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Determination of Cd, Pb and Zn in Polymers by Laser Ablation Microwave Induced Plasma Optical Emission Spectrometry 激光烧蚀微波诱导等离子体发射光谱法测定聚合物中的Cd、Pb和Zn
Pub Date : 2023-07-15 DOI: 10.2478/eces-2023-0035
M. Ślachciński, Michał Janeda, H. Matusiewicz
Abstract The potential of laser ablation microwave induced plasma optical emission spectrometry (LA-MIP OES) for the analysis of plastic materials has been investigated. Inorganic species, e.g., metals may be added to them as additives, anti-oxidising agents, stabilisers, plasticisers, colorants and catalytic residues, contaminants and may be present in a wide range of concentrations. The study revealed elevated content of trace elements (Cd, Pb and Zn) which are components of poly(vinyl chloride) (PVC) and polyethylene (PE). Laser ablation using wavelengths of 266 nm as a sampling method for MIP OES was used. The result achieved using elaborated system were compared with those obtained after polymer samples decomposition in high pressure-temperature focused microwave heating digestion system and standard sample pneumatic nebulisation (PN) to MIP OES spectrometer. The calibration strategy using cellulose pellets as support for qualitative analysis for element determination in polymers by LA-MIP OES was proposed. This analytical performance of the LA-MIP OES system was characterised by a determination of the limits of detection (LODs) and precision (RSDs) for elements tested. The experimental concentration detection limits for simultaneous determination, calculated as the concentration giving a signal equal to three times of the standard deviation of the blank (LOD, 3σblank criterion, peak height) were 2 µg g−1, 3 µg g−1 and 5 µg g−1 for Cd, Pb and Zn, respectively. The method offers relatively good precision (RSD ranged from 3 % to 5 %) for micro sampling analysis.
摘要研究了激光烧蚀微波诱导等离子体光谱法(LA-MIP OES)分析塑料材料的潜力。无机物质,例如金属,可以作为添加剂、抗氧化剂、稳定剂、增塑剂、着色剂和催化残留物、污染物加入其中,并且可能以各种浓度存在。研究发现,作为聚氯乙烯(PVC)和聚乙烯(PE)成分的微量元素(Cd、Pb和Zn)含量升高。采用266 nm激光烧蚀作为MIP OES的采样方法。将该系统所得到的聚合物样品在高压-高温聚焦微波加热消解系统和标准样品气动雾化(PN)分解后得到的结果与MIP OES光谱仪进行了比较。提出了以纤维素颗粒为支撑的LA-MIP OES测定聚合物中元素定性分析的校准策略。这种分析性能的LA-MIP OES系统的特点是确定的检出限(lod)和精密度(rsd)的元素被测试。同时测定Cd、Pb、Zn的实验浓度检出限分别为2µg g−1、3µg g−1和5µg g−1,其信号值为空白标准偏差(LOD、3σ空白判据、峰高)的3倍。该方法对微量样品分析具有较好的精密度(RSD为3% ~ 5%)。
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引用次数: 0
Ecovoltaics - A Truly Ecological and Green Source of Renewable Goods 生态发电-一个真正的生态和绿色来源的可再生产品
Pub Date : 2023-07-15 DOI: 10.2478/eces-2023-0032
A. Nowak, P. Świsłowski, S. Świerszcz, S. Nowak, M. Rajfur, M. Wacławek
Abstract The intensive exploitation of natural resources, expansion of human population and degradation of natural and semi-natural habitats, caused among others by agriculture, forestry and urbanisation, enforce special care for the natural resources, especially the disappearing types of vegetation that are refugees of biodiversity. One of the most threatened plant communities are grasslands (pastures and meadows), which has suffered the most in recent decades due to the intensification of agriculture and the transformation of land use. The purpose of this paper is to propose a hybrid approach to clean energy production on photovoltaic (PV) farms, taking into account the needs of grassland conservation and restoration. Nine sets of sciophilous species are proposed, including grasslands rich of pollinator benefits, grasslands with low pollen production to maintain high electrical efficiency of panels, and rich, standard meadows in wet (Molinion, Calthion, Alopecurion, Cnidion), fresh (Arrhenatherion) and dry (Cirsio-Brachypodion) types. The combination of clean energy and grassland conservation has been called ecovoltaics (EV) because it combines the production of renewable electricity with care for the diversity of valuable grassland ecosystems. The research will continue on an experimental ecovoltaic farm with innovative technical solutions to effectively maintain the desired meadow species composition. The purpose of this study was to analyse and select plant species that could be introduced into areas where PV cells are installed under climatic conditions in southern Poland. Using databases, environmental and ecological factors were taken into account. As a result of the study, a list of 206 species was selected that could be introduced to areas where they will coexist with PV panels, taking into account the effect of shading. The developed selection of these plant species provides a starting point for future work by botanists and engineers seeking to increase the biodiversity of sites where PV panels will be placed.
