首页 > 最新文献

Letters in Applied NanoBioScience最新文献

英文 中文
Pre-column Derivatization¸ Elution Order, Molecular Configuration and Green Chromatographic Separation of Diastereomeric Derivatives of β-Amino Alcohols β-氨基醇非对映异构体衍生物的柱前衍生、洗脱顺序、分子构型和绿色色谱分离
Pub Date : 2022-10-08 DOI: 10.33263/lianbs124.139
A green chromatographic method was developed for the indirect enantio-separation of racemic amino alcohols by introducing a micellar mobile phase for the HPLC. Here, cyanuric chloride-based activated chiral reagents were prepared, characterized, and used to derivatize racemic amino alcohols into diastereomeric derivatives. The chromatographic separation of the prepared diastereomeric derivatives was achieved on the C18 column of the RP-HPLC using a surfactant-based (Brij-35 + SDS) aqueous mobile phase (as an alternative to organic solvents). The impact of the varying concentration of surfactants in the mobile phase and pH of buffer on the chromatographic separation was optimized. Additionally, the DFT calculations were performed, and the absolute configurations and elution orders of the diastereomeric derivatives were investigated. Developed method’s robustness and selectivity was optimized by performing validation studies (LOD = 0.286 ng/mL; LOQ = 0.858 ng/mL). Also, the green assessment score was calculated for the developed method (84 scores; an excellent green method).
通过引入胶束流动相,建立了外消旋氨基醇间接对映分离的绿色色谱方法。本研究制备了三聚氰胺氯基活化手性试剂,对其进行了表征,并用于将外消旋氨基醇衍生为非对映异构体衍生物。制备的非对映异构体衍生物在反相高效液相色谱(RP-HPLC)的C18柱上使用基于表面活性剂(Brij-35 + SDS)的水流动相(作为有机溶剂的替代品)进行色谱分离。优化了流动相中不同表面活性剂浓度和缓冲液pH对色谱分离的影响。此外,进行了DFT计算,研究了非对映异构体衍生物的绝对构型和洗脱顺序。通过验证研究对方法的稳健性和选择性进行了优化(LOD = 0.286 ng/mL;LOQ = 0.858 ng/mL)。同时,计算了所开发方法的绿色评价得分(84分;一个极好的绿色方法)。
{"title":"Pre-column Derivatization¸ Elution Order, Molecular Configuration and Green Chromatographic Separation of Diastereomeric Derivatives of β-Amino Alcohols","authors":"","doi":"10.33263/lianbs124.139","DOIUrl":"https://doi.org/10.33263/lianbs124.139","url":null,"abstract":"A green chromatographic method was developed for the indirect enantio-separation of racemic amino alcohols by introducing a micellar mobile phase for the HPLC. Here, cyanuric chloride-based activated chiral reagents were prepared, characterized, and used to derivatize racemic amino alcohols into diastereomeric derivatives. The chromatographic separation of the prepared diastereomeric derivatives was achieved on the C18 column of the RP-HPLC using a surfactant-based (Brij-35 + SDS) aqueous mobile phase (as an alternative to organic solvents). The impact of the varying concentration of surfactants in the mobile phase and pH of buffer on the chromatographic separation was optimized. Additionally, the DFT calculations were performed, and the absolute configurations and elution orders of the diastereomeric derivatives were investigated. Developed method’s robustness and selectivity was optimized by performing validation studies (LOD = 0.286 ng/mL; LOQ = 0.858 ng/mL). Also, the green assessment score was calculated for the developed method (84 scores; an excellent green method).","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79955332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Morphology and Anti-microbial Studies of Zinc Stannate Nanoparticles Constructed via Green Synthesis Approach 绿色合成法制备锡酸锌纳米颗粒的形貌及抗菌性能研究
Pub Date : 2022-10-08 DOI: 10.33263/lianbs124.138
In the scientific field, microbial contaminations are growing along with the developments of newer research methodologies. Evaluating anti-microbial activity using newly designed materials has been gaining importance over the years to address this issue. The present work aims to form zinc stannate nanoparticles (ZTO NPs) through bio-synthesis and compare their biological efficiency with the as-synthesized nanoparticles through chemical synthesis. The nanoparticles (Zn2SnO4) were synthesized through a hydrothermal method by developing moderate experimental conditions. Three different combinations were synthesized using 2:1 mole ratio of ZnCl2 and SnCl2 precursors, and leaf extracts such as Aloe barbadensis mill and Terminalia catappa were used in the bio-synthesis method. Sodium hydroxide was used as a mineralizer in the chemical synthesis method. The obtained ZTO NPs were characterized by XRD, SEM-EDS, and UV-Visible spectral techniques. Finally, the antibacterial and anti-fungal activities were evaluated using the Agar-well diffusion method. Competitive biological activity response from the bio-synthesized ZTO NPs against the selected bacterial (Bacillus subtilis, S. Aureus, E. Coli, and P. Aeruginosa) and fungal strains (A. Niger and C. albicans). The synthesized ZTO NPs were highly efficient in exhibiting potential biological activity against the selected microbes.
