用于选择性气体吸收的新型介孔过滤器

M. Baumbach, A. Schutze, F. Cheng, S. Kelly, H. Delprat, F. Parret, P. Ménini, K. Soulantica, B. Chaudret, A. Maisonnat
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引用次数: 5

摘要

半导体气体传感器具有低成本和高灵敏度气体检测的潜力。然而,选择性仍然是许多应用的主要问题之一。报道了一种具有纳米级孔的新型介孔陶瓷过滤器。陶瓷过滤器提供机械保护,可以通过选择性气体吸收极大地提高选择性。所开发的纳米技术过滤器是基于具有特定粒径的介孔二次和三元氮化硅衍生物,并通过新的溶胶-凝胶途径制备的。利用宽带传感器评价了过滤器与CO、NO/sub - 2/、H/sub - 2/和丙烷的相互作用。对不同的气体,特别是NO/sub 2/,均有较高的选择性吸收。从这些实验中计算出过滤效率值,从而可以轻松选择适合不同应用的过滤材料。
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Novel mesoporous filters for selective gas absorption
Semiconductor gas sensors have a proven potential for low cost and highly sensitive gas detection. However, selectivity remains one of the main problems for many applications. We report a new kind of mesoporous ceramic filter with nanoscale pores. The ceramic filter offers mechanical protection and can help to boost selectivity enormously through selective gas absorption. The developed nano-technological filters are based on mesoporous secondary and ternary silicon nitride derivatives with a defined particle size and are prepared via a new sol gel route. The interaction of the filters with CO, NO/sub 2/, H/sub 2/ and propane were evaluated using broadband sensors. Highly selective absorption was observed for different gases, especially NO/sub 2/. From these experiments a filter efficiency value is calculated, which allows easy selection of suitable filter materials for different applications.
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