由于农业、林业和城市化等原因,对自然资源的集约化开发、人口的膨胀以及自然和半自然栖息地的退化,迫使人们对自然资源,特别是正在消失的植被类型给予特别的关注,它们是生物多样性的难民。受威胁最严重的植物群落之一是草原(牧场和草甸),近几十年来,由于农业集约化和土地利用方式的转变,草原遭受的损失最大。本文的目的是在考虑草原保护和恢复需求的情况下,提出一种光伏(PV)农场清洁能源生产的混合方法。本文提出了9组亲科学草地,包括具有丰富传粉者利益的草地、低花粉产量以维持面板高电效率的草地和丰富的标准湿草地(Molinion、Calthion、Alopecurion、Cnidion)、新鲜草地(Arrhenatherion)和干燥草地(Cirsio-Brachypodion)类型。清洁能源和草原保护的结合被称为生态发电(ecovoltaics, EV),因为它将可再生电力的生产与保护有价值的草原生态系统的多样性结合起来。该研究将继续在一个实验性生态光伏农场进行,并采用创新的技术解决方案,以有效地维持所需的草甸物种组成。本研究的目的是分析和选择在波兰南部气候条件下安装光伏电池的地区可以引入的植物物种。利用数据库,考虑了环境和生态因素。研究的结果是,考虑到遮阳的影响,选择了206个物种的清单,可以将它们引入与光伏板共存的区域。这些植物物种的成熟选择为植物学家和工程师寻求增加光伏电池板放置地点的生物多样性的未来工作提供了一个起点。
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引用次数: 1
Separation Technology of Components of Waste Pharmaceutical Blisters 废药膏组分分离技术研究
Pub Date : 2023-07-15 DOI: 10.2478/eces-2023-0034
E. Miękoś, M. Zieliński, D. Sroczyński, A. Fenyk
Abstract In this paper, the separation technology of components of waste pharmaceutical blisters and its adaptation to the industrial scale are described. It involved, among others, taking advantage of the phenomenon of difference in the density of the individual phases that were contained in the separation tank, i.e., the separating mixture, PVC plastics, and aluminium. As a result, the directions of movement of the separated blister components were opposite. All components of the separating mixture feature a similar surface tension (γ > 20 mN/m) which facilitates the penetration of the liquid between the blister component layers. After separation, the full-value products, i.e. polyvinyl chloride (PVC) and aluminium are obtained. The resulting products can be further processed and the entire technological process is a waste-free. PVC can be melted and processed into other products e.g. plastic components for the construction industry. Pure aluminium is a metal sought after and widely used in industry due to its low specific weight. An additional element supplementing the technology is the separation tank of our design in which the separation process of the blister components takes place. The advantage of the separation tank is that the separation process can be repeated many times with the same separating mixture until it is exhausted. Both separated blister components are directed to filtering followed by air drying without a mixing PVC plastic with aluminium.
摘要本文介绍了医药废旧泡剂的组分分离技术及其对工业规模的适应性。除其他外,它还涉及利用分离槽中包含的各个相的密度差异现象,即分离混合物,PVC塑料和铝。因此,分离的泡罩组分的运动方向是相反的。分离混合物的所有组分具有相似的表面张力(γ > 20 mN/m),这有利于液体在泡罩组分层之间的渗透。分离后,得到全价值产品,即聚氯乙烯(PVC)和铝。得到的产品可以进一步加工,整个工艺过程是零浪费的。PVC可以熔化并加工成其他产品,例如建筑行业的塑料部件。纯铝因其较低的比重而在工业上受到追捧和广泛应用。补充技术的另一个元素是我们设计的分离罐,其中泡罩组件的分离过程发生。分离槽的优点是可以用相同的分离混合物重复多次分离过程,直到耗尽为止。两种分离的吸塑组件都直接过滤,然后在没有混合PVC塑料和铝的情况下进行空气干燥。
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引用次数: 0
Corporate Environmental Management with Digital Transformation: Theory and Applications 数字化转型下的企业环境管理:理论与应用
Pub Date : 2023-06-01 DOI: 10.2478/eces-2023-0014
Wei Liu, S. Tsai, Chia-Huei Wu, Xuefeng Shao, M. Wacławek
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引用次数: 0
Carbon Emission Reduction Effect of Digital Infrastructure: From the “Broadband China” Strategy 数字基础设施的碳减排效应——基于“宽带中国”战略
Pub Date : 2023-06-01 DOI: 10.2478/eces-2023-0030
Yao Feng, Luosha Li, Hong Chen
Abstract The establishment of digital infrastructure embodies a pivotal instrument in propelling developmental metamorphosis, whilst fostering energy preservation and emission abatement. By employing municipal-level data spanning the period from 2009 to 2019, this research establishes a quasi-natural experiment anchored upon the “Broadband China” strategy. Employing the Difference-in-Differences (DID) methodology, this inquiry thoroughly examines the influence of digital infrastructure construction on the alleviation of carbon emissions. The findings indicate that the implementation of digital infrastructure exerts a notable impact on the reduction of carbon emissions. Moreover, carbon emission reduction resulting from digital infrastructure construction exhibits distinctive characteristics of heterogeneity. The empirical evidence presented within this study serves as a fundamental cornerstone for attaining the objectives of carbon peaking and carbon neutrality.