在科学领域,随着新研究方法的发展,微生物污染也在不断增加。近年来,利用新设计的材料评估抗微生物活性对于解决这一问题越来越重要。本研究旨在通过生物合成制备锡酸锌纳米颗粒(ZTO NPs),并将其与化学合成的纳米颗粒进行生物效率比较。在适当的实验条件下,采用水热法制备了纳米Zn2SnO4。以ZnCl2和SnCl2为前体,以2:1的摩尔比合成了3种不同的组合,并以芦荟叶提取物和石斛叶提取物为原料进行生物合成。用氢氧化钠作为矿化剂进行化学合成。采用XRD、SEM-EDS和uv -可见光谱技术对所制得的ZTO NPs进行了表征。最后,采用琼脂孔扩散法对其抑菌和抗真菌活性进行了评价。生物合成的ZTO NPs对选定细菌(枯草芽孢杆菌、金黄色葡萄球菌、大肠杆菌和铜绿假单胞菌)和真菌(尼日尔芽孢杆菌和白色念珠菌)的竞争性生物活性反应。所合成的ZTO NPs对所选微生物具有很强的生物活性。
{"title":"Morphology and Anti-microbial Studies of Zinc Stannate Nanoparticles Constructed via Green Synthesis Approach","authors":"","doi":"10.33263/lianbs124.138","DOIUrl":"https://doi.org/10.33263/lianbs124.138","url":null,"abstract":"In the scientific field, microbial contaminations are growing along with the developments of newer research methodologies. Evaluating anti-microbial activity using newly designed materials has been gaining importance over the years to address this issue. The present work aims to form zinc stannate nanoparticles (ZTO NPs) through bio-synthesis and compare their biological efficiency with the as-synthesized nanoparticles through chemical synthesis. The nanoparticles (Zn2SnO4) were synthesized through a hydrothermal method by developing moderate experimental conditions. Three different combinations were synthesized using 2:1 mole ratio of ZnCl2 and SnCl2 precursors, and leaf extracts such as Aloe barbadensis mill and Terminalia catappa were used in the bio-synthesis method. Sodium hydroxide was used as a mineralizer in the chemical synthesis method. The obtained ZTO NPs were characterized by XRD, SEM-EDS, and UV-Visible spectral techniques. Finally, the antibacterial and anti-fungal activities were evaluated using the Agar-well diffusion method. Competitive biological activity response from the bio-synthesized ZTO NPs against the selected bacterial (Bacillus subtilis, S. Aureus, E. Coli, and P. Aeruginosa) and fungal strains (A. Niger and C. albicans). The synthesized ZTO NPs were highly efficient in exhibiting potential biological activity against the selected microbes.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76440341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Comprehensive Review on the Antimicrobial and Photocatalytic Properties of Green Synthesized Silver Nanoparticles 绿色合成纳米银的抗菌和光催化性能综述
Pub Date : 2022-10-08 DOI: 10.33263/lianbs124.140
With the advancement of technology, there is a growing demand for new nanoparticles that are viable, eco-friendly, non-toxic, and non-hazardous, as well as having unique chemical and physical properties. Silver nanoparticles are currently promising for antibacterial, antimicrobial, and photocatalytic applications. Because of their toxicity, nanosilver particles are now widely used in various applications, including cosmetics, clothing, sunscreen, medicinal, sensing, antibacterial, antimicrobial, and photocatalytic. The importance of plant extracts in the synthesis of AgNPs is emphasized. The various mechanisms and characterization techniques used in the study of silver nanoparticles will also be covered. This review also discusses the role of green synthesized AgNPs in antimicrobial and photocatalytic applications, which adds to our understanding of improving health, and the environment and preventing contagious diseases.
