高挥发性有机化合物单片多结太阳能电池用半导体背反射器的设计

I. García, J. Geisz, M. Steiner, J. Olson, D. Friedman, S. Kurtz
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引用次数: 20

摘要

最先进的多结电池设计在进入更高数量的结之前有很大的改进潜力。例如,如果在结处发生的光子循环得到增强,Voc可以大大增加。这已经被证明(由Alta Devices)用于GaAs单结电池。为此,必须尽量减少由于底层或衬底的吸收而重新发射的光子的损失。为此需要选择性的后表面反射器。在这项工作中,评估了不同架构的半导体分布式布拉格反射器(DBR)作为应用于单片多结太阳能电池的合适选择。由于光子回收过程中的光子再发射在空间上是各向同性的,因此入射角对反射光谱的影响至关重要。此外,DBR结构的设计必须考虑到其集成到单片多结太阳能电池中,涉及串联电阻,增长经济等问题。我们分析了DBR设计复杂性的权衡与所有这些要求,以确定这种反射器是否适合改进多结太阳能电池。
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Design of semiconductor-based back reflectors for high Voc monolithic multijunction solar cells
State-of-the-art multijunction cell designs have the potential for significant improvement before going to higher number of junctions. For example, the Voc can be substantially increased if the photon recycling taking place in the junctions is enhanced. This has already been demonstrated (by Alta Devices) for a GaAs single-junction cell. For this, the loss of re-emitted photons by absorption in the underlying layers or substrate must be minimized. Selective back surface reflectors are needed for this purpose. In this work, different architectures of semiconductor distributed Bragg reflectors (DBR) are assessed as the appropriate choice for application in monolithic multijunction solar cells. Since the photon re-emission in the photon recycling process is spatially isotropic, the effect of the incident angle on the reflectance spectrum is of central importance. In addition, the DBR structure must be designed taking into account its integration into the monolithic multijunction solar cells, concerning series resistance, growth economics, and other issues. We analyze the tradeoffs in DBR design complexity with all these requirements to determine if such a reflector is suitable to improve multijunction solar cells.
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