数字基础设施的建设是推动发展转型、促进节能减排的关键手段。本研究采用2009年至2019年的市级数据,建立了一个基于“宽带中国”战略的准自然实验。采用差异中差异(DID)方法,本研究深入考察了数字基础设施建设对减少碳排放的影响。研究结果表明,实施数字化基础设施对减少碳排放有显著影响。此外,数字基础设施建设带来的碳减排表现出明显的异质性特征。本研究中提出的经验证据是实现碳峰值和碳中和目标的基本基石。
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引用次数: 0
Evaluation of Soil Rocky Desertification in Karst Region Based on Deep Belief Network 基于深度信念网络的喀斯特地区土壤石漠化评价
Pub Date : 2023-06-01 DOI: 10.2478/eces-2023-0016
Guanyao Lu, Dan Xu, Y. Meng
Abstract Dynamic features from remote sensing photos may be successfully extracted using deep learning and symmetric network structure, which can then be used to direct them to carry out accurate classification. The DBN model can more effectively extract features from photos since it uses unsupervised learning. It can be reduced to the many symmetric Restricted Boltmann Machines (RBM) training problem. In this paper, a soil rocky desertification (RD) assessment model based on a deep belief network (DBN) is created in light of the complicated influencing aspects of Karst RD risk assessment encompassing several geographical elements. The model builds upon the conventional RBM framework and incorporates the influence layer of related elements as an auxiliary requirement for retrieving Geographic Information System (GIS) score data. Then, in order to forecast the level of soil rocky desertification, it learns the features of many elements. The experimental results show that the proposed model proposed in this paper has better prediction performance and faster convergence speed, and its classification results for different degrees of RD are more consistent with the actual risk assessment results.
摘要利用深度学习和对称网络结构可以成功提取遥感照片的动态特征,并指导遥感照片进行准确分类。DBN模型由于使用了无监督学习,可以更有效地从照片中提取特征。它可以简化为多对称受限玻尔特曼机(RBM)的训练问题。针对喀斯特土壤石漠化风险评估影响因素复杂、包含多个地理因素的特点,建立了基于深度信念网络(DBN)的土壤石漠化风险评估模型。该模型建立在传统RBM框架的基础上,并将相关元素的影响层作为检索地理信息系统(GIS)分数数据的辅助需求。然后,通过学习多种要素的特征来预测土壤石漠化程度。实验结果表明,本文提出的模型具有更好的预测性能和更快的收敛速度,其对不同程度RD的分类结果与实际风险评估结果更加一致。
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引用次数: 0
Remote Sensing Detection and Resource Utilisation of Urban Sewage Sludge Based on Mobile Edge Computing 基于移动边缘计算的城市污泥遥感检测与资源化利用
Pub Date : 2023-06-01 DOI: 10.2478/eces-2023-0029
Weijie Hu, Youfei Zhou, Junying Lu, Jun Sheng, Zechen Jin
Abstract Improper disposal of municipal sewage sludge poses a significant threat to effective environmental protection. With the continuous advancement of artificial intelligence technology and the Internet of Things (IoT), remote sensing detection technology is emerging as a promising research avenue to address this issue. However, the current state of real-time detection technology is inadequate, hindering comprehensive and stable monitoring operation. Additionally, the rational use of network resources remains suboptimal. To address this challenge, this study proposes a resource optimisation technology for the current insufficient intelligent monitoring system of urban sewage sludge. By leveraging IoT and wireless technology, water meter data can be collected with minimal earth construction compared to traditional PLC collection. This is followed by utilising Faster R-CNN to plan the network transmission of sewage remote sensing information resources. Finally, the architecture collection module’s scalability is enhanced by incorporating edge computing and reserving sensor ports to meet future plant expansion demands. The experiment demonstrates the significant potential of this technology in application and resource optimisation. In actual parameter tracking tests, the proposed method effectively monitors sewage sludge, providing policy guidance and measure optimisation for relevant authorities, ultimately contributing to pollution-free urban development.