随着技术的进步,人们对新型纳米颗粒的需求不断增长,这些纳米颗粒必须可行、环保、无毒、无害,并且具有独特的化学和物理性质。银纳米颗粒目前在抗菌、抗菌素和光催化等方面有着广阔的应用前景。由于其毒性,纳米银颗粒现在广泛应用于各种应用,包括化妆品、服装、防晒、医药、传感、抗菌、抗菌剂和光催化。强调了植物提取物在AgNPs合成中的重要性。各种机制和表征技术用于银纳米粒子的研究也将被覆盖。本文综述了绿色合成AgNPs在抗菌和光催化方面的应用,为我们增进健康、环境和预防传染病的认识提供了新的途径。
{"title":"A Comprehensive Review on the Antimicrobial and Photocatalytic Properties of Green Synthesized Silver Nanoparticles","authors":"","doi":"10.33263/lianbs124.140","DOIUrl":"https://doi.org/10.33263/lianbs124.140","url":null,"abstract":"With the advancement of technology, there is a growing demand for new nanoparticles that are viable, eco-friendly, non-toxic, and non-hazardous, as well as having unique chemical and physical properties. Silver nanoparticles are currently promising for antibacterial, antimicrobial, and photocatalytic applications. Because of their toxicity, nanosilver particles are now widely used in various applications, including cosmetics, clothing, sunscreen, medicinal, sensing, antibacterial, antimicrobial, and photocatalytic. The importance of plant extracts in the synthesis of AgNPs is emphasized. The various mechanisms and characterization techniques used in the study of silver nanoparticles will also be covered. This review also discusses the role of green synthesized AgNPs in antimicrobial and photocatalytic applications, which adds to our understanding of improving health, and the environment and preventing contagious diseases.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85721588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sorption Removal of Methylene Blue Dye from Aqueous Solution by Powdered Yellow Flame Tree Flower (Peltophorum pterocarpum) 粉状黄焰树花对水溶液中亚甲基蓝染料的吸附去除
Pub Date : 2022-10-08 DOI: 10.33263/lianbs124.135
Present study involves the biosorptive removal study of methylene blue, a blue cationic thiazine dye using Peltophorum pterocarpumflowers (PPF). The effect of parameters on dye removal, such as contact time, pH, adsorbent, and adsorbate concentrations, were examined. The results demonstrated that the optimal experimental conditions for the adsorption were attained at pH 9 and contact time at 40 minutes. The equilibrium data of adsorption isotherms were well fitted to the Langmuir model with maximum adsorption efficiency of 71.9434 mg/g. The pseudo-second-order model could well fit the adsorption kinetics. These results demonstrate that the PPF biomaterial has the potential in effective sorptive elimination of MB dye from aqueous solutions.
