取向(K, Na) nbo3基陶瓷织构发育机理

A. Kikuchihara, T. Kimura
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引用次数: 1

摘要

采用单步熔盐合成(MSS)和两步熔盐合成(MSS)制备的两种片状NaNbO3模板粉和四种基体粉,考察了(K, Na) nbo3基陶瓷的晶粒取向发展,考察了取向程度的控制因素。单步MSS制备的模板颗粒溶解在NaNbO3和KNbO3粉末混合物的基质中,留下较大的空隙。两步MSS制备的模板颗粒不溶解,取向度重现性好。以KNbO3、NaNbO3和(K0.5Na0.5)NbO3为基体,以及KNbO3和NaNbO3粉末的混合物为模板粉,采用两步MSS法制备模板粉,考察了基体种类对晶粒取向的影响。只有在(K0.5Na0.5)NbO3和KNbO3和NaNbO3混合粉末中才出现了广泛的晶粒取向。通过显微组织观察分析了晶粒取向行为差异的原因。
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Mechanism of texture development in <001> oriented (K, Na)NbO3-based ceramics
The development of grain orientation was examined for (K, Na)NbO3-based ceramics using two kinds of platelike NaNbO3 template powders made by single- and two-step molten salt synthesis (MSS) and four kinds of matrix powders to examine the factors controlling the degree of orientation. The template grains made by single-step MSS were dissolved in the matrix of a mixture of NaNbO3 and KNbO3 powders, leaving large voids. The template grains made by two-step MSS were not dissolved and gave high reproducibility in the degree of orientation. The effect of matrix species on the grain orientation was examined using the template powder made by two-step MSS and the matrixes of KNbO3, NaNbO3, and (K0.5Na0.5)NbO3 powders and a mixture of KNbO3 and NaNbO3 powders. The extensive grain orientation developed only in (K0.5Na0.5)NbO3 and a mixture of KNbO3 and NaNbO3 powders. The origin of the difference in the grain orientation behavior was examined by microstructure observation.
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