钴(II)和镍(II)配合物的磁性和光谱学研究

D. Machin, J. Sullivan
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引用次数: 4

摘要

本文报道了氯化钴(II)和硝酸、氯化镍(II)和溴与2,3-、2,4-、3,4-和3,5-鲁替丁的八面体和四面体配合物在80 ~ 300 K温度范围内的磁化率和电子能谱。八面体钴(II)和四面体镍(II)配合物的磁性数据与具有轴对称的结构一致。
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Magnetic and spectroscopic studies of some lutidine complexes of cobalt(II) and nickel(II)
Magnetic susceptibilities in the temperature range 80—300 K, and electronic spectra of some octahedral and tetrahedral complexes of cobalt(II) chloride and nitrate, and nickel(II) chloride and bromide with 2,3-, 2,4-, 3,4-, and 3,5-lutidine are reported. The magnetic data for the octahedral cobalt(II) and tetrahedral nickel(II) complexes are consistent with structures having axial symmetry.
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