本文研究了用紫花苜蓿(Peltophorum pterocarpumflowers, PPF)对蓝色阳离子噻嗪染料亚甲基蓝的生物吸附去除。考察了接触时间、pH、吸附剂、吸附质浓度等参数对染料去除率的影响。结果表明,在pH为9、接触时间为40 min时,吸附效果最佳。吸附等温线的平衡数据符合Langmuir模型,最大吸附效率为71.9434 mg/g。拟二阶模型能很好地拟合吸附动力学。这些结果表明PPF生物材料具有有效吸附去除水溶液中MB染料的潜力。
{"title":"Sorption Removal of Methylene Blue Dye from Aqueous Solution by Powdered Yellow Flame Tree Flower (Peltophorum pterocarpum)","authors":"","doi":"10.33263/lianbs124.135","DOIUrl":"https://doi.org/10.33263/lianbs124.135","url":null,"abstract":"Present study involves the biosorptive removal study of methylene blue, a blue cationic thiazine dye using Peltophorum pterocarpumflowers (PPF). The effect of parameters on dye removal, such as contact time, pH, adsorbent, and adsorbate concentrations, were examined. The results demonstrated that the optimal experimental conditions for the adsorption were attained at pH 9 and contact time at 40 minutes. The equilibrium data of adsorption isotherms were well fitted to the Langmuir model with maximum adsorption efficiency of 71.9434 mg/g. The pseudo-second-order model could well fit the adsorption kinetics. These results demonstrate that the PPF biomaterial has the potential in effective sorptive elimination of MB dye from aqueous solutions.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85929154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
In vitro Virucidal Activity of Silver Nanoparticles against H1N1 Influenza A Virus and Herpes Simplex Virus-1 纳米银对甲型H1N1流感病毒和单纯疱疹病毒1型的体外杀病毒活性研究
Pub Date : 2022-10-08 DOI: 10.33263/lianbs124.136
Silver nanoparticles (AgNPs) have provided a broad spectrum of antiviral activity against some types of enveloped and non-enveloped viruses. Silver nanoparticles are currently the most widely commercialized nanomaterials. In recent times, viral infections are emerging as one of the most common diseases with high mortality in the human population. The present study investigates the antiviral efficacy of the silver nanoparticles synthesized by the green method against HSV-1 and H1N1 influenza viruses. Characterization studies revealed that the silver nanoparticles showed an average particle size of 47 nm with a surface plasmon resonance peak at 426 nm. Silver nanoparticles exhibited 50% cytotoxicity in Vero cells at 197 µg/mL concentration, and 50% Inhibitory concentration (IC50) against HSV-1 was observed at 19.6 μg/mL. Silver nanoparticles demonstrated > 1 log reduction in H1N1 influenza A virus at 17 µg/mL. These findings indicate that silver nanoparticles possess excellent antiviral activity, which can be suitably used in various formulations to eradicate the spread of viral infections.
银纳米颗粒(AgNPs)对某些类型的包膜和非包膜病毒具有广谱的抗病毒活性。银纳米粒子是目前应用最广泛的纳米材料。近年来,病毒感染正在成为人口中死亡率高的最常见疾病之一。本研究考察了绿色法合成的银纳米颗粒对HSV-1和H1N1流感病毒的抗病毒作用。表征研究表明,银纳米粒子的平均粒径为47 nm,表面等离子体共振峰位于426 nm处。197 μg/mL银纳米粒子对Vero细胞具有50%的细胞毒性,19.6 μg/mL银纳米粒子对HSV-1有50%的抑制浓度(IC50)。在17 μ g/mL时,银纳米颗粒对甲型H1N1流感病毒的作用降低了1倍以上。这些发现表明,银纳米颗粒具有良好的抗病毒活性,可以适当地用于各种配方,以消除病毒感染的传播。
{"title":"In vitro Virucidal Activity of Silver Nanoparticles against H1N1 Influenza A Virus and Herpes Simplex Virus-1","authors":"","doi":"10.33263/lianbs124.136","DOIUrl":"https://doi.org/10.33263/lianbs124.136","url":null,"abstract":"Silver nanoparticles (AgNPs) have provided a broad spectrum of antiviral activity against some types of enveloped and non-enveloped viruses. Silver nanoparticles are currently the most widely commercialized nanomaterials. In recent times, viral infections are emerging as one of the most common diseases with high mortality in the human population. The present study investigates the antiviral efficacy of the silver nanoparticles synthesized by the green method against HSV-1 and H1N1 influenza viruses. Characterization studies revealed that the silver nanoparticles showed an average particle size of 47 nm with a surface plasmon resonance peak at 426 nm. Silver nanoparticles exhibited 50% cytotoxicity in Vero cells at 197 µg/mL concentration, and 50% Inhibitory concentration (IC50) against HSV-1 was observed at 19.6 μg/mL. Silver nanoparticles demonstrated > 1 log reduction in H1N1 influenza A virus at 17 µg/mL. These findings indicate that silver nanoparticles possess excellent antiviral activity, which can be suitably used in various formulations to eradicate the spread of viral infections.