不同温度下维生素B7与乙二醇混合物的热力学-声学研究

M. Lamba, N. Chakraborty, K. C. Juglan, Harsh Kumar
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引用次数: 0

摘要

用Anton Paar DSA 5000 M测量了含维生素B7(生物素)水溶液在(288.15K ~ 318.15K)和(0.000 ~ 0.003)mol.kg-1浓度下的密度和声速。利用观测数据推导出各种热声参数。声阻抗、绝热压缩系数、范德瓦尔常数、拉奥常数、瓦达常数和分子间自由长度由得到的声速和密度值决定。此外,生物素和乙二醇(丙二醇和己二醇)的三元混合物在液体溶液中显示出分子间(溶质-溶剂)相互作用。
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Thermodynamic-Acoustic Studies of Mixture Vitamin B7 with Glycols at Different Temperatures
The density and speed of sound for an aqueous solution containing Vitamin B7 (biotin) at variant temperatures from (288.15K to 318.15K) and (0.000 to 0.003) mol.kg-1 concentration has been measured with Anton Paar DSA 5000 M at constant pressure 0.1 MPa. The observed data were used to derive various thermo-acoustic parameters. Acoustic impedance, adiabatic compressibility, Vander Waal’s constant, Rao’s constant, Wada’s constant, and intermolecular free length were determined by the obtained speed of sound and density values. In addition, the ternary mixture of biotin and glycols (Propylene glycol and hexylene glycol) shows the intermolecular (solute-solvent) interactions inside the liquid solution.
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