掺杂TGS单晶的介电性能及低温弛豫研究

B. Jin, S. Erdei, A. Bhalla
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摘要

采用慢冷法制备了几种掺杂TGS的掺杂剂(丙氨酸、LiVO/ sub3 /和缬氨酸)。通过测量温度依赖性介电光谱,研究了相变温度、K/sub max/和室温介电常数随掺杂剂的变化规律。此外,还选择了几件来研究同一样品的位置不均匀性。进行D-E磁滞回线测量以检查内部偏置场(E/sub b/)。缬氨酸掺杂的TGS由于在-10/spl度/C左右的低温弛豫,虽然在转变温度(T/sub C/)下的热释电系数比丙氨酸高3倍,但不能得到高的品质系数(p/K)。
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Dielectric properties and low temperature relaxation studies of doped TGS single crystals
Several kinds of dopants (alanine, LiVO/sub 3/ and valine) doped TGS were grown from solution by slow cooling method. Temperature dependence dielectric spectra were measured to study the variation of transition temperature, K/sub max/ and room temperature dielectric constant depending on the dopants. Furthermore, several pieces were selected to investigate the positional inhomogeneities of the same sample. D-E hysteresis loop measurements were done to check for the internal bias field (E/sub b/). We could not get a high figure of merit (p/K) in valine doped TGS because of low temperature relaxation around -10/spl deg/C, although it has three times higher pyroelectric coefficient than that of alanine at transition temperature (T/sub C/).
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