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87232212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Organic Chromophores from D–π–A to D–A’–π–A: Influence of the Auxiliary Acceptor on Energy Levels, Molecular Absorption, and Nonlinear Optical Response 从D -π-A到D - a ' -π-A的有机发色团:辅助受体对能级、分子吸收和非线性光学响应的影响
Pub Date : 2022-10-08 DOI: 10.33263/lianbs124.137
In this research article, four organic chromophores of type D–Ai–π–A (i=2–4) combining various auxiliary acceptors (Ai) with phenothiazine (PTZ) as the electron donor, thiophene as the π-conjugated bridge, and tricyanovinyl dihydrofuran (TCF) as the electron acceptor have been structured and theoretically studied using density functional theory (DFT) and time-dependent DFT (TD-DFT) methods. The effects of various auxiliary acceptors in D–Ai–π–A chromophores on the nonlinear optical (NLO) response have been examined. In this context, the geometric and electronic structures, intramolecular charge transfer (ICT), NBO analysis, absorption wavelength in different organic solvents, polarizability (α), and hyperpolarizability (β) have been determined. They have been assessed to predict the appropriate candidates for NLO material. The data obtained illustrate that all chromophores with various auxiliary acceptors present a large NLO response ranging from 13541.17 to 66723.38 (a.u), PTZ-2 especially with auxiliary acceptor 2,3-dimethylthieno[3,4-b]pyrazine presents the highest [(879.10 (a.u)) and βtot (66723.38 (a.u)] values. A strong NLO response indicates that this series of organic chromophores with a D-Ai-π-A architecture exhibits large first hyperpolarizability βtot values, which are much greater than those of urea.
本文采用密度泛函(DFT)和时变DFT (TD-DFT)方法,以吩噻嗪(PTZ)为电子给体,噻吩为π共轭桥,三氰乙烯基二氢呋喃(TCF)为电子受体,构建了四种由多种辅助受体(Ai)组成的D-Ai -π-A (i= 2-4)型有机发色团,并对其进行了理论研究。研究了D-Ai -π-A发色团中各种辅助受体对非线性光学响应的影响。在此背景下,测定了其几何和电子结构、分子内电荷转移(ICT)、NBO分析、在不同有机溶剂中的吸收波长、极化率(α)和超极化率(β)。对它们进行了评估,以预测NLO材料的合适候选材料。得到的数据表明,所有辅助受体的发色团的NLO响应范围在13541.17 ~ 66723.38 (a.u)之间,PTZ-2特别是辅助受体2,3-二甲基噻吩[3,4-b]吡嗪的NLO响应值最高[(879.10 (a.u))]和βtot (66723.38 (a.u)]。较强的NLO响应表明,该系列具有D-Ai-π-A结构的有机发色团具有较大的第一超极化率βtot值,远高于尿素。
{"title":"Organic Chromophores from D–π–A to D–A’–π–A: Influence of the Auxiliary Acceptor on Energy Levels, Molecular Absorption, and Nonlinear Optical Response","authors":"","doi":"10.33263/lianbs124.137","DOIUrl":"https://doi.org/10.33263/lianbs124.137","url":null,"abstract":"In this research article, four organic chromophores of type D–Ai–π–A (i=2–4) combining various auxiliary acceptors (Ai) with phenothiazine (PTZ) as the electron donor, thiophene as the π-conjugated bridge, and tricyanovinyl dihydrofuran (TCF) as the electron acceptor have been structured and theoretically studied using density functional theory (DFT) and time-dependent DFT (TD-DFT) methods. The effects of various auxiliary acceptors in D–Ai–π–A chromophores on the nonlinear optical (NLO) response have been examined. In this context, the geometric and electronic structures, intramolecular charge transfer (ICT), NBO analysis, absorption wavelength in different organic solvents, polarizability (α), and hyperpolarizability (β) have been determined. They have been assessed to predict the appropriate candidates for NLO material. The data obtained illustrate that all chromophores with various auxiliary acceptors present a large NLO response ranging from 13541.17 to 66723.38 (a.u), PTZ-2 especially with auxiliary acceptor 2,3-dimethylthieno[3,4-b]pyrazine presents the highest [(879.10 (a.u)) and βtot (66723.38 (a.u)] values. A strong NLO response indicates that this series of organic chromophores with a D-Ai-π-A architecture exhibits large first hyperpolarizability βtot values, which are much greater than those of urea.