生物相容性ZnO/β-CD纳米复合材料的合成及亚甲基蓝染料光催化降解研究

T. Rajalakshmi, G. Alagumuthu
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摘要

文章历史:2019年3月20日收稿2019年4月29日接受2019年6月29日在线2019年6月8日在本研究中,以六水合物硝酸锌和碳酸钠为前体,通过简单沉淀法成功合成了氧化锌/ β-环糊精纳米复合材料。将制备的ZnO纳米颗粒与β-环糊精溶液按一定比例混合,形成纳米复合材料,然后在150℃下退火2 h。采用x射线衍射(XRD)、傅里叶红外光谱(FTIR)、紫外可见光谱(UVvisible spectroscopy)和原子力显微镜(AFM)对制备的样品进行表征。XRD结果表明ZnO晶体具有六方纤锌矿结构。通过测量样品在室温下的紫外可见吸收来研究样品的光学性质。FTIR结果证实了官能团的存在。以合成的纳米复合材料为光催化剂,对亚甲基蓝染料的光催化降解进行了研究。
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Synthesis of Biocompatible ZnO/β-CD Nanocomposite and Photocatalytic Degradation Study with Methylene Blue Dye
Article history: Received 20 March 2019 Accepted 29 April 2019 Available online 08 June 2019 In this present work zinc oxide/ β-cyclodextrin nanocomposite was successfully synthesized by a simple precipitation method using zinc nitrate hexa hydrate and sodium carbonate as precursors. The prepared ZnO nanoparticles were mixed with β-cyclodextrin solution under proper proportions and formed nanocomposite then annealed at 150 C for 2 h. The prepared samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UVvisible spectroscopy and AFM. The XRD results indicate that the ZnO crystal has a hexagonal wurtzite structure. The optical properties of the samples are investigated by measuring the UV-VIS absorption at room temperature. FTIR results prove the functional groups present. Photocatalytic degradation of methylene blue (MB) dye was studied using the synthesized nanocomposites applied as photocatalyst.
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