城市污水污泥处置不当对有效的环境保护构成重大威胁。随着人工智能技术和物联网(IoT)的不断发展,遥感检测技术正在成为解决这一问题的一个有前途的研究途径。然而,目前实时检测技术的现状尚不完善,阻碍了全面、稳定的监测运行。此外,网络资源的合理使用仍然是次优的。为了应对这一挑战,本研究针对目前城市污泥智能监测系统的不足,提出了一种资源优化技术。通过利用物联网和无线技术,与传统的PLC收集相比,水表数据可以以最少的土地建设收集。然后利用Faster R-CNN规划污水遥感信息资源的网络传输。最后,通过结合边缘计算和保留传感器端口来增强架构采集模块的可扩展性,以满足未来工厂扩展的需求。实验证明了该技术在应用和资源优化方面的巨大潜力。在实际参数跟踪测试中,本文方法有效地监测了污水污泥,为相关部门提供政策指导和措施优化,最终促进城市无公害发展。
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引用次数: 1
One Belt and One Road Impact on Environment, Economy & Health in Western China Through Industry Transfer “一带一路”通过产业转移对西部地区环境、经济和健康的影响
Pub Date : 2023-06-01 DOI: 10.2478/eces-2023-0020
Kai Wang, Ao-Dong Wang
Abstract Based on fully absorbing and learning from the relevant research results at home and abroad, this paper focuses on four aspects: the transfer of polluting industries in the central and western regions and residents’ health problems. Firstly, the current pattern and development trend of regional pollution transfer in China; secondly, the economic effect of the transfer of polluting industries on the western undertaking areas; finally, from the micro and macro perspectives, the paper investigates the impact of the transfer of polluting industries on the individual health and health expenditure of residents in western China. The results show that the gap between industrial environmental and economic efficiency in the western region narrowed and gradually stabilised from 2008 to 2017. However, the gap between industrial environmental efficiency and economic efficiency in the western region widened from 2017 to 2020. The impact of environmental pollution on industrial environmental efficiency in the western provinces and regions has regional differences. Secondly, the present situation and trend of pollution control in western China are macroscopically investigated by comparing the output of general industrial solid waste and the investment in pollution control in different regions. Finally, this paper reveals the impact of the transfer of polluting industries on the health of residents in western China. Based on the characteristics of household category, age, and income of interviewees, the income growth effect of the transfer of polluting industries is less than the health loss caused by the transfer of pollution. It can be found that the transfer of polluting industries has a significant impact on the environment, economy, and the health of residents in western China.
摘要本文在充分吸收和借鉴国内外相关研究成果的基础上,重点从中西部污染产业转移和居民健康问题四个方面进行研究。首先,中国区域污染转移的现状与发展趋势;二是污染产业转移对西部承建区的经济影响;最后,从微观和宏观两方面考察了污染产业转移对西部地区居民个人健康和卫生支出的影响。结果表明:2008 - 2017年,西部地区工业环境与经济效率的差距逐渐缩小并趋于稳定;然而,2017 - 2020年西部地区工业环境效率与经济效率之间的差距有所扩大。环境污染对西部省区工业环境效率的影响存在区域差异。其次,通过比较不同地区一般工业固体废物产出量和污染治理投入,从宏观上考察了西部地区污染治理的现状和趋势。最后,本文揭示了污染产业转移对西部地区居民健康的影响。基于受访者的家庭类别、年龄和收入特征,污染产业转移的收入增长效应小于污染转移造成的健康损失。研究发现,污染产业转移对西部地区的环境、经济和居民健康都有显著影响。
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引用次数: 0
The Influence of Ecoenvironment Factors on the Development of Skiing 生态环境因素对滑雪运动发展的影响
Pub Date : 2023-06-01 DOI: 10.2478/eces-2023-0022
Xiao Zhang
Abstract Skiing depends on the external environment, in which material, energy and information are frequently exchanged, and this external environment greatly affects the quality of skiing’s existence. In this article, an ecosystem assessment algorithm based on ANN (Artificial Neural Network) is put forward. Based on this, a skiing development model under the influence of ecosystem factors is constructed to explore the influence of ecosystem factors on skiing development. The simulation results show that after many iterations, the error of this method is better than that of the comparison algorithm in ecosystem analysis, with the error reduced by 28.17 % and the recall rate reaching 94.65 %, which is improved by 16.88 % compared with the comparison algorithm. Therefore, this model can provide theoretical support for studying the influence of ecological and environmental factors on the growth of skiing. Based on the analysis of the characteristics of the regional landscape ecosystem, the eco-environmental impact assessment of the ski resort project predicts the impact of project construction on the regional landscape ecosystem. It explores ways and means to maintain the ecological integrity of the natural system to carry out project construction on the premise of protecting the local ecosystem and building a natural and artificial composite landscape ecosystem with reasonable structure and high efficiency.