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86807681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Physico-Chemical, Ultrasonic, and Structural Studies on Dextrin with alpha-Amylase in Aqueous Media At 298.15 K 298.15 K水介质中α -淀粉酶糊精的理化、超声和结构研究
Pub Date : 2022-10-08 DOI: 10.33263/lianbs124.141
The ultrasonic velocity, density, and viscosity of dextrin in an aqueous medium at 298.15 K were measured using -amylase in this study. The measured parameters were used to calculate acoustic/density parameters such as molar volume (Vm), isentropic compressibility (T), thermal expansion coefficient (T), relaxation time (t), relaxation strength (r), relative viscosity (r), Enthalpy (H), Activation Energy (G), Surface Tension (), van der Walls constant (b), molecular radius (r), Geometrical volume (B), molar surface area (Y), Collision factor (S). Different acoustic magnitudes are computed because they are important in researching unique chemical interactions and theoretical calculations.
本研究用-淀粉酶测定了糊精在298.15 K水介质中的超声速度、密度和粘度。测量参数用于计算声/密度参数,如摩尔体积(Vm)、等熵压缩率(T)、热膨胀系数(T)、弛豫时间(T)、弛豫强度(r)、相对粘度(r)、焓(H)、活化能(G)、表面张力()、范德沃尔常数(b)、分子半径(r)、几何体积(b)、摩尔表面积(Y)、碰撞因子(S)计算不同的声级,因为它们在研究独特的化学相互作用和理论计算中很重要。
{"title":"Physico-Chemical, Ultrasonic, and Structural Studies on Dextrin with alpha-Amylase in Aqueous Media At 298.15 K","authors":"","doi":"10.33263/lianbs124.141","DOIUrl":"https://doi.org/10.33263/lianbs124.141","url":null,"abstract":"The ultrasonic velocity, density, and viscosity of dextrin in an aqueous medium at 298.15 K were measured using -amylase in this study. The measured parameters were used to calculate acoustic/density parameters such as molar volume (Vm), isentropic compressibility (T), thermal expansion coefficient (T), relaxation time (t), relaxation strength (r), relative viscosity (r), Enthalpy (H), Activation Energy (G), Surface Tension (), van der Walls constant (b), molecular radius (r), Geometrical volume (B), molar surface area (Y), Collision factor (S). Different acoustic magnitudes are computed because they are important in researching unique chemical interactions and theoretical calculations.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82265040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Herbal Immunomodulators: A Powerful Preventive Weapon for COVID-19 草药免疫调节剂:COVID-19的有力预防武器
Pub Date : 2022-09-25 DOI: 10.33263/lianbs124.134
S. Srivastava, S. Yadav, R. Chaubey, S. Ojha, A. Mishra, S. Mishra
The Corona Virus Disease of 2019 is characterized by a serious epidemic (COVID-19). The acute respiratory syndrome is caused by the coronavirus, which is followed by an inflammatory response in the host. Systemic inflammatory response syndrome (SIRS) is a condition in which the body causes acute breathing problems, multiple organ impairment disorder, and even in the early stages of multiple organ failure extreme COVID-19. Increased development of anti-inflammatory cytokines in the late stages of serious disease causes the immune system's reaction to becoming controlled, resulting in immune fatigue. Pandemics have wreaked havoc on humanity’s strata, wiped out whole nations, and strengthening immunity is long overdue. A strong immune system is needed to fight a viral infection. Multivitamin-rich diets improve pathogen immunity by triggering immune responses in several immune cells, as an example. Various immune-stimulating herbs, plants, and spices like chicory, Tinospora cordifolia, Withania somnifera, myrrh, ginger, etc., must be included to counteract the pathogens.
