关注。因此,出现了各种有前景的新技术,如吸附法去除工业废水中的染料。与高成本的处理技术相比,采用吸附法去除染料相对简单,成本较低。采用合成沸石作为高容量纳米吸附剂,对有色废水中的活性染料进行了脱除。考察了吸附剂用量(0.0025 ~ 0.02 g)、污染物浓度(25 ~ 200 mg/L)、接触时间(10 ~ 120 min)、搅拌程度(25 ~ 300 rpm)、溶液pH(2 ~ 8)对合成沸石吸附性能的影响。这些参数的最佳去除率分别为0.02 g、200 mg/L、80 min、300 rpm和6-7。同时,对Langmuir等温线和Freundlich等温线两种模型进行了评价。Langmuir等温线比Freundlich等温线更能有效地表示数据。Langmuir等温线的KL = 0.08 L/mg, qm = 6.02 mg/g, R2 = 0.98,与沸石吸附数据吻合。合成沸石对活性染料的吸附是确定工业废水处理厂染料去除率的重要工具。
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Adsorption Performance of Dyes Over Zeolite for Textile Wastewater Treatment
Abstract Removal of textile dyes from wastewater have recently attracted much attention, due to the toxicity, difficult visibility, and thereby the negative consequences on the aqueous environment. Therefore, there have been diverse promising new techniques such as adsorption for dyes removal from industrial wastewater. Compared to the highly cost treatment techniques, removal of dyes using the adsorption process is relatively simple and requires less cost. Synthetic zeolite was used in this research as a high capacity nano-adsorbent for the removal of reactive dyes from coloured wastewater. The impact of main parameters: dose of adsorbent (0.0025 to 0.02 g), pollutant concentration (25 to 200 mg/L), contact time (10 to 120 minutes), degree of agitation (25 and 300 rpm), and solution pH (2 to 8) on adsorption performance of the synthesised zeolite was investigated. The optimum values of these parameters to remove dyes efficiently at 90 % removal were 0.02 g, 200 mg/L, 80 min, 300 rpm, and 6-7 respectively. Also, two models were evaluated, the Langmuir and Freundlich isotherms. Langmuir isotherm was more efficient for representing the data than the Freundlich. The results of the Langmuir isotherm gave KL = 0.08 L/mg, qm = 6.02 mg/g, and R2 = 0.98, which fitted to the adsorption data of zeolite. Reactive dye adsorption by synthetic zeolite is a vital tool in identifying the fate of dye removal from industrial wastewater treatment plants.
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