摘要滑雪运动依赖于外部环境,物质、能量和信息的交换频繁,这种外部环境极大地影响着滑雪运动的生存质量。本文提出了一种基于人工神经网络的生态系统评价算法。在此基础上,构建生态因子影响下的滑雪运动发展模型,探讨生态因子对滑雪运动发展的影响。仿真结果表明,经过多次迭代,该方法在生态系统分析中的误差优于对比算法,误差降低了28.17%,召回率达到94.65%,比对比算法提高了16.88%。因此,该模型可以为研究生态环境因素对滑雪运动生长的影响提供理论支持。在分析区域景观生态系统特征的基础上,对滑雪场项目进行生态环境影响评价,预测项目建设对区域景观生态系统的影响。在保护当地生态系统的前提下,探索保持自然系统生态完整性的途径和手段,开展项目建设,构建结构合理、效率高的自然与人工复合景观生态系统。
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引用次数: 0
Design of Urban Sludge Emission Reduction Optimisation Strategy Based on Fuzzy Neural Network 基于模糊神经网络的城市污泥减排优化策略设计
Pub Date : 2023-06-01 DOI: 10.2478/eces-2023-0025
Youfei Zhou, Weina Hu, Junjie Sheng, Juanjuan Zhou, Wei-Guo Zou
Abstract Urban sewage sludge treatment is important for sustainable utilisation and virtuous cycle of freshwater resources. However, with the improvement of sewage discharge standards, ensuring stable operation of sewage sludge treatment plants is becoming an urgent problem to be solved in the sewage treatment industry. This paper proposes a FNN control framework based on different working conditions to optimise the whole process of municipal sewage sludge treatment and discharge. The framework first divides the working conditions according to the weather, forming a separate feature and an input vector together with the typical indicators of other sewage treatment plants. Then the FNN is used to complete the control and optimisation of various indicators, achieving the dual objectives of reducing energy consumption and optimising water quality. Finally, the model is tested for the tracking index of sewage flow. The results demonstrate that the FNN control method used has significantly lower MAE than the single method in the two indexes of energy consumption and water quality evaluation. This provides new ideas for the optimisation of urban sewage sludge treatment process in the future. Overall, the paper effectively highlights the importance of urban sewage sludge treatment and presents a well-designed FNN control framework for optimising the treatment process. Additionally, the paper could benefit from further elaboration on the significance of the results obtained, and suggestions for future research in this area.
城市污泥处理对淡水资源的可持续利用和良性循环具有重要意义。然而,随着污水排放标准的提高,确保污水污泥处理厂的稳定运行成为污水处理行业亟待解决的问题。本文提出了一种基于不同工况的模糊神经网络控制框架,对城市污泥处理排放全过程进行优化。框架首先根据天气对工况进行划分,与其他污水处理厂的典型指标形成单独的特征和输入向量。然后利用FNN完成各指标的控制和优化,达到降低能耗和优化水质的双重目的。最后,对模型进行了污水流量跟踪指标的测试。结果表明,采用FNN控制方法的能耗和水质评价两项指标的MAE均显著低于单一方法。这为今后城市污泥处理工艺的优化提供了新的思路。总体而言,本文有效地强调了城市污水污泥处理的重要性,并提出了一个精心设计的FNN控制框架,以优化处理过程。此外,本文可以受益于进一步阐述所获得的结果的意义,并建议在这一领域的未来研究。
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引用次数: 0
期刊
Ecological Chemistry and Engineering S
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