2019年冠状病毒病的特点是严重流行(COVID-19)。急性呼吸综合征是由冠状病毒引起的,随后宿主会出现炎症反应。全身性炎症反应综合征(SIRS)是一种身体引起急性呼吸问题、多器官损害障碍,甚至在多器官衰竭的早期阶段出现极端COVID-19的病症。在严重疾病的晚期,抗炎细胞因子的增加会导致免疫系统的反应受到控制,从而导致免疫疲劳。流行病给人类的各个阶层造成了巨大的破坏,摧毁了整个国家,增强免疫力早就应该了。对抗病毒感染需要强大的免疫系统。例如,富含多种维生素的饮食通过触发几种免疫细胞的免疫反应来提高病原体免疫力。各种免疫刺激的草药,植物和香料,如菊苣,Tinospora cordifolia, Withania somnifera,没药,姜等,必须包括在内,以抵消病原体。
{"title":"Herbal Immunomodulators: A Powerful Preventive Weapon for COVID-19","authors":"S. Srivastava, S. Yadav, R. Chaubey, S. Ojha, A. Mishra, S. Mishra","doi":"10.33263/lianbs124.134","DOIUrl":"https://doi.org/10.33263/lianbs124.134","url":null,"abstract":"The Corona Virus Disease of 2019 is characterized by a serious epidemic (COVID-19). The acute respiratory syndrome is caused by the coronavirus, which is followed by an inflammatory response in the host. Systemic inflammatory response syndrome (SIRS) is a condition in which the body causes acute breathing problems, multiple organ impairment disorder, and even in the early stages of multiple organ failure extreme COVID-19. Increased development of anti-inflammatory cytokines in the late stages of serious disease causes the immune system's reaction to becoming controlled, resulting in immune fatigue. Pandemics have wreaked havoc on humanity’s strata, wiped out whole nations, and strengthening immunity is long overdue. A strong immune system is needed to fight a viral infection. Multivitamin-rich diets improve pathogen immunity by triggering immune responses in several immune cells, as an example. Various immune-stimulating herbs, plants, and spices like chicory, Tinospora cordifolia, Withania somnifera, myrrh, ginger, etc., must be included to counteract the pathogens.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81867981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance Evaluation of Heat Pipe Heat Exchanger with Nanofluid: An Experimental Study 纳米流体热管换热器性能评价的实验研究
Pub Date : 2022-09-18 DOI: 10.33263/lianbs124.121
A heat pipe heat exchanger is fabricated and tested to recapture heat energy in low-temperature applications. The heat transfer fluid used has nanoparticles of zinc oxide suspended in water. The heat transmission performance of the arrangement is evaluated for variable heat supply at distinct mass flow rates. The mass flux for cold and hot air streams is changed for a specific heat input, and observations are recorded. The heat input values are incremented from 25 W to 1500 W while the flow rate of air is incremented from 0.047 to 0.236 m3/s. Maximum effectiveness of 0.28 is noted for heat input of 1500 W at a flow rate of 0.047 m3/s. The variation of heat transfer coefficient is studied for change in flow rate of air and source temperature of the air supplied. It is found that the coefficient of heat transfer increases with source temperature. The enhancement of performance is credited to better thermal conductivity due to the introduction of nanoparticles.
