含三硫化钼量子点涂层保护油画免受不同环境因素的影响

Eslam M. Taha, M. Mohie, M. Korany, N. Aly, A. Ropy, M. Negem
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摘要

目的深入探讨三硫化钼量子点(MoS3 QDs)在防止微生物、污垢积聚和紫外线(UV)降解等方面对油画变质的保护作用。设计/方法/途径保护油漆免受不同的劣化因素需要可持续的方法和先进的技术。利用扫描电子显微镜和透射电子显微镜分别研究了涂层量子点和MoS3量子点的形态结构,并用光学显微镜检测了MoS3量子点对不同类型细菌的抗菌活性。为了研究绘画对变质的保护作用,使用傅里叶变换红外光谱(FTIR)对露天放置一年的绘画进行了研究。利用x射线衍射和x射线光电子能谱分析分别研究了MoS3量子点的化学组成和晶体结构。结果:在油漆涂料中加入MoS3纳米粒子,可以提高亚麻籽油基涂料的抗紫外线老化的耐久性,并通过FTIR分析证实了这一点。通过在油画涂层中加入MoS3量子点,研究了油画对各种变质因素的保护作用。研究了MoS3量子点对铜绿假单胞菌等不同类型细菌的抑菌效果,证实了油画涂层中的MoS3量子点对油画产生了高保护层,使油画免受多种微生物的攻击。此外,含有MoS3量子点的涂层在露天放置一年后减少了油画上污垢的积累。利用新型的MoS3量子点,为油画形成一层具有保护作用的透明涂层,克服了变质,显示出良好的保护效果,可应用于不同的油画。
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Coatings containing molybdenum trisulphide QDs to protect oil paintings against different environmental factors
Purpose This study aims to investigate profoundly the protection of oil painting from deterioration using molybdenum trisulphide quantum dots (MoS3 QDs) against microbe, dirt accumulation and ultraviolet (UV) degradation. Design/methodology/approach The protection of painting against different deterioration factors necessitates the sustainable methods and advanced techniques. Scanning electron microscopy and transmission electron microscopy have been used to investigate the morphological structure of the painting and MoS3 QDs, respectively, and optical microscopy was used to examine antibacterial activity of MoS3 QDs towards different types of bacteria. To investigate the protection of painting against deterioration, the Fourier transform IR spectroscopy (FTIR) was used to investigate the paintings left in open air for a year. Chemical composition and crystal structure of MoS3 QDs have been studied using X-ray diffraction and X-ray photoelectron spectroscopy analysis, respectively. Findings The addition of MoS3 nanoparticles into painted coatings enhances the durability of linseed oil-based paintings toward UV ageing regarding the change in colour which confirmed by FTIR analysis. The protection of oil painting opposed to various deterioration factors was developed by involving of MoS3 QDs in the coating of the painting. Antibacterial effect of MoS3 QDs was tested against different types of bacteria such as Pseudomonas aeruginosa confirming that the MoS3 QDs involved in the coatings of oil paintings produces a high protection layer for the paintings against several microbial attacks. In addition, coatings containing MoS3 QDs reduce the accumulation of dirt on oil paintings when subjected to open air for a year. Originality/value The novel MoS3 QDs was used to form a protective and transparent coating layer for the oil painting to overcome the deterioration, displays the promising protection and can be applied for different oil paintings.
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