Cu2O/g-C3N4催化剂光降解2,4-二氯苯氧乙酸的研究

Son Le Thanh, Binh Nguyen Thanh, Dang Do Van, Long Dang Van
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摘要

采用常规浸渍法制备了x% (wt) Cu2O/g-C3N4系列复合材料。用x射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、紫外-可见漫反射光谱(UV-DRS)和光致发光光谱(PL)等方法对化合物进行了表征。结果清楚地表明Cu2O和g-C3N4相的存在。通过对2,4-二氯苯氧乙酸(2,4- d)的降解来评价其光催化活性。5% Cu2O/g-C3N4催化剂活性最高,光降解率达到7.3%。H2O2的加入显著提高了产率,辐照1小时后产率达到98.5%。
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Investigation of photodegradation of 2,4-Dichlorophenoxyacetic acid on Cu2O/g-C3N4 catalysts
The series x% (wt) Cu2O/g-C3N4 composites were prepared by the conventional impregnation method. These compounds were characterized by different methods such as X-ray Diffraction (XRD), Fourier Transform Infrared spectroscopy (FTIR), UV–vis diffuse reflectance spectroscopy (UV-DRS), and Photoluminescence spectroscopy (PL). The results clearly showed the existence of Cu2O and g-C3N4 phases. The photocatalytic activity was estimated by the degradation of 2,4-Dichlorophenoxyacetic acid (2,4-D). The 5% Cu2O/g-C3N4 catalyst showed the highest activity, with the photodegradation yield reached 7,3%. The addition of H2O2 remarkably improved the yield, with 98,5% attained after 1 hour of irradiation. 
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