制造并测试了一种热管换热器,用于在低温应用中回收热能。所使用的传热流体含有悬浮在水中的氧化锌纳米颗粒。在不同的质量流量下,对不同的供热进行了评价。冷热气流的质量通量根据特定的热量输入而改变,并记录观测结果。热量输入由25w增加到1500w,风量由0.047 m3/s增加到0.236 m3/s。当流量为0.047 m3/s,热量输入为1500 W时,最大效率为0.28。研究了送风流量和送风源温度的变化对换热系数的影响。结果表明,传热系数随热源温度的升高而增大。性能的增强归功于纳米颗粒的引入带来了更好的导热性。
{"title":"Performance Evaluation of Heat Pipe Heat Exchanger with Nanofluid: An Experimental Study","authors":"","doi":"10.33263/lianbs124.121","DOIUrl":"https://doi.org/10.33263/lianbs124.121","url":null,"abstract":"A heat pipe heat exchanger is fabricated and tested to recapture heat energy in low-temperature applications. The heat transfer fluid used has nanoparticles of zinc oxide suspended in water. The heat transmission performance of the arrangement is evaluated for variable heat supply at distinct mass flow rates. The mass flux for cold and hot air streams is changed for a specific heat input, and observations are recorded. The heat input values are incremented from 25 W to 1500 W while the flow rate of air is incremented from 0.047 to 0.236 m3/s. Maximum effectiveness of 0.28 is noted for heat input of 1500 W at a flow rate of 0.047 m3/s. The variation of heat transfer coefficient is studied for change in flow rate of air and source temperature of the air supplied. It is found that the coefficient of heat transfer increases with source temperature. The enhancement of performance is credited to better thermal conductivity due to the introduction of nanoparticles.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74358926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Nano Adsorbents in Wastewater Treatment: A New Paradigm in Wastewater Management 纳米吸附剂在废水处理中的应用:废水管理的新范式
Pub Date : 2022-09-18 DOI: 10.33263/lianbs124.125
Increasing water pollution has urged the need to elucidate more potent techniques for removing contaminants from wastewater 1 and groundwater. Numerous techniques or processes have been explored and designed for water purification. Amongst all other water/wastewater remediation techniques, nanotechnology has gained wider attention in water remediation via numerous mechanisms, such as the adsorption of heavy metals and the removal of pathogens. Nanoadsorbent materials have emerged as a promising solution for solving this crucial environmental issue. Their unique chemical and physical properties, such as higher ranking, quality, and status, promote their application compared to traditional adsorbents. Recent research studies have reported their promising potential in water treatment, including polymeric, carbon, tubezeolites, and metal nanosorbents. Hence, this review mainly aims to provide summarized data presenting all the beneficial aspects of nanosorbents in wastewater/water remediation.
日益严重的水污染迫切需要阐明从废水和地下水中去除污染物的更有效的技术。已经探索和设计了许多用于水净化的技术或工艺。在所有其他水/废水修复技术中,纳米技术通过多种机制在水修复中获得了广泛的关注,例如吸附重金属和去除病原体。纳米吸附材料已成为解决这一关键环境问题的一个有希望的解决方案。与传统吸附剂相比,它们独特的化学和物理性质,如更高的等级、质量和地位,促进了它们的应用。最近的研究报道了聚合物、碳、管状沸石和金属纳米吸附剂在水处理中的应用前景。因此,本文主要旨在总结纳米吸附剂在废水/水修复中的所有有益方面的数据。
{"title":"Nano Adsorbents in Wastewater Treatment: A New Paradigm in Wastewater Management","authors":"","doi":"10.33263/lianbs124.125","DOIUrl":"https://doi.org/10.33263/lianbs124.125","url":null,"abstract":"Increasing water pollution has urged the need to elucidate more potent techniques for removing contaminants from wastewater 1 and groundwater. Numerous techniques or processes have been explored and designed for water purification. Amongst all other water/wastewater remediation techniques, nanotechnology has gained wider attention in water remediation via numerous mechanisms, such as the adsorption of heavy metals and the removal of pathogens. Nanoadsorbent materials have emerged as a promising solution for solving this crucial environmental issue. Their unique chemical and physical properties, such as higher ranking, quality, and status, promote their application compared to traditional adsorbents. Recent research studies have reported their promising potential in water treatment, including polymeric, carbon, tubezeolites, and metal nanosorbents. Hence, this review mainly aims to provide summarized data presenting all the beneficial aspects of nanosorbents in wastewater/water remediation.","PeriodicalId":18009,"journal":{"name":"Letters in Applied NanoBioScience","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84060928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
Letters in Applied NanoBioScience
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1